包装等级：

III

风险类别：

8

海关代码：

2916190090

WGK_Germany：

1
德国有关水污染物质的分类清单

危险类别码：

R36/38;R43

安全说明：

S39

RTECS号：

UD3370000

安全标志：

S39:佩戴眼/面防护装置。

危险标志：

Xi:Irritant;

CHEMICAL IDENTIFICATION

RTECS NUMBER :

UD3370000

CHEMICAL NAME :

2-Propenoic acid, 2-(hydroxymethyl)-2-(((1-oxo-2-propenyl)oxy)methyl)-1 ,3-propanediyl ester

CAS REGISTRY NUMBER :

3524-68-3

LAST UPDATED :

199712

DATA ITEMS CITED :

15

MOLECULAR FORMULA :

C14-H18-O7

MOLECULAR WEIGHT :

298.32

WISWESSER LINE NOTATION :

1U1VO1X1Q1OV1U1&1OV1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Open irritation test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

2460 uL/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

4 mL/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

16 gm/kg/80W-I

TOXIC EFFECTS :

Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

2 gm/kg/2W-I

TOXIC EFFECTS :

Skin and Appendages - dermatitis, other (after systemic exposure)

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

16 gm/kg/80W-I

TOXIC EFFECTS :

Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease

MUTATION DATA

TYPE OF TEST :

Cytogenetic analysis

TEST SYSTEM :

Rodent - mouse Lymphocyte

DOSE/DURATION :

300 ug/L

REFERENCE :

MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1986- Volume(issue)/page/year: 4,381,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1224 No. of Facilities: 56 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 138 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1224 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 62 (estimated) No. of Female Employees: 41 (estimated)

毒理学数据：

1、  皮肤/眼睛刺激数据：

兔子皮肤注射刺激实验：500mgREACTIONSEVERITY:Mild

兔子皮肤注射标准Draize测试：500mgREACTIONSEVERITY:Moderate

兔子眼部注射标准Draize测试：1mgREACTIONSEVERITY:Severe

2、  急性毒性数据：

大鼠口经LD50：2460uL/kg

大鼠皮肤注射LD50：4mL/kg

3、  其他多剂量毒性数据：

小鼠皮肤注射TDLo：16gm/kg/80W-I

兔子皮肤注射TDLo：2gm/kg/2W-I

4、  致肿瘤数据：

小鼠皮肤注射TDLo：16gm/kg/80W-I

5、  致突变数据：

微testTEST系统：啮齿动物-小鼠淋巴细胞：350ug/L

生态数据：

通常对水是不危害的，若无政府许可，勿将材料排入周围环境

中国海关编码：2916190090

概述：

2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

监管条件：

A.入境货物通关单B.出境货物通关单

检验检疫：

R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验

摘要/Summary：

2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

分子结构数据

1、  摩尔折射率：72.91

2、  摩尔体积（m³/mol）：252.9

3、  等张比容（90.2K）：642.1

4、  表面张力（dyne/cm）：41.5

5、  极化率（10^-24cm³）：28.90

计算化学数据

1.疏水参数计算参考值（XlogP）:1.1

2.氢键供体数量:1

3.氢键受体数量:7

4.可旋转化学键数量:13

5.互变异构体数量:无

6.拓扑分子极性表面积99.1

7.重原子数量:21

8.表面电荷:0

9.复杂度:365

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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