二(t-丁基环戊二烯基)二氯化锆(IV),32876-92-9，生产厂家，价格-洛克化工网移动版

二(t-丁基环戊二烯基)二氯化锆(IV)

中文名称：: 二(t-丁基环戊二烯基)二氯化锆(IV)

中文别名：: 二(t-丁基环戊二烯基)二氯化锆(IV);
二(T-丁基环戊二烯基)二氯化锆(IV),98+%;
二(T-丁基环戊二烯基)二氯化锆(IV);
双(叔丁基环戊二烯)二氯化锆(Ⅳ);
二(叔-丁基环戊二烯基)二氯化锆(IV),97%;
双(叔丁基环戊二烯基)二氯化锆(IV);
二(叔-丁基环戊二烯基)二氯化锆(IV)

英文名称：: Zirconium,dichlorobis[(1,2,3,4,5-h)-1-(1,1-dimethylethyl)-2,4-cyclopentadien-1-yl]-

英文别名：: 2-tert-butylcyclopenta-1,3-diene,zirconium(4+),dichloride;
BIS(TERT-BUTYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE;
BIS(T-BUTYLCYCLOPENTADIENYL)ZIRCONIUM DICHLORIDE;
BIS(T-BUTYLCYCLOPENTADIENYL)ZIRCONIUM(IV) DICHLORIDE;
Bistbutylcyclopentadienylzirconiumdichloridemin;
BIS(TERT-BUTYLCYCLOPENTADIENYL)ZIRCONIU&;
Bis(tert-butylcyclopentadienyl)zirkoniumdichlorid;
Bis(tert-butylcyclopentadienyl)zirkoniumdichloride;
Bis(t-butylcyclopentadienyl)zirconiumdichloride,min.98%

CAS No.：: 32876-92-9

分子式：: C₁₈H₂₆Cl₂Zr

分子量：: 404.53

精确分子量：: 402.04600

PSA：: 0.00000

MDL：: MFCD01073785

危险品标志：: Xi:Irritant

风险术语：: R36/37/38;

安全术语：: S26; S37/39;

分子结构式：

SDS：: 查看

二(t-丁基环戊二烯基)二氯化锆(IV) 物化性质

熔点：: 192-194ºC
存储条件/存储方法：: 保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置
稳定性相关：: 如果遵照规格使用和储存则不会分解，未有已知危险反应
其它信息：: 1.         性状：固体

2.         密度（g/mL,20℃）：未确定

3.         相对蒸汽密度（g/mL,空气=1）：未确定

4.         熔点（ºC）：192-194

5.         沸点（ºC,常压）：未确定

6.         沸点（ºC,KPa）：未确定

7.         折射率：未确定

8.         闪点（ºC）：未确定

9.         比旋光度（º）：未确定

10.      自燃点或引燃温度（ºC）：未确定

11.      蒸气压（Pa,20ºC）：未确定

12.      饱和蒸气压（KPa,20ºC）：未确定

13.      燃烧热（KJ/mol）：未确定

14.      临界温度（ºC）：未确定

15.      临界压力（KPa）：未确定

16.      油水（辛醇/水）分配系数的对数值：未确定

17.      爆炸上限（%,V/V）：未确定

18.      爆炸下限（%,V/V）：未确定

19.     溶解性：未确定

二(t-丁基环戊二烯基)二氯化锆(IV) 安全信息

危险类别码：: R36/37/38
安全说明：: S26-S37/39
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
:
危险标志：: Xi:Irritant;

二(t-丁基环戊二烯基)二氯化锆(IV) 毒理性

生态数据：

二(t-丁基环戊二烯基)二氯化锆(IV) MSDS

Name:	Bis(tert-butylcyclopentadienyl)zirkonium dichloride Material Safety Data Sheet
Synonym:	None Known
CAS:	32876-92-9

Section 1 - Chemical Product MSDS Name:Bis(tert-butylcyclopentadienyl)zirkonium dichloride Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
32876-92-9	Bis(tert-butylcyclopentadienyl)zirkoni	ca. 100	unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled. Can produce delayed pulmonary edema.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT get water inside containers.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Store protected from air. Use and store under argon. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from moisture. Store under argon.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 32876-92-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 192 - 194 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C18H26Cl2Zr
Molecular Weight: 404.308

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Air sensitive. Moisture sensitive.
Conditions to Avoid:
Exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 32876-92-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bis(tert-butylcyclopentadienyl)zirkonium dichloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 32876-92-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 32876-92-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 32876-92-9 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A