海关代码：

29161910

WGK_Germany：

1
德国有关水污染物质的分类清单

危险类别码：

R36/38;R52/53

安全说明：

S26-S61-S37/39

RTECS号：

YQ2975000

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S61:避免排放到环境中。参考专门的说明/安全数据表。
:
S36:穿戴合适的防护服装。

危险标志：

Xi:Irritant;

CHEMICAL IDENTIFICATION

RTECS NUMBER :

YQ2975000

CHEMICAL NAME :

10-Undecenoic acid

CAS REGISTRY NUMBER :

112-38-9

BEILSTEIN REFERENCE NO. :

1762631

LAST UPDATED :

199803

DATA ITEMS CITED :

11

MOLECULAR FORMULA :

C11-H20-O2

MOLECULAR WEIGHT :

184.31

WISWESSER LINE NOTATION :

QV9U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,883,1978 ** ACUTE TOXICITY DATA **

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

2500 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 4,386,1969

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

8150 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle contraction or spasticity

REFERENCE :

JIDEAE Journal of Investigative Dermatology. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1938- Volume(issue)/page/year: 13,145,1949

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

960 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

JIDEAE Journal of Investigative Dermatology. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1938- Volume(issue)/page/year: 13,145,1949

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - guinea pig

DOSE/DURATION :

50 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4954,1982 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

140 gm/kg/8W-C

TOXIC EFFECTS :

Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :

JIDEAE Journal of Investigative Dermatology. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1938- Volume(issue)/page/year: 13,145,1949 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0625 No. of Facilities: 369 (estimated) No. of Industries: 6 No. of Occupations: 7 No. of Employees: 7037 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0625 No. of Facilities: 45 (estimated) No. of Industries: 6 No. of Occupations: 8 No. of Employees: 10243 (estimated) No. of Female Employees: 8109 (estimated)

毒理学数据：

急性毒性：

口腔     LD50    8150mg/kg(mus)

                 2500mg/kg(rat)

刺激皮肤  severe 500mg/24H(rbt)

主要的刺激性影响：

在皮肤上面:刺激皮肤和黏膜。

在眼睛上面:刺激的影响。

致敏作用：没有已知的敏化作用。

生态数据：

总括注解

通常来说对水是不危害的

若无政府许可，勿将材料排入周围环境。

分子结构数据

1、   摩尔折射率：54.63

2、   摩尔体积（cm³/mol）：198.3

3、   等张比容（90.2K）：478.7

4、   表面张力（dyne/cm）：33.9

5、   极化率（10^-24cm³）：21.65

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:2

4.可旋转化学键数量:9

5.互变异构体数量:无

6.拓扑分子极性表面积37.3

7.重原子数量:13

8.表面电荷:0

9.复杂度:141

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

• 
  10-十一烯酸核磁图(¹³CNMR)
• 
  10-十一烯酸质谱(MS)
• 
  10-十一烯酸红外图谱(IR3)
• 
  10-十一烯酸红外图谱(IR2)
• 
  10-十一烯酸红外图谱(IR1)