制备方法

本品属性能优良的胺类抗氧剂，在多种石油产品中起到优异的抗氧化效果。具有优异的自由基和脱硫性能。广泛应用于矿物油、加氢油、合成油和植物油等。

用途简介

包装等级：

III

风险类别：

第8.2类碱性腐蚀品(国内暂不属于危险化学品范畴)

海关代码：

2921519090

WGK_Germany：

3
德国有关水污染物质的分类清单

危险类别码：

R25;R34;R43;R50/53

安全说明：

S26-S36/37/39-S45-S61

RTECS号：

SS9040000

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
S61:避免排放到环境中。参考专门的说明/安全数据表。
:

危险标志：

C:Corrosive

CHEMICAL IDENTIFICATION

RTECS NUMBER :

SS9040000

CHEMICAL NAME :

p-Phenylenediamine, N,N'-di-sec-butyl-

CAS REGISTRY NUMBER :

101-96-2

BEILSTEIN REFERENCE NO. :

2805827

LAST UPDATED :

199801

DATA ITEMS CITED :

10

MOLECULAR FORMULA :

C14-H24-N2

MOLECULAR WEIGHT :

220.40

WISWESSER LINE NOTATION :

2Y1&MR DMY2&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010 ** ACUTE TOXICITY DATA **

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

148 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes in urine composition

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :

LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

600 mg/m3/6H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

2806 mg/kg

TOXIC EFFECTS :

Behavioral - tremor Kidney, Ureter, Bladder - other changes in urine composition Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - guinea pig

DOSE/DURATION :

5 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928- Volume(issue)/page/year: 45,627,1972

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

10 mL/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6950 No. of Facilities: 184 (estimated) No. of Industries: 3 No. of Occupations: 11 No. of Employees: 9196 (estimated) No. of Female Employees: 257 (estimated)

毒理学数据：

1、皮肤/眼睛刺激性：标准德来塞实验：兔子皮肤接触，500μL/24HREACTION SEVERITY，强烈反应；

中国海关编码：2921519090

概述：

2921519090. 间-、对-苯二胺、二氨基甲苯等〔包括衍生物及它们的盐〕. 增值税率:17.0%. 退税率:17.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

摘要/Summary：

2921519090. o-, m-, p-phenylenediamine, diaminotoluenes, and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

分子结构数据

1、   摩尔折射率：73.18

2、   摩尔体积（cm³/mol）：228.1

3、   等张比容（90.2K）：558.5

4、   表面张力（dyne/cm）：35.9

5、   介电常数：

6、   偶极距（10^-24cm³）：

7、   极化率：29.01

计算化学数据

1.疏水参数计算参考值（XlogP）:4.5

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:6

5.互变异构体数量:无

6.拓扑分子极性表面积24.1

7.重原子数量:16

8.表面电荷:0

9.复杂度:154

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:2

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

• 
  N
• 
  N'-二仲丁基苯二胺红外图谱(IR1)
• 
  N
• 
  N'-二仲丁基苯二胺核磁图(¹HNMR)