C.I.颜料红53：1,5160-02-1，生产厂家，价格-洛克化工网移动版

C.I.颜料红53：1

中文名称：: C.I.颜料红53：1

中文别名：: 金光红C;
C.I.颜料红53：1

英文名称：: Benzenesulfonic acid,5-chloro-2-[2-(2-hydroxy-1-naphthalenyl)diazenyl]-4-methyl-, barium salt (2:1)

英文别名：: Pigment Red 53:1;
cred9;
redlakec;
Toner;
D and C Red No. 9;
red1860;
1860red;
C.I. Pigment Red 9;
redzhb;
1-(4-Chloro-o-sulfo-5-tolylazo)-2-naphthol Barium Salt;
D and C red 9;
redno204;
AKA204;
Red 53:1

CAS No.：: 5160-02-1

分子式：: C₁₇H₁₃ClN₂O₄S.1/2Ba

分子量：: 888.94

精确分子量：: 887.94700

PSA：: 221.06000

EINECS：: 225-935-3

InChI：: InChI=1/2C17H13ClN2O4S.Ba/c2*1-10-8-14(16(9-13(10)18)25(22,23)24)19-20-17-12-5-3-2-4-11(12)6-7-15(17)21;/h2*2-9,21H,1H3,(H,22,23,24);/q;;+2/p-2/b2*20-19+;3

危险品标志：

风险术语：: R20/21/22

安全术语：: S22 S36/S37/S39

分子结构式：

SDS：: 查看

C.I.颜料红53：1 制备方法及用途

制备方法

CLT-酸加至盐酸水溶液中，搅拌过夜，次日降温，稀释，液面下加亚硝酸钠溶液重氮化，稀释备用；2-萘酚加至氢氧化钠水溶液中，使溶解，稀释，液面下加入重氮盐悬浮液偶合，搅拌，加入稀乙酸，过滤；将所得膏状物加水搅拌，稀释，再加入稀乙酸，使呈酸性，加入氯化钡沸腾液中，煮沸进行色沉淀化，过滤，干燥，得产品。

合成制备方法

在重氮桶放水2000L，加入拉开粉3kg，然后加入20%氨水50kg，再倒入CLT酸119kg，在搅拌下徐徐加入30%盐酸157kg，使CLT酸呈细态析出，加完续搅20min，温度10～12℃，体符号为500L，再加入亚硝酸钠36.7kg，温度14～15℃，溶液保持酸性，控制终点备偶合。
偶合桶中放水1000L，液碱108kg，升温至60℃，搅拌加入乙萘酚79.3kg使溶解，并调整体积至3500L，温度30℃左右，备用。
在良好搅拌下，快速把CLT酸重氮液放入偶合桶，终点pH值10～11温度28℃，继续反应1h，pH值逐渐降至7.5～8。加入13kg松香溶解的透明溶液，pH值为8.5～9。把116kg氧化钡溶解于一定体积中，加入到偶合桶中，总体积为8000～8500L，终点pH值8～8.5, 继续反应1h，快速升温至100℃，保温1h。过滤，滤饼80℃进行烘干。得量255kg。

用途简介

主要用于硝基墨，也可用于胶印墨，表印墨和里印墨。

用途

1.主要用于油墨、橡胶制品和自行车内胎的着色。也用于文教及塑料用品的着色。橡胶大红LC的结构与金光红C相同，但其合成工艺是偶合后直接制取钡盐色淀，产品为艳黄光大红色，质地松软，着色力强，耐热性好，不变色，无迁移性，主要用于橡胶、电缆和塑料制品的着色。

2.用于制造金光红色油墨，橡胶制品，还用于水彩颜料、蜡笔、铝笔等文教用品及塑料制品着色，适用于聚氯乙烯、丙烯酸树脂、酚醛树脂、氨基树脂等塑料。

C.I.颜料红53：1 物化性质

外观与性状：: 淡黄色-红色或微红的橙色粉末
密度：: 1.48g/cm3
熔点：: 343-345°C
水溶解性：: <0.01 g/100 mL at 18℃
存储条件/存储方法：: 库房低温,通风,干燥
稳定性相关：: 颜色鲜艳，显示强烈彩色金光，且金光又较为耐久牢固，制成的油墨流动性好，耐晒性和耐热性较好。遇浓硫酸呈樱桃红色，稀释后呈棕红色沉淀，微溶于10%热氢氧化钠（为黄色）、水和乙醇，不溶于丙酮和苯。
其它信息：: 1.       性状：红色带黄光的粉末
2.       密度（g/mL ,25/4℃）：不确定
3.       相对蒸汽密度（g/mL,空气=1）：不确定
4.       熔点（ºC）：343-345
5.       沸点（ºC,常压）：不确定
6.       沸点（ºC,2.5mmHg）：不确定
7.       折射率（nD20）：不确定
8.       闪点（ºF）：不确定
9.       比旋光度（º）：不确定
10.    自燃点或引燃温度（ºC）：不确定
11.    蒸气压（kPa,25ºC）：不确定
12.    饱和蒸气压（kPa,60ºC）：不确定
13.    燃烧热（KJ/mol）：不确定
14.    临界温度（ºC）：不确定
15.    临界压力（KPa）：不确定
16.    油水（辛醇/水）分配系数的对数值：不确定
17.    爆炸上限（%,V/V）：不确定
18.    爆炸下限（%,V/V）：不确定
19.    溶解性：微溶于水、乙醇和10%氢氧化钠热溶液，不溶于苯和丙酮

C.I.颜料红53：1 安全信息

危险类别码：: R20/21/22
安全说明：: S22-S36/37/39
RTECS号：: DB5500000
安全标志：: S22:不要吸入粉尘。
:

C.I.颜料红53：1 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DB5500000

CHEMICAL NAME :: Benzenesulfonic acid, 5-chloro-2-((2-hydroxy-1-naphthalenyl)azo)-4-methyl-, barium salt

CAS REGISTRY NUMBER :: 5160-02-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 17

MOLECULAR FORMULA :: C17-H12-Cl-N2-O4-S.1/2Ba

MOLECULAR WEIGHT :: 444.49

WISWESSER LINE NOTATION :: L66J BNUNR DG C FSWQ& CQ & 2-BA-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 27300 mg/kg/91D-C

TOXIC EFFECTS :: Liver - other changes Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 546 gm/kg/2Y-C

TOXIC EFFECTS :: Endocrine - changes in spleen weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 21 gm/kg/14D-C

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 130 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Blood - tumors

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 109 gm/kg/2Y-C

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Blood - tumors

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 1 mg/plate

REFERENCE :: SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 236,933,1987 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 8,107,1975 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 8,107,1975 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,203,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3849 No. of Facilities: 1160 (estimated) No. of Industries: 15 No. of Occupations: 21 No. of Employees: 14370 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3849 No. of Facilities: 8245 (estimated) No. of Industries: 43 No. of Occupations: 49 No. of Employees: 122313 (estimated) No. of Female Employees: 23095 (estimated)

生态数据：

可燃；火场分解有毒氮氧化物,，硫氧化物，氯化物和氧化钡烟雾。

C.I.颜料红53：1 MSDS

Lake Red CBA Revision number: 5
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Lake Red CBA

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 3
    Blood, Spleen
  Specific target organ toxicity
  - Repeated exposure [Category 2]
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger
  Hazard statements        Toxic if swallowed
    May cause damage to organs through prolonged or
    repeated exposure : Blood Spleen
  Precautionary statements:
    Do not breathe dust/fume/gas/mist/vapours/spray.
  [Prevention]
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
  [Response]        IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse
    mouth.
    Get medical advice/attention if you feel unwell.
    Store locked up.
  [Storage]
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        Lake Red CBA
  Percent:        ....
  CAS Number:        5160-02-1
    1-(4-Chloro-o-sulfo-5-tolylazo)-2-naphthol Barium Salt
  Synonyms:
  Chemical Formula:        C34H24BaCl2N4O8S2
  Lake Red CBA

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Immediately call a POISON CENTER or doctor/physician. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep
  protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
  emergency procedures: be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a local exhaust if dust or aerosol will be
    generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
    etc. Use respirators approved under appropriate government standards and follow
    local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.
  Lake Red CBA

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        Crystal- Powder
    Yellow red - Red
  Colour:
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:No data available
    No data available
  Boiling point/range:
  Flash point:        No data available
  Flammability or explosive
  limits:
    No data available
  Lower:
  Upper:        No data available
    No data available
  Relative density:
  Solubility(ies):
    Slightly soluble
  [Water]
  [Other solvents]
    Ethanol
  Slightly soluble:
  Insoluble:        Benzene, Acetone
    -0.49
  Log Pow:

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Sulfur oxides, Hydrogen
  products:        chloride

Section 11. TOXICOLOGICAL INFORMATION
    No data available
  Acute Toxicity:
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: mmo-sat 1 mg/plate (+S9)
  Carcinogenicity:
    Group 3 (Not classifiable as carcinogenic to humans)
  IARC =
  NTP =        No data available
    No data available
  Reproductive toxicity:
  RTECS Number:        DB5500000

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: 0% (by BOD)
  Bioaccumulative        0.9 - 1.8 (conc. 0.7 mg/L), 8.5 - 15 (conc. 0.07 mg/L)
  potential(BCF):
  Mobility in soil
  Log Pow:        -0.49
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):
  Lake Red CBA

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        6.1: Toxic substance.
  UN-No:        1564
  Proper shipping name:        Barium compound, n.o.s.
    III
  Packing group:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

C.I.颜料红53：1 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：887.946501Da

8、标称质量：888Da

9、平均质量：888.9394Da

计算化学数据

1、氢键供体数量：2

2、氢键受体数量：12

3、可旋转化学键数量：4

4、互变异构体数量：6

5、拓扑分子极性表面积（TPSA）：197

6、重原子数量：51

7、表面电荷：0

8、复杂度：672

9、同位素原子数量：0

10、确定原子立构中心数量：0

11、不确定原子立构中心数量：0

12、确定化学键立构中心数量：2

13、不确定化学键立构中心数量：0

14、共价键单元数量：3

C.I.颜料红53：1

C.I.颜料红53：1 制备方法及用途

制备方法

合成制备方法

用途简介

用途

C.I.颜料红53：1 物化性质

C.I.颜料红53：1 安全信息

C.I.颜料红53：1 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

C.I.颜料红53：1 MSDS

C.I.颜料红53：1 分子结构与计算化学数据

分子结构数据

计算化学数据

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