5-硝基邻甲氧基苯酚,636-93-1，生产厂家，价格-洛克化工网移动版

5-硝基邻甲氧基苯酚

中文名称：: 5-硝基邻甲氧基苯酚

中文别名：: 2-甲氧基-5-硝基苯酚;
5-硝基邻甲氧基苯酚;
5-硝基愈疮木酚;
5-硝基愈创木酚;
2-羟基-1-甲氧基-5-硝基苯

英文名称：: Phenol,2-methoxy-5-nitro-

英文别名：: 2-Methoxy-5-nitrophenol;
2-Hydroxy-4-nitroanisole;
Phenol,2-methoxy-5-nitro;
5-nitro-2-methoxyphenol;
3-HYDROXY-4-METHOXYNITROBENZENE;
5-nitroguaiacol;
2-Methoxy-5-nitro-phenol;
2-Methoxy-5-nitrophe

CAS No.：: 636-93-1

分子式：: C₇H₇NO₄

分子量：: 169.14

精确分子量：: 169.03800

PSA：: 75.28000

MDL：: MFCD00015561

EINECS：: 211-269-0

BRN：: 2047074

InChI：: InChI=1/C7H7NO4/c1-12-7-3-2-5(8(10)11)4-6(7)9/h2-4,9H,1H33

风险术语：: R20/21/22; R36/37/38;

安全术语：: S26; S36/37/39;

分子结构式：

SDS：: 查看

5-硝基邻甲氧基苯酚物化性质

外观与性状：: 白色至灰白色固体
密度：: 1.367g/cm3
熔点：: 103-107 °C(lit.)
沸点：: 110-112 °C1 mm Hg(lit.)
闪点：: 110-112°C/1mm
折射率：: 1.583
存储条件/存储方法：: 存放在密封容器内，并放在阴凉，干燥处。储存的地方必须远离氧化剂。
稳定性相关：: 远离氧化物。
其它信息：: 1.       性状：黄色粉末。
2.       密度（g/mL,25/4℃）：未确定
3.       相对蒸汽密度（g/mL,空气=1）：未确定
4.       熔点（ºC）：103-107
5.       沸点（ºC,常压）：未确定
6.       沸点（ºC,5.2kPa）：未确定
7.       折射率：未确定
8.       闪点（ºC）：未确定
9.       比旋光度（º）：未确定
10.    自燃点或引燃温度（ºC）：未确定
11.    蒸气压（kPa,25ºC）：未确定
12.    饱和蒸气压（kPa,60ºC）：未确定
13.    燃烧热（KJ/mol）：未确定
14.    临界温度（ºC）：未确定
15.    临界压力（KPa）：未确定
16.    油水（辛醇/水）分配系数的对数值：未确定
17.    爆炸上限（%,V/V）：未确定
18.    爆炸下限（%,V/V）：未确定
19.    溶解性：未确定。

5-硝基邻甲氧基苯酚安全信息

包装等级：: III
海关代码：: 29095090
WGK_Germany：: 3
德国有关水污染物质的分类清单
危险类别码：: R20/21/22;R36/37/38
安全说明：: S26
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
危险标志：: Xn,Xi

5-硝基邻甲氧基苯酚毒理性

毒理学数据：

主要的刺激性影响：

在皮肤上面：刺激皮肤和粘膜

在眼睛上面: 刺激的影响

致敏作用：没有已知的敏化作用。

生态数据：

对水稍微有危害的，不要让未稀释或者大量产品接触地下水，水道或者污水系统。若无政府许可，勿将材料排入周围环境。

5-硝基邻甲氧基苯酚 MSDS

5-Nitroguaiacol Revision number: 5
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        5-Nitroguaiacol

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
  Skin corrosion/irritation        Category 2
    Category 2A
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statements        Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Wash hands thoroughly after handling.
  [Prevention]
    Wear protective gloves/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
  [Response]
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        5-Nitroguaiacol
  Percent:        >97.0%(T)
  CAS Number:        636-93-1
  Synonyms:        2-Methoxy-5-nitrophenol , 2-Hydroxy-1-methoxy-4-nitrobenzene
    C7H7NO4
  Chemical Formula:

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  5-Nitroguaiacol

Section 4. FIRST AID MEASURES
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
    Crystal- Powder
  Form:
  Colour:        Pale yellow - Yellow green
    No data available
  Odour:
  5-Nitroguaiacol

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  pH: No data available
  Melting point/freezing point:105°C
  Boiling point/range:        112°C/0.1kPa
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
  [Water]        No data available
  [Other solvents]
  Soluble:        Methanol

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents, Strong bases
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations
  UN-No:        Not listed
  5-Nitroguaiacol

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

5-硝基邻甲氧基苯酚分子结构与计算化学数据

分子结构数据

1、摩尔折射率：41.35

2、摩尔体积（cm³/mol）：123.7

3、等张比容（90.2K）：334.4

4、表面张力（dyne/cm）：53.4

5、极化率（10^-24cm³）：16.29

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:4

4.可旋转化学键数量:1

5.互变异构体数量:3

6.拓扑分子极性表面积75.3

7.重原子数量:12

8.表面电荷:0

9.复杂度:167

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

5-硝基邻甲氧基苯酚上游产品

1,2-亚甲二氧基-4-硝基苯 1,2-二甲氧基-4-硝基苯正己胺 1,2-二羟基-4-硝基苯硫酸二甲酯

5-硝基邻甲氧基苯酚下游产品

3-羟基-4-甲氧基苯腈 2-羟基-4-氯苯甲醚 2-(3-氯丙氧基)-1-甲氧基-4-硝基苯 1,2-二甲氧基-4-硝基苯 4-碘藜芦醚