|
Name:
|
Aluminum ammonium sulfate dodecahydrate 99% Material Safety Data Sheet
|
|
Synonym:
|
Ammonium aluminum sulfate dodecahydrate; Ammonium alum; Aluminum ammonium sulfate, 12-hydrate; Ammonia alum
|
|
CAS:
|
7784-25-0
|
Section 1 - Chemical Product
MSDS Name:Aluminum ammonium sulfate dodecahydrate 99% Material Safety Data Sheet
Synonym:Ammonium aluminum sulfate dodecahydrate; Ammonium alum; Aluminum ammonium sulfate, 12-hydrate; Ammonia alum
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|
CAS#
|
Chemical Name
|
content
|
EINECS#
|
|
7784-25-0
|
Aluminum ammonium sulfate dodecahydrat
|
99
|
unlisted
|
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 7784-25-0: United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2 mg/m3 TWA United Kingdom, WEL - STEL: (listed as aluminum, soluble salts): mg/m3 STEL Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE ( Al) France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al CAS# 7784-26-1: United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2 mg/m3 TWA United Kingdom, WEL - STEL: (listed as aluminum, soluble salts): mg/m3 STEL Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE ( Al) France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Crystals
Color: white
Odor: Odorless.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 200 deg C @ 760mm Hg
Freezing/Melting Point: 93.5 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >280 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.6400g/cm3
Molecular Formula: AlNH4(SO4)2.12H2O
Molecular Weight: 453.33
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, aluminum, copper, steel, zinc.
Hazardous Decomposition Products:
Nitrogen oxides, oxides of sulfur, ammonia and/or derivatives.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7784-25-0 unlisted.
CAS# 7784-26-1: WS5640010 LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Aluminum ammonium sulfate, anhydrous - Not listed by ACGIH, IARC, or NTP.
Aluminum ammonium sulfate dodecahydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7784-25-0: No information available.
CAS# 7784-26-1: 1
Canada
CAS# 7784-25-0 is listed on Canada's DSL List.
CAS# 7784-26-1 is listed on Canada's DSL List.
CAS# 7784-25-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7784-26-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7784-25-0 is listed on the TSCA inventory.
CAS# 7784-26-1 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
SECTION 16 - ADDITIONAL INFORMATION N/A
