皮蝇磷,299-84-3，生产厂家，价格-洛克化工网移动版

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基本信息

制备方法及用途

物化性质

安全信息

毒理性

MSDS

结构与计算化学

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下游产品

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皮蝇磷

中文名称：: 皮蝇磷

中文别名：: 皮蝇磷;
皮蝇硫磷;
O，O-二甲基-O-(2，4，5-三氯苯基)硫逐磷酸酯;
芬氯磷;
0,O-二甲基-O-(2,4,5-三氯苯基)硫代磷酸酯

英文名称：: Phosphorothioic acid,O,O-dimethyl O-(2,4,5-trichlorophenyl) ester

英文别名：: fenchlorphos;
dimethoxy-sulfanylidene-(2,4,5-trichlorophenoxy)-λ5-phosphane;
Dermafos;
ronnel;
Fenclofos;
Korlane;
Etrolene;
O,O-dimethyl O-2,4,5-trichlorophenyl phosphorothioate;
O,O-dimethyl O-(2,4,5-trichlorophenyl) phosphorothioate;
Ectoral;
Fenchlorphos;
O,O-dimethyl-O-(2,4,5-trichlorophenyl) phosphorothionate;
RONNEL;
fenclofos;
Phenchlorfos;
Fenchlorfos;
Nanchor

CAS No.：: 299-84-3

分子式：: C₈H₈Cl₃O₃PS

分子量：: 321.55

精确分子量：: 319.90000

PSA：: 69.59000

MDL：: MFCD00055245

EINECS：: 206-082-6

BRN：: 1885571

InChI：: InChI=1/C8H8Cl3O3PS/c1-13-15(12,14-2)16-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H33

危险品标志：: XnNF

风险术语：: R21/22;R50/53;R67;R65;R38;R11;

安全术语：: S25;S36/37;S60;S61;S62;

分子结构式：

SDS：: 查看

皮蝇磷物化性质

密度：
1.527g/cm3

熔点：
35ºC

沸点：
97 at 0.01 mm Hg

闪点：
-18 °C

水溶解性：
0.00 g/100 mL

折射率：
1.572

蒸汽压：
3.15E-05mmHg at 25°C

存储条件/存储方法：
库房通风低温干燥,与食品原料分开储运

稳定性相关：
在中性或酸性介质中稳定，不和和碱性物质如石灰、硫磺液混合，在碱性介质中迅速分解失效。

其它信息：

一、物性数据
性状：白色结晶粉末.
密度（g/mL,25/4℃）：不可用
相对蒸汽密度（g/mL,空气=1）：1.485

皮蝇磷安全信息

危险类别码：
21/22-50/53-67-65-38-11

安全说明：
25-36/37-60-61-62

RTECS号：
TG0525000

安全标志：
S25:避免接触眼睛。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。
S62:如果不慎吞咽，不要催吐；立刻找医生诊治并出示产品容器或标签。
:

危险标志：
Xn,N,F

皮蝇磷毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TG0525000

CHEMICAL NAME :
Phosphorothioic acid, O,O-dimethyl O-(2,4,5-trichlorophenyl) ester

CAS REGISTRY NUMBER :
299-84-3

BEILSTEIN REFERENCE NO. :
1885571

LAST UPDATED :
199712

DATA ITEMS CITED :
55

MOLECULAR FORMULA :
C8-H8-Cl3-O3-P-S

MOLECULAR WEIGHT :
321.54

WISWESSER LINE NOTATION :
GR BG DG EOPS&O1&O1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
625 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
2 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
2823 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Subcutaneous

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
1380 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
2 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
118 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Mammal - dog

DOSE/DURATION :
500 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rabbit

DOSE/DURATION :
420 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - rabbit

DOSE/DURATION :
1 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - guinea pig

DOSE/DURATION :
1400 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - guinea pig

DOSE/DURATION :
2 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Bird - chicken

DOSE/DURATION :
6375 mg/kg

TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Subcutaneous

SPECIES OBSERVED :
Bird - chicken

DOSE/DURATION :
>1600 mg/kg

TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage)

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Bird - duck

DOSE/DURATION :
3500 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Bird - turkey

DOSE/DURATION :
500 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Mammal - domestic

DOSE/DURATION :
1 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Unreported

SPECIES OBSERVED :
Mammal - species unspecified

DOSE/DURATION :
400 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Bird - wild bird species

DOSE/DURATION :
80 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
350 mg/kg/14D-I

TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Mammal - dog

DOSE/DURATION :
5940 mg/kg/2Y-C

TOXIC EFFECTS :
Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
368 mg/kg

SEX/DURATION :
female 16-22 day(s) after conception

TOXIC EFFECTS :
Reproductive - Effects on Newborn - biochemical and metabolic

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
6 gm/kg

SEX/DURATION :
female 6-15 day(s) after conception

TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
650 mg/kg

SEX/DURATION :
female 6-18 day(s) after conception

TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
162 mg/kg

SEX/DURATION :
female 6-18 day(s) after conception

TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - other developmental abnormalities

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
2100 mg/kg

SEX/DURATION :
female 30-50 day(s) after conception

TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) Reproductive - Specific Developmental Abnormalities - musculoskeletal system

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
2100 mg/kg

SEX/DURATION :
female 30-50 day(s) after conception

TOXIC EFFECTS :
Reproductive - Effects on Newborn - live birth index (measured after birth) Reproductive - Effects on Newborn - sex ratio
MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange

TEST SYSTEM :
Human Lymphocyte

REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 102,89,1982 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 10 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW AQMOAC Air Quality Monographs. (Washington, DC) No.69-1 - No.75-25, 1969-75(?). Discontinued. Volume(issue)/page/year: #73-19,1973 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 46,1,1973 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 63,1,1976 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 10 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,222,1971 OSHA PEL (Gen Indu):8H TWA 15 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 10 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 10 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 15 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 10 mg/m3 JAN 1993 OEL-BELGIUM:TWA 10 mg/m3 JAN 1993 OEL-DENMARK:TWA 5 mg/m3 JAN 1993 OEL-FRANCE:TWA 10 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 10 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 10 mg/m3 JAN 1993 OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 10 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 10 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO RONNEL-air:10H TWA 10 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 67525 No. of Facilities: 86 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 383 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 67525 No. of Facilities: 333 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 3824 (estimated) No. of Female Employees: 574 (estimated)

毒理学数据：

二、毒理学数据：
低毒，半数致死量：1740 mg/kg(大鼠经口)；

生态数据：

三、生态学数据：
1、其它有害作用：该物质对环境有危害，不要让该物质进入环境。。

皮蝇磷 MSDS

第一部分：化学品名称

皮蝇磷分子结构与计算化学数据

分子结构数据

1、   摩尔折射率：69.87
2、   摩尔体积（cm³/mol）：210.5
3、   等张比容（90.2K）：564.2
4、   表面张力（dyne/cm）：51.5
5、   极化率（10^-24cm³）：27.69

计算化学数据

1.疏水参数计算参考值（XlogP）:无
2.氢键供体数量:0
3.氢键受体数量:4
4.可旋转化学键数量:4
5.互变异构体数量:无
6.拓扑分子极性表面积59.8
7.重原子数量:16
8.表面电荷:0
9.复杂度:273
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:1

皮蝇磷上游产品

2,4,5-三氯苯酚氯代亚磷酸二甲酯杀螟硫磷甲基对硫磷异氯磷

皮蝇磷下游产品

O,O,O-三甲基巯基磷酸酯 2,4,5-三氯苯酚杀螟硫磷

皮蝇磷表征图谱

皮蝇磷质谱(MS)

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皮蝇磷

皮蝇磷 制备方法及用途

制备方法

合成制备方法

用途简介

用途

皮蝇磷 物化性质

皮蝇磷 安全信息

皮蝇磷 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

皮蝇磷 MSDS

皮蝇磷 分子结构与计算化学数据

分子结构数据

计算化学数据

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皮蝇磷安全信息

皮蝇磷毒理性

皮蝇磷分子结构与计算化学数据

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