N-苯甲基-N-苯肼盐酸盐,5705-15-7，生产厂家，价格-洛克化工网移动版

N-苯甲基-N-苯肼盐酸盐

中文名称：: N-苯甲基-N-苯肼盐酸盐

中文别名：: N-苯甲基-N-苯肼盐酸盐;
N-苄基-N-苯肼盐酸盐;
1-苄基-1-苯肼盐酸盐

英文名称：: Hydrazine,1-phenyl-1-(phenylmethyl)-, hydrochloride (1:1)

英文别名：: 1-BENZYL-1-PHENYLHYDRAZINE HYDROCHLORIDE;
1-benzyl-1-phenylhydrazine,hydrochloride

CAS No.：: 5705-15-7

分子式：: C₁₃H₁₄N₂.ClH

分子量：: 157.60

精确分子量：: 234.09200

PSA：: 29.26000

MDL：: MFCD00050690

EINECS：: 227-195-7

BRN：: 3707186

InChI：: InChI=1/C31H33ClN2O3S/c1-30(2)18-23(13-16-37-30)34-28(36)26-27(24-8-4-3-7-21(24)17-31(26)14-5-6-15-31)33-29(34)38-19-25(35)20-9-11-22(32)12-10-20/h3-4,7-12,23H,5-6,13-19H2,1-2H33

风险术语：: R36/37/38;

安全术语：: S26; S36;

分子结构式：

SDS：: 查看

N-苯甲基-N-苯肼盐酸盐制备方法及用途

制备方法

有机合成。

用途简介

用途

有机合成。

N-苯甲基-N-苯肼盐酸盐物化性质

密度：: 1.13 g/cm3
熔点：: 178-181°C
沸点：: 346.6ºC at 760 mmHg
闪点：: 186.3ºC
折射率：: 1.672
存储条件/存储方法：: 本品应密封避光保存。
稳定性相关：: 常温常压下稳定，针状结晶。熔点170℃。
其它信息：: 1.       性状：针状结晶。

2.       密度（g/mL,25/4℃）：未确定

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：170

5.       沸点（ºC,常压）：未确定

6.       沸点（ºC,5.2kPa）：未确定

7.       折射率：未确定

8.       闪点（ºC）：未确定

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（kPa,25ºC）：未确定

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.    溶解性：未确定。

N-苯甲基-N-苯肼盐酸盐安全信息

海关代码：: 2928000090
危险类别码：: R36/37/38
安全说明：: S26-S36/37/39
RTECS号：: MU9800000
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

N-苯甲基-N-苯肼盐酸盐毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MU9800000

CHEMICAL NAME :: Hydrazine, 1-benzyl-1-phenyl-, hydrochloride

CAS REGISTRY NUMBER :: 5705-15-7

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C13-H14-N2.Cl-H

MOLECULAR WEIGHT :: 234.75

WISWESSER LINE NOTATION :: ZNR&1R &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 404 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABMGAJ Acta Biologica et Medica Germanica. (Berlin, Ger. Dem. Rep.) V.1-41, 1958-82. For publisher information, see BBIADT. Volume(issue)/page/year: 18,617,1967

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 106 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABMGAJ Acta Biologica et Medica Germanica. (Berlin, Ger. Dem. Rep.) V.1-41, 1958-82. For publisher information, see BBIADT. Volume(issue)/page/year: 17,614,1966

毒理学数据：

1、急性毒性：

小鼠静脉LD50：106mg/kg，毒性作用的描述没有报告除此以外的其他致死剂量值。

生态数据：

该物质对环境可能有危害，对水体应给予特别注意

N-苯甲基-N-苯肼盐酸盐 MSDS

1-Benzyl-1-phenylhydrazine Hydrochloride Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: 1-Benzyl-1-phenylhydrazine Hydrochloride

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statement        Causes skin irritation
    Causes serious eye irritation
  Precautionary statements
  [Prevention]        Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Component(s):        1-Benzyl-1-phenylhydrazine Hydrochloride
  Percent:        >98.0%(T)
  CAS Number:        5705-15-7
  Chemical Formula:        C13H14N2·HCl

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  1-Benzyl-1-phenylhydrazine Hydrochloride

Section 4. FIRST AID MEASURES
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.
  Storage
    Keep container tightly closed. Store in a cool and dark place.
  Storage conditions:
    Store away from incompatible materials such as oxidizing agents.
    Law is followed.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        crystal - powder
  Color:        White - Very pale yellow
  Odor:        No data available
  pH: No data available
  Melting point/freezing point:176 °C
  Boiling Point/Range:        No data available
  1-Benzyl-1-phenylhydrazine Hydrochloride

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Flash Point:        No data available
  Explosive limits
  Lower:        No data available
    No data available
  Upper:
  Density:        No data available
    No data available
  Solubility:

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
  Reactivity:        No special reactivity has been reported.
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen chloride
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        ipr-rat LD50:404 mg/kg
    ivn-mus LD50:106 mg/kg
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available
    No data available
  Reproductive toxicity:
  RTECS Number:        MU9800000

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not Listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.
  1-Benzyl-1-phenylhydrazine Hydrochloride

SECTION 16 - ADDITIONAL INFORMATION
N/A

N-苯甲基-N-苯肼盐酸盐海关数据

中国海关编码：2928000090

概述：: 2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素：: 品名, 成分含量, 用途
摘要/Summary：: 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

N-苯甲基-N-苯肼盐酸盐分子结构与计算化学数据

分子结构数据

1、摩尔折射率：63.95

2、摩尔体积（cm³/mol）：175.2

3、等张比容（90.2K）：470.6

4、表面张力（dyne/cm）：51.9

5、极化率（10-24cm3）：25.35

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:3

5.互变异构体数量:无

6.拓扑分子极性表面积29.3

7.重原子数量:16

8.表面电荷:0

9.复杂度:169

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2