3-溴-1,1,1-三氟-2-丙醇

中文名称：

3-溴-1,1,1-三氟-2-丙醇 

中文别名：

3-溴-1,1,1-三氟-2-丙醇;
3-Bromo-1,1,1-trifluoropropan-2-ol 

英文名称：

2-Propanol,3-bromo-1,1,1-trifluoro-, (2S)-

英文别名：

3-BROMO-1,1,1-TRIFLUORO-2-PROPANOL;
N-benzyloxycarbonyl-L-aspartic acid imide;
(S)-3-biphenyl-4-yl-2-(9H-fluoren-9-ylmethoxycarbonylamino)propionic acid;
3-(S)-N-benzyloxycarbonylaminopyrrolidine-2,5-dione;
(S)-2-(benzyloxycarbonylamino)succinimide;
Fmoc-4-phenyl-L-alanine;
(S)-3-N-Cbz-amino-succinimide;
(S)-benzyl 2,5-dioxopyrrolidin-3-ylcarbamate;
(S)-2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-3-(biphenyl-4-yl)propanoic acid;
(S)-3-Bromo-1,1,1-trifluoro-2-propanol;
Fmoc-4-phenyl-phenylalanine;
(S)-3-N-carbobenzyloxyaminosuccinimide;
Fmoc-Bip-OH;
(s)-(2,5-dioxo-pyrrolidin-3-yl)-carbamic acid benzyl ester;
Fmoc-L-4-phenyl-phenylalanine;
(3S)-3-(benzyloxycarbonylamino)succinimide;
(S)-3-benzyloxycarbonylaminopyrrolidine-2,5-dione;
Fmoc-(p-Phe)Phe-OH;
(S)-(+)-1-Bromo-3,3,3-trifluoro-2-propanol 

CAS No.：

88378-50-1

分 子 式：

C₃H₄BrF₃O

分 子 量：

192.96

精确分子量：

191.94000

PSA：

20.23000

MDL：

MFCD00040945

InChI：

The Key: VBHIIZIQRDVGDH-UWTATZPHSA-N3

危险品标志：

风险术语：

36/37/38

安全术语：

SDS：

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3-溴-1,1,1-三氟-2-丙醇 物化性质

密度：

1.861 g/mL at 25ºC(lit.)

沸点：

124.5ºC743 mm Hg(lit.)

折射率：

n20/D 1.4(lit.)

其它信息：

1.      性状：未确定

2.      密度（g/mL25 ºC）：1.861

3.      相对蒸汽密度（g/mL,空气=1）：未确定

4.      熔点（ºC）：未确定

5.      沸点（ºC,常压）：未确定

6.      沸点（ºC743mmHg）：124.5

7.      折射率：n20/D 1.4

8.      闪点（ºF）：110

9.      比旋光度（º）：未确定

10.   自燃点或引燃温度（ºC）：未确定

11.   蒸气压（Pa,）：未确定

12.   饱和蒸气压（kPa,60ºC）：未确定

13.   燃烧热（KJ/mol）：未确定

14.   临界温度（ºC）：未确定

15.   临界压力（KPa）：未确定

16.   油水（正辛醇/水）分配系数的对数值：未确定

17.   爆炸上限（%,V/V）：未确定

18.   爆炸下限（%,V/V）：未确定

19.   溶解性：未确定

3-溴-1,1,1-三氟-2-丙醇 安全信息

海关代码：

2905590090

危险类别码：

36/37/38

安全说明：

26-36

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。

危险标志：

Xi: Irritant;

3-溴-1,1,1-三氟-2-丙醇 MSDS

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	UN 1987 3/PG 3
WGK Germany	3

Name:	3-Bromo-1 1 1-trifluoro-2-propanol 96% (g c) Material Safety Data Sheet
Synonym:	3-Bromo-1,1,1-trifluoroisopropano
CAS:	88378-50-1

Section 1 - Chemical Product   MSDS Name:3-Bromo-1 1 1-trifluoro-2-propanol 96% (g c) Material Safety Data Sheet
Synonym:3-Bromo-1,1,1-trifluoroisopropano

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
88378-50-1	3-Bromo-1,1,1-trifluoro-2-propanol	96	unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

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Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

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Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 88378-50-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 124 - 126 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C3H4BrF3O
Molecular Weight: 192.96

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Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong reducing agents - strong acids - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, hydrogen bromide.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 88378-50-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Bromo-1,1,1-trifluoro-2-propanol - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION
 

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Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 88378-50-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 88378-50-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 88378-50-1 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A