2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶,174500-20-0，生产厂家，价格-洛克化工网移动版

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶

中文名称：: 2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶

中文别名：: 2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶;
2,6-双[(4S)-4-苯基-2-噁唑啉基]吡啶;
2,6-二[(4S)-4-苯基-2-噁唑啉基]吡啶;
2,6-双[4S-4-苯基-2-噁唑啉基]吡啶;
(-)-2,6-双((4S)-4-苯基-2-恶唑啉)吡啶;
(S,S)-2,6-双(4,5-二氢-4-苯基-2-噁唑基)吡啶;
2,6-双[(4S)-4-苯基-2-恶唑啉]吡啶;
2,6-二[(4S)-4-苯基-2-恶唑啉基;
(S,S)-2,6-双(4-苯基-2-恶唑啉-2-基)吡啶;
(S,S)-2,6-双(4-苯基-2-噁唑啉基)吡啶;
(S,S)-2,2'-(2,6-吡啶二基)双(4-苯基-2-恶唑啉

英文名称：: Pyridine,2,6-bis[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]-

英文别名：: (S,S)-2,2'-(2,6-Pyridinediyl)bis(4-phenyl-2-oxazoline);
2,6-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)pyridine;
(4S)-4-phenyl-2-[6-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]pyridin-2-yl]-4,5-dihydro-1,3-oxazole;
2,6-Bis[(4S)-phenyl-2-(oxazolin-2-yl)]pyridine;
(S,S)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine;
2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine;
2,6-Bis[4S-4-phenyl-2-oxazolinyl]pyridine;
2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine;
(S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine;
(S,S)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine

CAS No.：: 174500-20-0

分子式：: C₂₃H₁₉N₃O₂

分子量：: 369.42

精确分子量：: 369.14800

PSA：: 56.07000

MDL：: MFCD01863586

InChI：: The Key: HLHBIMJNCKZZQO-NHCUHLMSSA-N3

危险品标志：

风险术语：: R36/37/38

安全术语：: S26;S37/39

分子结构式：

SDS：: 查看

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶物化性质

外观与性状：: 白色至灰白色结晶粉末
密度：: 1.28 g/cm3
熔点：: 171-175 °C(lit.)
沸点：: 600.4ºC at 760 mmHg
闪点：: 316.9ºC
水溶解性：: Insoluble
存储条件/存储方法：: 密封冷藏于干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：171-175

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：-224（ C=1, 氯仿）

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：不溶于水

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶安全信息

WGK_Germany：: 3
德国有关水污染物质的分类清单
危险类别码：: R36/37/38
安全说明：: S26-S36/37/39-S37/39
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:
危险标志：: Xi:Irritant;

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶 MSDS

Name:	2 6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine Material Safety Data Sheet
Synonym:
CAS:	174500-20-0

Section 1 - Chemical Product MSDS Name:2 6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
174500-20-0	2,6-bis[(4s)-phenyl-2-oxazolin-2-yl]py		unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 174500-20-0: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 171 - 175 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C23H19N3O2
Molecular Weight: 369.42

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 174500-20-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,6-bis[(4s)-phenyl-2-oxazolin-2-yl]pyridine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 174500-20-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 174500-20-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 174500-20-0 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶分子结构与计算化学数据

分子结构数据

1、摩尔折射率：107.74

2、摩尔体积（m³/mol）：287.2

3、等张比容（90.2K）：766.0

4、表面张力（dyne/cm）：50.6

5、极化率（10^-24cm³）：42.71

计算化学数据

1.疏水参数计算参考值（XlogP）:4

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:4

5.互变异构体数量:无

6.拓扑分子极性表面积56.1

7.重原子数量:28

8.表面电荷:0

9.复杂度:543

10.同位素原子数量:0

11.确定原子立构中心数量:2

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

2,6-二[(4S)-4-苯基-2-恶唑啉基]吡啶上游产品

2,6-氯甲酰吡啶 (S)-(+)-2-氨基-1-苯乙醇 L-苯甘氨醇 2,6-吡啶二甲腈; 2,6-二氰基吡啶