酸性黑1,1064-48-8，生产厂家，价格-洛克化工网移动版

酸性黑1

中文名称：: 酸性黑1

中文别名：: 酸性黑 1;
萘酚蓝;
萘黑10B;
酸性黑1/氨基黑10B;
酸性黑1;
氨基黑10B

英文名称：: Acid Black 1

英文别名：: 2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[2-(4-nitrophenyl)diazenyl]-6-(2-phenyldiazenyl)-, sodium salt (1:2);
2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[(4-nitrophenyl)azo]-6-(phenylazo)-, disodium salt (9CI);
Amido Black 10B (6CI);
C.I. Acid Black 1 (7CI);
C.I. Acid Black 1, disodium salt (8CI);
Acid Black 1;
Acid Black 10A;
Acid Black 10B;
Acid Black 10BA;
Acid Black 10BN;
Acid Black 10BX;
Acid Black 12B;
Acid Black 4BN;
Acid Black 4BNU;
Acid Black 8GB;
Acid Black BRX;
Acid Black BX;
Acid Black Base M;
Acid Black H;
Acid Black JVS;
Acid Blue Black;
Acid Blue Black 10B;
Acid Blue Black 10BX;
Acid Blue Black B;
Acid Blue Black BG;
Acid Blue Black Double 600;
Acid Blue Black Sh;
Acid Leather Blue IGW;
Acid Leather Dark Blue G;
Acid Leather Fast Blue Black G;
Acidal Black 10B;
Acidal Black MV;
Acidal Navy Blue 3BR;
Aciderm Black E 10B;
Acilan Black 10B;
Airedale Black 2BG;
Amacid Black 10BR;
Amide Black 10B;
Amido Black;
Amido Blue Black 12B;
Apollo Acid Blue Black 10B;
Atul Acid Black 10BX;
Atul Acid Black BX;
Azanol Fast Acid Black 10B;
Azo Dark Blue C 2B;
Azo Dark Blue HR;
Azo Dark Blue S;
Azo Dark Blue SH;
BTK Black 10BX;
Best Acid Dark Blue B;
Black 401;
Black No. 401;
Blue Black 12B;
Blue Black SX;
Borunil Grey A 10B;
Boruta Black A;
Brasilan Black BS;
Brysoap Black 10B;
Bucacid Blue Black;
Buffalo Black NBR;
C.I. 20470;
Calcocid Blue Black;
Calcocid Blue Black 2R;
Colacid Black 10A;
Colocid Black 10BX;
Colorosacid Blue Black;
Comacid Blue Black B;
Conacid Black A;
Concorde Leather Blue TB;
Covalene Blue Black 6BN;
D & C Black 1;
D and C Black No. 1;
Daedo Acid Black 10BN;
Dermacid Blue G;
Diacid Blue Black 10B;
Dinacid Black 10BX;
Dyacid Bla

CAS No.：: 1064-48-8

分子式：: C₂₂H₁₄N₆Na₂O₉S₂

分子量：: 616.49

精确分子量：: 618.02156

PSA：: 272.67000

MDL：: MFCD00004017

EINECS：: 213-903-1

BRN：: 5374263

InChI：: InChI=1/C22H16N6O9S2.2Na/c23-19-18-12(11-17(39(35,36)37)21(22(18)29)27-24-13-4-2-1-3-5-13)10-16(38(32,33)34)20(19)26-25-14-6-8-15(9-7-14)28(30)31;;/h1-11,24H,23H2,(H,32,33,34)(H,35,36,37);;/q;2*+1/p-2/b26-25+,27-21+;;3

危险品标志：: Xn:Harmful

风险术语：: R20/21; R33;

安全术语：: S26;S37/39

分子结构式：

SDS：: 查看

酸性黑1 制备方法及用途

制备方法

以 H 酸、对硝基苯胺、苯胺为原料,首先将对硝基苯胺重氮化,于酸性条件下与 H 酸偶合,然后将苯胺重氮化,于碱性条件下与前述偶合产物进行第二次偶合即得产物。经盐析、过滤、干燥、粉碎得成品。。

合成制备方法

1.对硝基苯胺重氮化,与H酸偶合得单偶氮化合物.将苯胺重氮化,与上述单偶化合物偶合而得原料消耗(kg/t)H酸（100%） 240 亚硝酸钠 107对硝基苯胺（100%） 110 碳酸钠（98%） 192苯胺（99%） 66 氢氧化钠（100%）83 .

以 H 酸、对硝基苯胺、苯胺为原料，首先将对硝基苯胺重氮化，于酸性条件下与 H 酸偶合，然后将苯胺重氮化，于碱性条件下与前述偶合产物进行第二次偶合即得产物。经盐析、过滤、干燥、粉碎得成品。

用途简介

主要用于羊毛、蚕丝、锦纶及其混纺织物的染色和印花,也可用于拼色

用途

1.酸性黑 10B 主要用于羊毛、蚕丝、锦纶及其混纺织物的染色和直接印花。匀染性较差。可与酸性橙 II (C.I.Acid Orange 7) 拼混成酸性黑 ATT，用途广泛。也用于皮革、纸张、肥皂、木制品、生物、医药、化妆品的着色和制造墨水。

2.色谱分析员试剂，生物染色剂，氧化还原指示剂。

酸性黑1 物化性质

外观与性状：: 暗红色至黑色粉末
密度：: 1.05 g/mL at 20 °C
闪点：: 30 °C
水溶解性：: 10 G/L (25 ºC)
存储条件/存储方法：: 1.密封干燥保存。
稳定性相关：: 1.常温常压下稳定，避免氧化物接触
2.水溶液加浓盐酸生成绿光蓝色沉淀；加氢氧化钠溶液生成蓝色沉淀
3.避免吸入本品的粉尘，避免了与眼睛及皮肤接触。
其它信息：: 1. 性状：黑褐色粉末。
2. 密度（g/mL,20℃）： 1.05

酸性黑1 安全信息

海关代码：: 3204120000
WGK_Germany：: 3
德国有关水污染物质的分类清单
危险类别码：: R36/37/38
安全说明：: 26-36-37/39-45-36/37/39-23-16
RTECS号：: QJ6196000
危险标志：: Xi:Irritant

酸性黑1 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QJ6196000

CHEMICAL NAME :: 2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-((4-nitrophenyl)azo)-6-(phenylazo )-, disodium salt

CAS REGISTRY NUMBER :: 1064-48-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C22-H16-N6-O9-S2.2Na

MOLECULAR WEIGHT :: 618.54

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 50 ug/plate

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 22,188,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81698 No. of Facilities: 591 (estimated) No. of Industries: 10 No. of Occupations: 23 No. of Employees: 6615 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81698 No. of Facilities: 1816 (estimated) No. of Industries: 20 No. of Occupations: 45 No. of Employees: 51898 (estimated) No. of Female Employees: 26897 (estimated)

生态数据：

对水是稍微有害的，不要让未稀释或大量的产品接触地下水，水道或者污水系统，若无政府许可，勿将材料排入周围环境储存

酸性黑1 MSDS

Name:	Acid Black 1 Material Safety Data Sheet
Synonym:	Naphthol blue black; Amido Schwarz
CAS:	1064-48-8

Section 1 - Chemical Product MSDS Name:Acid Black 1 Material Safety Data Sheet
Synonym:Naphthol blue black; Amido Schwarz

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1064-48-8	C.I. Acid Black	100.0%	213-903-1

Hazard Symbols: XN
Risk Phrases: 20/21 33

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin. Danger of cumulative effects.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Wash clothing before reuse. Flush skin with plenty of soap and water.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid contact with eyes. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1064-48-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: black
Odor: Not available
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C22H14N6O9S2Na2
Molecular Weight: 616.48

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, none reported, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of sulfur, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1064-48-8: QJ6196000 LD50/LC50:
Not available.
Carcinogenicity:
C.I. Acid Black - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1064-48-8: 1
Canada
CAS# 1064-48-8 is listed on Canada's DSL List.
CAS# 1064-48-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1064-48-8 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

酸性黑1 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：616.005906 Da

8、标称质量：616 Da

9、平均质量：616.4909 Da

计算化学数据

1、氢键供体数量：2

2、氢键受体数量：14

3、可旋转化学键数量：4

4、互变异构体数量：26

5、拓扑分子极性表面积（TPSA）：250

6、重原子数量：41

7、表面电荷：0

8、复杂度：1230

9、同位素原子数量：0

10、确定原子立构中心数量：0

11、不确定原子立构中心数量：0

12、确定化学键立构中心数量：1

13、不确定化学键立构中心数量：0

14、共价键单元数量：3

酸性黑1 下游产品

甲酸草酸乙酸

酸性黑1

酸性黑1 制备方法及用途

制备方法

合成制备方法

用途简介

用途

酸性黑1 物化性质

酸性黑1 安全信息

酸性黑1 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

酸性黑1 MSDS

酸性黑1 分子结构与计算化学数据

分子结构数据

计算化学数据

酸性黑1 下游产品

酸性黑1 表征图谱

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