六氟乙酰丙酮锌二水合物,16743-33-2，生产厂家，价格-洛克化工网移动版

六氟乙酰丙酮锌二水合物

中文名称：: 六氟乙酰丙酮锌二水合物

中文别名：: 六氟乙酰丙酮锌二水合物;
六氟乙酰丙酮锌

英文名称：: Zinc,bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-kO,kO')-, dihydrate, (T-4)- (9CI)

英文别名：: Zinc, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κO2,κO4)-, hydrate (1:2), (T-4)-;
Zinc, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-, dihydrate (8CI);
Zinc, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O')-, dihydrate, (T-4)-;
Zinc, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-κO,κO')-, dihydrate, (T-4)- (9CI);
Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)zinc dihydrate;
Bis(hexafluoroacetylacetonato)zinc dihydrate;
Zinc(II) hexafluoroacetylacetonate dihydrate

CAS No.：: 16743-33-2

分子式：: C₁₀H₂F₁₂O₄Zn.2H₂O

分子量：: 515.52

精确分子量：: 513.92642

PSA：: 71.06000

MDL：: MFCD00150577

InChI：: InChI=1/2C5H2F6O2.2H2O.Zn/c2*6-4(7,8)2(12)1-3(13)5(9,10)11;;;/h2*1,12H;2*1H2;/q;;;;+2/p-2/b2*2-1-;;;3

危险品标志：: Xi

风险术语：: R36/37/38

安全术语：: S26;S36;

分子结构式：

SDS：: 查看

六氟乙酰丙酮锌二水合物制备方法及用途

制备方法

将0.55mL 30%的氨水加到含有1.69g六氟乙酰丙酮的水悬浮液中，然后将其加到含有0.6g氯化锌的水溶液中，搅拌，很快析出六氟乙酰丙酮锌沉淀，滤出，干燥，即得产品。

合成制备方法

将0.55mL 30%的氨水加到含有1.69g六氟乙酰丙酮的水悬浮液中，然后将其加到含有0.6g氯化锌的水溶液中，搅拌，很快析出六氟乙酰丙酮锌沉淀，滤出，干燥，即得产品。

用途简介

六氟乙酰丙酮锌二水合物物化性质

熔点：: 157-158ºC
沸点：: 114.1ºC at 760mmHg
闪点：: 22.8ºC
蒸汽压：: 10.3mmHg at 25°C
存储条件/存储方法：: 常温密闭避光，通风干燥
稳定性相关：: 常温常压下稳定
避免的物料：氧化物。不溶于水和四氯化碳，溶于乙醇、丙酮和乙醚。在五氧化二磷存在下进行真空干燥失去结晶水。
其它信息：: 1. 性状：白色固体，具八面体晶体结构。
2. 密度（g/mL,25/4℃）：未确定
3. 相对蒸汽密度（g/mL,空气=1）：未确定
4. 熔点（ºC）：53～154
5. 沸点（ºC,常压）：未确定
6. 沸点（ºC,5.2kPa）：未确定
7. 折射率：未确定
8. 闪点（ºC）：未确定
9. 比旋光度（º）：未确定
10. 自燃点或引燃温度（ºC）：未确定
11. 蒸气压（kPa,25ºC）：未确定
12. 饱和蒸气压（kPa,60ºC）：未确定
13. 燃烧热（KJ/mol）：未确定
14. 临界温度（ºC）：未确定
15. 临界压力（KPa）：未确定
16. 油水（辛醇/水）分配系数的对数值：未确定
17. 爆炸上限（%,V/V）：未确定
18. 爆炸下限（%,V/V）：未确定
19. 溶解性：未确定

六氟乙酰丙酮锌二水合物安全信息

危险类别码：: R36/37/38
安全说明：: 26-36
危险标志：: Xi: Irritant;

六氟乙酰丙酮锌二水合物毒理性

生态数据：

通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

六氟乙酰丙酮锌二水合物 MSDS

Section 1: Product Identification
   Chemical Name:       Zinc hexafluoroacetylacetonate hydrate, min. 98%
   CAS Registry Number:       16743-33-2
   Formula:       Zn(CF3COCHCOCF3)2.2H2O
   EINECS Number:       None
   Chemical Family:       metal fluorobeta-diketonate complexes
   Synonym:       Zinc hexafluoro 2,4-pentanedionate

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 16743-33-2 100% 2.5mg/m3 (as F) 2.5mg/m3 (as F)

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. Inhalation of high levels may produce symptoms known as metal
   Emergency Overview:
   fume fever or zinc shakes. These include chills, fever, nausea, and vomiting.
   Primary Routes of Exposure:       Ingestion, Inhalation of dust.
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes slight to mild irritation of the skin.
   Irritating to the nose, mucous membranes and respiratory tract. Inhalation may produce symptoms known as
   Inhalation:
   metal fume fever and zinc shakes.
   Ingestion:       Zinc salts have a harsh metallic taste.
   Inhalation of dust may cause chills, muscle ache, nausea, fever, dry throat, cough; headache; blurred vision;
   Acute Health Affects:
   low back pain; vomiting; dyspnea (breathing difficulty), rales, and decreased pulmonary function
   Prolonged or repeated exposure may cause breathing difficulty and decreased pulmonary function. In animal
   Chronic Health Affects:
   studies mutagenic and reproductive effects were observed after prolonged exposures to zinc oxide dust.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, foam or dry powder
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and corrosive fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.
   Molecular Weight:       479.47 (515.50)
   Melting Point:       157-158°C
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       Oxidizing agents
   Decomposition Products:       Fluorinated organics, carbon dioxide, carbon monoxide, organic fumes, and zinc oxide.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       No data
   Mutagenic Effects:       No data
   Tetratogenic Effects:       No data

SECTION 12: Ecological Information
Ecological Information: Very toxic to aquatic organisms.

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.
   SARA (Title 313):       Title compound: See category N982 for reporting.
   Second Ingredient:       None

SECTION 16 - ADDITIONAL INFORMATION
N/A

六氟乙酰丙酮锌二水合物分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:2

3.氢键受体数量:18

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积82.3

7.重原子数量:29

8.表面电荷:0

9.复杂度:210

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:2

15.共价键单元数量:5