制备方法

1.天然矿加工法天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。制备方法有三种:天然太后加工法、锑白转化法和直接化合法。 (1)天然矿加工法。天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。 (2)锑白转化法。反应方程式: 操作方法:将Sb2O3 1.80kg、Ca(OH)2 0.6kg、H2O 6kg混合后,在80℃加热1h。将2.41kg 60%Na2S溶解在3L水中配成Na2S溶液,在搅拌下,于80℃下,在30min内将此Na2S溶液加入上述混合物中,再维持搅拌30min。然后用30%的HCl在3h内酸化至pH为0.4。升温至95℃,再搅拌3h,降温、过滤、洗涤、干燥,制得Sb2S3颜料。 (3)直接化合法。反应方程式: 操作方法:将金属锑高温熔化后,向其中通入硫蒸气,直接化合生成三硫化二锑。硫的用量为化学计量的103%～115%,搅拌反应0.3～1h,反应温度维持在650～850℃。 2.向三价锑盐的酸性水溶液中通入硫化氢,即得三硫化二锑沉淀,呈橙红色,无定形。在隔绝空气下加热到200℃,即得结晶。

合成制备方法

1.天然矿加工法天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。制备方法有三种：天然太后加工法、锑白转化法和直接化合法。

（1）天然矿加工法。天然辉锑矿经筛选、粉碎等加工而制得硫化锑成品。

（2）锑白转化法。反应方程式：

操作方法：将Sb2O3 1.80kg、Ca(OH)2 0.6kg、H2O 6kg混合后，在80℃加热1h。将2.41kg 60%Na2S溶解在3L水中配成Na2S溶液，在搅拌下，于80℃下，在30min内将此Na2S溶液加入上述混合物中，再维持搅拌30min。然后用30%的HCl在3h内酸化至pH为0.4。升温至95℃，再搅拌3h，降温、过滤、洗涤、干燥，制得Sb2S3颜料。

（3）直接化合法。反应方程式：

操作方法：将金属锑高温熔化后，向其中通入硫蒸气，直接化合生成三硫化二锑。硫的用量为化学计量的103%～115%，搅拌反应0.3～1h，反应温度维持在650～850℃。

2.向三价锑盐的酸性水溶液中通入硫化氢，即得三硫化二锑沉淀，呈橙红色，无定形。在隔绝空气下加热到200℃，即得结晶。

用途简介

主要用于制造火柴和烟火，各种锑盐和有色玻璃。橡胶工业用作硫化剂及军工用等。

用途

1.主要用于制造火柴和烟火，各种锑盐和有色玻璃。橡胶工业用作硫化剂及军工用等。

2.用于制颜料、烟火、火柴等。^[13]

包装等级：

III

风险类别：

6.1

海关代码：

2830902000

危险类别码：

R36/37/38;R20/21/22

安全说明：

S36/37/39-S26

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

危险标志：

Xn

CHEMICAL IDENTIFICATION

RTECS NUMBER :

CC9450000

CHEMICAL NAME :

Antimony trisulfide

CAS REGISTRY NUMBER :

1345-04-6

LAST UPDATED :

199712

DATA ITEMS CITED :

38

MOLECULAR FORMULA :

S3-Sb2

MOLECULAR WEIGHT :

339.68

WISWESSER LINE NOTATION :

SB2 S3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Human

DOSE/DURATION :

580 ug/m3/35W

TOXIC EFFECTS :

Cardiac - EKG changes not diagnostic of specified effects Vascular - BP elevation not characterized in autonomic section Gastrointestinal - ulceration or bleeding from stomach

REFERENCE :

IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 23,521,1954

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

1390 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :

INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 10,15,1941

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

209 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,23,1982

TYPE OF TEST :

LD - Lethal dose

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

>139 mg/kg

REFERENCE :

GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(7),25,1964 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:STEL 0.5 ppm JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4884 No. of Facilities: 786 (estimated) No. of Industries: 34 No. of Occupations: 27 No. of Employees: 26669 (estimated) No. of Female Employees: 1082 (estimated)

毒理学数据：

1.急性毒性^[6]  LD50：209mg/kg（小鼠腹腔）

2.刺激性  暂无资料

3.致癌性^[7]  IARC致癌性评论：G3，对人及动物致癌性证据不足。

生态数据：

水危害级别3：对水是极其危害的，即使是少量产品渗入地下也会对饮用水造成危害，若无政府许可勿将产品排入周围环境。对水中有机物有剧毒和危害。

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：337.723854 Da

8、标称质量：338 Da

9、平均质量：339.715 Da

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积152

7.重原子数量:10

8.表面电荷:0

9.复杂度:84.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

• 
  三硫化锑红外图谱(IR1)