丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃),9003-56-9，生产厂家，价格-洛克化工网移动版

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基本信息

制备方法及用途

物化性质

安全信息

毒理性

MSDS

结构与计算化学

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃)

中文名称：: 丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃)

中文别名：: 聚(丙烯腈-co-丁二烯-co-苯乙烯);
丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃)

英文名称：: Acrylonitrile-butadiene-styrene terpolymer,flame retarding

英文别名：: 2-Propenenitrile, polymer with 1,3-butadiene and ethenylbenzene;
Acrylonitrile, polymer with 1,3-butadiene and styrene (8CI);
Acrylonitrile, polymer with butadiene and styrene (6CI);
1,3-Butadiene polymer, with acrylonitrile and styrene (6CI);
1,3-Butadiene, polymer with ethenylbenzene and 2-propenenitrile (9CI);
Benzene, ethenyl-, polymer with 1,3-butadiene and 2-propenenitrile (9CI);
Styrene, polymer with acrylonitrile and 1,3-butadiene (8CI);
Styrene, polymer with acrylonitrile and butadiene (6CI);
0215A;
06-10A;
1,3-Butadiene-acrylonitrile-styrene copolymer;
1,3-Butadiene-styrene-acrylonitrile copolymer;
10JK2;
121H0013;
15A1;
15NP;
2020AST;
2501K;
250X10;
3001M;
3001MG2A;
300SF;
301K;
342EZ;
429J;
450Y-X10;
480S;
60P;
660SF;
700X01;
707K;
747K;
747S;
749SK;
750A;
750N;
750NSW;
750SW;
756H;
757K;
759A;
8391A;
8586K24;
88K4;
9715A;
9738R;
975BK1;
9815A;
A 201;
A 201 (styrene polymer);
A 402;
A 404;
A 404 (polymer);
A 4571S27;
A 50B;
AB 303300;
ABS;
ABS (polymer);
ABS 0215A;
ABS 1;
ABS 10;
ABS 101;
ABS 12;
ABS 121;
ABS 121H;
ABS 130;
ABS 150;
ABS 170;
ABS 180;
ABS 181;
ABS 200NT;
ABS 2020;
ABS 2501K;
ABS 3453;
ABS 350;
ABS 3513;
ABS 380;
ABS 4;
ABS 400;
ABS 4134;
ABS 433;
ABS 50;
ABS 547P;
ABS 55;
ABS 5503;
ABS 556/499;
ABS 55NP;
ABS 60;
ABS 606;
ABS 60P;
ABS 660;
ABS 680;
ABS 6MI;
ABS 705;
ABS 707;
ABS 720;
ABS 728;
ABS 740;
ABS 746;
ABS 747;
ABS 750;
ABS 750SW;
ABS 757;
ABS 757K;
ABS 758;
ABS 775;
ABS 780;
ABS 8384;
ABS 8391;
ABS 8434;
ABS 8504;
ABS 900;
ABS 9030;
ABS 920;
ABS 9332;
ABS 9555;
ABS 9815;

CAS No.：: 9003-56-9

分子式：: C₄₅H₅₁N₃X₂

分子量：: 211.30200

精确分子量：: 211.13610

PSA：: 23.79000

MDL：: MFCD00133993

InChI：: InChI=1/C8H8.C4H6.C3H3N/c1-2-8-6-4-3-5-7-8;1-3-4-2;1-2-3-4/h2-7H,1H2;3-4H,1-2H2;2H,1H23

危险品标志：: Xn:有害物质

风险术语：: R20/21/22;

安全术语：: S36;

分子结构式：

SDS：: 查看

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) 制备方法及用途

制备方法

用作汽车工业材料、建筑材料、木材代用品, 并用于制安全帽、旅行箱、用具壳体、泡沫塑料等

合成制备方法

典型的乳液接枝掺混法ABS生产工艺　流程如下。

丙烯腈的用量20%～30%，丁二烯6%～35%，苯乙烯45%～70%。聚合温度约为50～100℃，接枝温度为60～90℃，凝聚时温度为85～95℃。

2.连续本体法ABS树脂生产工艺过程　将增韧橡胶溶于单体和少量溶剂中进行接枝聚合，随着聚合反应的进行，形成溶解于单体中的接枝橡胶和SAN两个独立相溶液。由于聚合反应的进一步加深，发生相转变，SAN成为连续相，橡胶粒子形成并分离出来，分散在SAN相中。通过相转变获得适当的橡胶粒径和界面相容性。反应后期，进行适度交联以增加橡胶粒子的强度，然后脱挥、造粒，得到ABS树脂产品。连续本体法ABS生产工艺程如下：

ＡＢＳ树脂的合成工艺大致可以分为混炼法和接枝共聚法两种。接枝共聚法可以分为不均匀接枝法和均匀接枝法。不均匀接枝法通常指乳液聚合法，而均匀接枝法则包括本体聚合、悬浮聚合和本体悬浮聚合等方法

用途简介

用途

1.用作汽车工业材料、建筑材料、木材代用品，并用于制安全帽、旅行箱、用具壳体、泡沫塑料等
2.用于配制溶剂型胶黏剂，粘接聚苯乙烯类塑料。ＡＢＳ树脂以较高的抗冲击强度、耐化学药品性、电性能和良好的加工性能、电镀性能，被广泛用于汽车工业、电子电气工业、办公机器及建筑管材等领域，近年来得到较快的发展。通过共混、共聚、填充、增强等改性技术，可赋予ABS树脂高性能和特殊功能，如将ＡＳ基料树脂中的苯乙烯的一部分或全部以苯基马来酰亚胺置换，可得到高耐热性树脂；将ＡＢＳ树脂中的丙烯腈含量提高或加入甲基丙烯酸甲酯单体，可得到耐化学药品性树脂；在ＡＢＳ树脂中掺入聚氯乙烯树脂或添加溴系阻燃剂，可提高其阻燃性；将ＡＢＳ树脂中的丁二烯橡胶组分用不含双键的丙烯酸酯橡胶或三元乙丙橡胶代替，可解决耐候性的问题；通过掺入无机或有机抗菌剂，能得到抗菌性树脂；值得一提的是，为了改善ABS树脂的耐热性、耐冲击性、耐化学药品等性能

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) 物化性质

外观与性状：
白色

密度：
1.05 g/mL at 25ºC

熔点：
58.54（±0.5）ºC

沸点：
145.2ºC at 760 mmHg

闪点：
31.1°C

水溶解性：
acetone, MEK and DMF: soluble

存储条件/存储方法：
库房通风低温干燥

稳定性相关：

遵照规定使用和储存则不会分解。

其它信息：

1.       性状：微黄色
2.       密度（g/mL,25/4℃）：1.05
3.       相对蒸汽密度（g/mL,空气=1）：无可用
4.       熔点（ºC）：58.54（±0.5）℃
5.       沸点（ºC,常压）：无可用
6.       沸点（ºC,5.2kPa）：无可用
7.       折射率：无可用
8.       闪点（ºC）：无可用
9.       比旋光度（º）：无可用
10.    自燃点或引燃温度（ºC）：无可用
11.    蒸气压（kPa,25ºC）：无可用
12.    饱和蒸气压（kPa,60ºC）：无可用
13.    燃烧热（KJ/mol）：无可用
14.    临界温度（ºC）：无可用
15.    临界压力（KPa）：无可用
16.    油水（辛醇/水）分配系数的对数值：无可用
17.    爆炸上限（%,V/V）：无可用
18.    爆炸下限（%,V/V）：无可用
19.    溶解性：溶于冷水，其水溶液呈酸性。

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) 安全信息

危险类别码：
R20/21/22;R36/37/38

安全说明：
S36-S26

危险标志：
Xn

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AT6970000

CHEMICAL NAME :
Acrylonitrile, polymer with 1,3-butadiene and styrene

CAS REGISTRY NUMBER :
9003-56-9

LAST UPDATED :
199710

DATA ITEMS CITED :
7

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) MSDS

Name: Poly(acrylonitrile-co-butadiene-co-styrene) Material Safety Data Sheet

Synonym: 2-Propenitrile, polymer with 1,3-butadiene and ethenylbenzene

CAS: 9003-56-9

Section 1 - Chemical Product MSDS Name:Poly(acrylonitrile-co-butadiene-co-styrene) Material Safety Data Sheet
Synonym:2-Propenitrile, polymer with 1,3-butadiene and ethenylbenzene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS# Chemical Name content EINECS#

9003-56-9 Poly(acrylonitrile-butadiene-styrene) 100 unlisted

Hazard Symbols: T
Risk Phrases: 20/21/22 45

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. May cause cancer.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Forms smooth, slippery surfaces on floors, posing an accident risk.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 9003-56-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C15H17N1x
Molecular Weight: 197.119

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 9003-56-9: AT6970000 LD50/LC50:
Not available.
Carcinogenicity:
Poly(acrylonitrile-butadiene-styrene) - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 9003-56-9: No information available.
Canada
CAS# 9003-56-9 is listed on Canada's DSL List.
CAS# 9003-56-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 9003-56-9 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用
2、   摩尔体积（cm³/mol）：无可用
3、   等张比容（90.2K）：无可用
4、   表面张力（dyne/cm）：无可用
5、   极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无
2.氢键供体数量:0
3.氢键受体数量:1
4.可旋转化学键数量:2
5.互变异构体数量:无
6.拓扑分子极性表面积23.8
7.重原子数量:16
8.表面电荷:0
9.复杂度:144
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:3

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Name:	Poly(acrylonitrile-co-butadiene-co-styrene) Material Safety Data Sheet
Synonym:	2-Propenitrile, polymer with 1,3-butadiene and ethenylbenzene
CAS:	9003-56-9

CAS#	Chemical Name	content	EINECS#
9003-56-9	Poly(acrylonitrile-butadiene-styrene)	100	unlisted