左旋-3-溴樟脑-8-磺酸铵盐,55870-50-3，生产厂家，价格-洛克化工网移动版

左旋-3-溴樟脑-8-磺酸铵盐

中文名称：: 左旋-3-溴樟脑-8-磺酸铵盐

中文别名：: 左旋-3-溴樟脑-8-磺酸铵盐;
L(-)-alpha-溴樟脑-pi-磺酸胺;
(-)-3-溴代莰酮-8-磺酸铵盐;
3-溴樟脑磺酸;
L(-)-Α-溴樟脑-PI-磺酸胺;
(-)-3-溴代樟脑-8-磺酸铵盐

英文名称：: Ammonium (-)-3-bromo-8-camphorsulfonate

英文别名：: Ammonium (-)-3-bromo-8-camphorsulfonate;
L-(-)-Alpha-Bromocamphor-8-sulfonic Acid Ammonium Salt;
L-(-)-a-Bromocamphor-8-sulfonic Acid Ammonium Salt;
(-)-Ammonium 3-bromocamphor-8-sulfonate;
ammonium L-5-bromo-6-oxo-9-bornanesulphonate;
3-Bromocamphorsulfonic acid;
((1S)-(endo,anti))-(-)-3-bromocamphor-8-sulfonic;
(-)-3-BROMOCAMPHOR-8-SULFONIC ACID AMMONIUM SALT;
[(1R)-(endo,anti)]-(+)-3-bromocamphor-8-sulfonate;
Ammonium ((1S,3R,4R,7S)-3-bromo-1,7-dimethyl-2-oxobicyclo[2.2.1]heptan-7-yl)methanesulfonate;
(1R)-3endo-bromo-2-oxo-bornane-8-sulfonic acid,ammonium salt;
(1R)-3endo-Brom-2-oxo-bornan-8-sulfonsaeure,Ammonium-Salz;
L-(-)-3-BROMOCAMPHOR 8-SULFONIC ACID,AMMONIUM SALT

CAS No.：: 55870-50-3

分子式：: C₁₀H₁₈BrNO₄S

分子量：: 328.22

精确分子量：: 327.01400

PSA：: 83.06000

EINECS：: 259-871-2

InChI：: InChI=1/C10H15BrO4S.H3N/c1-9-4-3-6(7(11)8(9)12)10(9,2)5-16(13,14)15;/h6-7H,3-5H2,1-2H3,(H,13,14,15);1H3/t6-,7+,9+,10?;/m0./s13

危险品标志：: Xi:Irritant

风险术语：: R36/37/38;

安全术语：: S26; S37/39;

分子结构式：

SDS：: 查看

左旋-3-溴樟脑-8-磺酸铵盐制备方法及用途

制备方法

用于化学中间体的拆分

用途简介

用途

用于化学中间体的拆分

左旋-3-溴樟脑-8-磺酸铵盐物化性质

外观与性状：: 白色至灰白色结晶粉末或针状
熔点：: 290 °C
沸点：: 477.5ºC at 760 mmHg
存储条件/存储方法：: 密闭于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：白色结晶性粉末

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：290

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

左旋-3-溴樟脑-8-磺酸铵盐安全信息

海关代码：: 2914700090
危险类别码：: R36/37/38
安全说明：: S37/39-S26-S36
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
:
危险标志：: Xi:Irritant;

左旋-3-溴樟脑-8-磺酸铵盐毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

左旋-3-溴樟脑-8-磺酸铵盐 MSDS

Name:	L-(-)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt 99% Material Safety Data Sheet
Synonym:	None Known
CAS:	55870-50-3

Section 1 - Chemical Product MSDS Name:L-(-)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt 99% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
55870-50-3	L-(-)-Alpha-Bromocamphor-Pi-Sulfonic	99%	259-871-2

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 55870-50-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 280.00 - 285.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H18BrNO4S
Molecular Weight: 328.21

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 55870-50-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
L-(-)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 55870-50-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 55870-50-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 55870-50-3 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

左旋-3-溴樟脑-8-磺酸铵盐海关数据

中国海关编码：2914700090

概述：: 2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%
申报要素：: 品名, 成分含量, 用途, 丙酮报明包装
摘要/Summary：: HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

左旋-3-溴樟脑-8-磺酸铵盐分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:4

4.可旋转化学键数量:1

5.互变异构体数量:2

6.拓扑分子极性表面积83.6

7.重原子数量:17

8.表面电荷:0

9.复杂度:427

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:4

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2