硫酸镍铵六水,15699-18-0，生产厂家，价格-洛克化工网移动版

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基本信息

制备方法及用途

物化性质

安全信息

毒理性

MSDS

结构与计算化学

硫酸镍铵六水

中文名称：: 硫酸镍铵六水

中文别名：: 硫酸镍铵;
carbon monooxide - osmium (4:1);
4,4'-methanediylbis(3-hydroxynaphthalene-2-carboxylic acid) - 1-methyl-2-[(E)-2-thiophen-2-ylethenyl]-1,4,5,6-tetrahydropyrimidine (1:1);
pyrante;
(6R,7R)-7-{[(2R)-2-amino-2-phenylacetyl]amino}-3-methyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid hydrate (1:1);
D-Cephalexin;
Cephalexin;
N-(Tert-Butyl)-2-Chloroacetamide;
Abilit;
Aiglonyl;
N-[(1-ethylpyrrolidin-3-yl)methyl]-2-methoxy-5-sulfamoylbenzamide;
(2S)-1

英文名称：: Sulfuric acid, ammoniumnickel(2+) salt (2:2:1)

英文别名：: Sulfuric acid, ammonium nickel(2+) salt (2:2:1);
Ammonium nickel sulfate ((NH4)2Ni(SO4)2) (6CI,7CI);
Diammonium nickel disulfate;
Nickel ammonium sulfate;
Nickel ammonium sulfate (Ni(NH4)2(SO4)2)

CAS No.：: 15699-18-0

分子式：: H₃N.H₂O₄S.1/2Ni

分子量：: 286.9

精确分子量：: 287.92321

PSA：: 178.10000

EINECS：: 239-793-5

InChI：: InChI=1/H3N.Ni.H2O4S/c;;1-5(2,3)4/h1H3;;(H2,1,2,3,4)/q;+2;/p-13

危险品标志：: T

风险术语：: R22；R45；R42/43

安全术语：: S22；S45；S53；S36/S37

分子结构式：

SDS：: 查看

硫酸镍铵六水物化性质

外观与性状：
暗绿色晶体

熔点：
85-89 °C(lit.)

沸点：
330ºC at 760mmHg

水溶解性：
Soluble

存储条件/存储方法：
存于密闭容器内，置于凉爽、通风处，避免接触强酸、硫。

稳定性相关：

1.加热时失去结晶水变为黄色结晶粉末。
2.皮肤接触过敏，症状为发痒、发红，而后出现皮疹，高度暴露或重复暴露会伤肺，引起咳嗽、气短、肺积水、气喘，对心脏、肝、肾有损害。

其它信息：

1.       性状：蓝绿色结晶或结晶性粉末。略有风化性。
2.       密度（g/mL,25/4℃）：1.923
3.       相对蒸汽密度（g/mL,空气=1）：未确定
4.       熔点（ºC）：85-89
5.       沸点（ºC,常压）：未确定
6.       沸点（ºC,5.2kPa）：未确定
7.       折射率：未确定
8.       闪点（ºC）：未确定
9.       比旋光度（º）：未确定
10.    自燃点或引燃温度（ºC）：未确定
11.    蒸气压（kPa,25ºC）：未确定
12.    饱和蒸气压（kPa,60ºC）：未确定
13.    燃烧热（KJ/mol）：未确定
14.    临界温度（ºC）：未确定
15.    临界压力（KPa）：未确定
16.    油水（辛醇/水）分配系数的对数值：未确定
17.    爆炸上限（%,V/V）：未确定
18.    爆炸下限（%,V/V）：未确定
19.溶解性：易溶于水，不溶于乙醇。

硫酸镍铵六水安全信息

WGK_Germany：
3
德国有关水污染物质的分类清单

危险类别码：
R45

安全说明：
S53-S22-S36/37-S45

RTECS号：
WS6061000

危险标志：
T

硫酸镍铵六水毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WS6050000

CAS REGISTRY NUMBER :
15699-18-0

LAST UPDATED :
199712

DATA ITEMS CITED :
37

MOLECULAR FORMULA :
O8-S2.Ni.2H4-N

MOLECULAR WEIGHT :
286.93
HEALTH HAZARD DATA
ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
400 mg/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
FDRLI* Food & Drug Research Laboratories, Inc., Papers. (P.O. Box 107, Rt. 17C, Waverly, NY 14892-0107) Volume(issue)/page/year: 8005A,1984

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
68100 ug/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intravenous

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
19600 ug/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
926 mg/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
68100 ug/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intravenous

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
43 mg/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

REFERENCE :
INJPD2 Indian Journal of Pharmacology. (Dept. of Pharmacology, Baranas Hindu Univ., Varanasi 221 005, India) V.1- 1968(?)- Volume(issue)/page/year: 23,153,1991 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 49,257,1990 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4948 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 7 (estimated)

硫酸镍铵六水 MSDS

Name: Ammonium Nickel Sulfate Material Safety Data Sheet

Synonym: Nickel ammonium sulfate

CAS: 15699-18-0

Section 1 - Chemical Product MSDS Name:Ammonium Nickel Sulfate Material Safety Data Sheet
Synonym:Nickel ammonium sulfate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS# Chemical Name content EINECS#

15699-18-0 Nickel ammonium sulfate 100 % 239-793-5

Hazard Symbols: XN
Risk Phrases: 22 40 42/43

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Possible risks of irreversible effects. May cause sensitization by inhalation and skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Dust is irritating to the respiratory tract. May cause allergic respiratory reaction.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Avoid contact with skin and eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Soluble in hot water.
Specific Gravity/Density: Not available.
Molecular Formula: O8S2Ni.2H4N
Molecular Weight: 286.8746

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of sulfur, nickel oxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 15699-18-0: WS6050000 LD50/LC50:
CAS# 15699-18-0: Oral, rat: LD50 = 400 mg/kg.
Carcinogenicity:
Nickel ammonium sulfate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
For further information, contact Fisher Scientific.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

CDG/CPL
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Possible risks of irreversible effects.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 22 Do not inhale dust.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 15699-18-0:
Canada
CAS# 15699-18-0 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 15699-18-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 15699-18-0:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3. OEL-A
USTRALIA:TWA 1 mg(Ni)/m3. OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compo
unds). OEL-BELGIUM:TWA 1 mg(Ni)/m3. OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)
/m3;STEL 0.25 mg(Ni)/m3. OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen. OE
L-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds). OEL-FINLAND:TWA 0.1 m
g(Ni)/m3;Carcinogen. OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble
compounds). OEL-FRANCE:TWA 1 mg(Ni)/m3. OEL-GERMANY;Carcinogen
UNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds). OEL-HUNGARY:STE
L 0.005 mg(Ni)/m3;Carcinogen. OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen. OE
L-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3. OEL-THE NETHERLANDS:TWA 1 mg(Ni)/
m3 (insoluble compounds). OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3. OEL-RUS
SIA:STEL 0.05 mg(Ni)/m3. OEL-SWEDEN:TWA 0.5 mg(Ni)/m3. OEL-SWITZERLAND
:TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-SWITZERLAND:TWA 0.5 mg(N
i)/m3;Carcinogen JAN9. OEL-THAILAND:TWA 1 mg(Ni)/m3. OEL-UNITED KINGDO
M:TWA 0.5 mg(Ni)/m3 (insoluble compounds). OEL-UNITED KINGDOM:TWA 1 mg
(Ni)/m3
IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 15699-18-0 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

硫酸镍铵六水分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值（XlogP）:无
2.氢键供体数量:1
3.氢键受体数量:4
4.可旋转化学键数量:0
5.互变异构体数量:无
6.拓扑分子极性表面积89.6
7.重原子数量:7
8.表面电荷:-1
9.复杂度:62.2
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:3

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硫酸镍铵六水

硫酸镍铵六水制备方法及用途

制备方法

合成制备方法

用途简介

用途

硫酸镍铵六水物化性质

硫酸镍铵六水安全信息

硫酸镍铵六水毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

硫酸镍铵六水 MSDS

硫酸镍铵六水分子结构与计算化学数据

计算化学数据

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硫酸镍铵

Name:	Ammonium Nickel Sulfate Material Safety Data Sheet
Synonym:	Nickel ammonium sulfate
CAS:	15699-18-0

CAS#	Chemical Name	content	EINECS#
15699-18-0	Nickel ammonium sulfate	100 %	239-793-5

硫酸镍铵六水

硫酸镍铵六水 制备方法及用途

制备方法

合成制备方法

用途简介

用途

硫酸镍铵六水 物化性质

硫酸镍铵六水 安全信息

硫酸镍铵六水 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

硫酸镍铵六水 MSDS

硫酸镍铵六水 分子结构与计算化学数据

计算化学数据

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硫酸镍铵六水制备方法及用途

硫酸镍铵六水物化性质

硫酸镍铵六水安全信息

硫酸镍铵六水毒理性

硫酸镍铵六水分子结构与计算化学数据