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Section 1. Chemical Product and Company Identification
    Wintergreen Oil, Natural
    Common Name/
    Trade Name
    Wintergreen Oil, Natural

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Section 4. First Aid Measures
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least
    Eye Contact
    15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
    In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
    Skin Contact
    contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
    attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
    Ingestion
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

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Section 5. Fire and Explosion Data
    Flammability of the Product May be combustible at high temperature.
    Auto-Ignition Temperature 850°C (1562°F)
    CLOSED CUP: 93.333°C (200°F). OPEN CUP: 96°C (204. 8°F).
    Flash Points
    Not available.
    Flammable Limits
    These products are carbon oxides (CO, CO2).
    Products of Combustion
    Fire Hazards in Presence of Slightly flammable to flammable in presence of open flames and sparks, of heat.
    Non-flammable in presence of shocks.
    Various Substances
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards in
    Risks of explosion of the product in presence of static discharge: Not available.
    Presence of Various
    Substances
    SMALL FIRE: Use DRY chemical powder.
    Fire Fighting Media
    LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
    and Instructions
    Not available.
    Special Remarks on
    Fire Hazards
    Not available.
    Special Remarks on
    Explosion Hazards

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Section 6. Accidental Release Measures
    Absorb with an inert material and put the spilled material in an appropriate waste disposal.
    Small Spill
    Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
    Large Spill
    spreading water on the contaminated surface and allow to evacuate through the sanitary system.
    Wintergreen Oil, Natural

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Section 7. Handling and Storage
    Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
    Precautions
    evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not
    breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable
    respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid
    contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids, alkalis.
    Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in
    Storage
    light-resistant containers.

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Section 8. Exposure Controls/Personal Protection
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
    Engineering Controls
    respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station
    location.
    Splash goggles. Lab coat. Gloves.
    Personal Protection
    Adequate general (room) ventilation or local exhaust (fume hood) is sufficient. Use a vapor respirator under
    conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapor,
    inadequate ventilation, development of respiratory tract irritation), and engineering controls are not feasible. Be sure
    to use an approved/certified respirator or equivalent.
    Personal Protection in Case Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to
    of a Large Spill        avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE    
    handling this product.
    Not available.
    Exposure Limits

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Section 9. Physical and Chemical Properties
    Liquid. (Oily liquid.)        Characteristic of Wintergreen Pleasant. Aromatic.    
    Physical state and        O dor    
    appearance
    Characteristic of Wintergreen
    Taste
    Not applicable.
    Molecular Weight
    Clear Colorless to light yellow to reddish.
    Color
    Not available.
    pH (1% soln/water)
    The lowest known value is 220°C (428°F) (Methyl sal icylate).
    Boiling Point
    May start to solidify at -8.6°C (16.5°F) based on d ata for: Methyl salicylate.
    Melting Point
    Not available.
    Critical Temperature
    1.179 - 1.185 (Water = 1)
    Specific Gravity
    The highest known value is <0.1 kPa (@ 20°C)
    Vapor Pressure
    1 mm Hg at 54 deg C.; 0.0343 mm Hg at 25 deg. C.; < 0.0343 mm Hg at 20 deg. C. (Methyl salicylate).
    The highest known value is 5.25 (Air = 1) (Methyl salicylate).
    Vapor Density
    Not available.
    Volatility
    Not available.
    Odor Threshold
    Not available.
    Water/Oil Dist. Coeff.
    Not available.
    Ionicity (in Water)
    See solubility in water, diethyl ether.
    Dispersion Properties
    Soluble in diethyl ether.
    Solubility
    Very slightly soluble in cold water.
    Miscible in alcohol, glacial acetic acid.
    Soluble in chloroform.
    Soluble in most common organic solvents.
    Solubility in water: 0.74%.
    Wintergreen Oil, Natural

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Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Not available.
    Instability Temperature
    Conditions of Instability Excess heat, ignition sources, ncompatible materials
    Incompatibility with various Reactive with oxidizing agents, acids, alkalis.
    substances
    Non-corrosive in presence of glass.
    Corrosivity
    Sensitive to heat Sensitive to light. (Methyl salicylate)
    Special Remarks on
    Reactivity
    Not available.
    Special Remarks on
    Corrosivity
    Will not occur.
    Polymerization

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Section 11. Toxicological Information
    Absorbed through skin. Eye contact.
    Routes of Entry
    Acute oral toxicity (LD50): 914 mg/kg (Rat) (Calculated value for the mixture).
    Toxicity to Animals
    Chronic Effects on Humans MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Methyl salicylate].
    Other Toxic Effects on        Hazardous in case of skin contact (irritant), of ingestion.    
    Humans        Slightly hazardous in case of inhalation.    
    Lethal Dose/Conc 50% Kill:
    Special Remarks on
    LD50 [Guinea Pig] - Route: Oral; Dose: 700 mg/kg
    Toxicity to Animals
    LD50 [Dog] - Route: Oral; Dose: 2100 mg/kg
    LDL (Lowest Published Lethal Dose):
    LDL [Human] - Route: Oral; Dose: 506 mg/kg
    LDL [Man] - Route: Oral; Dose: 101 - 1329 mg/kg
    LDL [Woman] - Route: Oral; Dose: 355 mg/kg
    LDL [Infant] - Route: Oral; Dose: 1480 mg/kg
    LDL [Child] - Route: Oral; Dose: 228 - 700 mg/kg (Methyl salicylate)
    Special Remarks on        May cause adverse reproductive effects and birth defects (teratogenic).    
    Chronic Effects on Humans Human: passes the placental barrier.
    May affect genetic material (mutagenic)
    Acute Potential Health Effects:
    Special Remarks on other
    Skin: Causes moderate to severe skin irritation. It can be absorbed through the skin.
    Toxic Effects on Humans
    Eyes: Causes mild to severe eye irritation.Inhalation: May cause respiratory tract irritation.
    Ingestion: May be harmful if swallowed. May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea,
    gastric ulceration, heartburn, dyspepsia, hyperpyrexia, sweating, thirst. May affect behavior/Central Nervous system
    (headache, excitation, dizziness, lassitude, drowsiness, mental confusion, convulsions, coma), respiration
    (hyperventilation, hyperpnea, dyspnea, pulmonary edema), ears (ringing in the ears), eyes (dimness of vision), blood
    (hemorrhage).
    Inhalation: Inhalation of mist or vapor may cause respiratory tract irritation.
    Chronic Potential Health Effects:
    Ingestion: Prolonged or repeated ingestion may cause weight loss, and also affect the blood (changes in white and
    red blood cell count), urinary system (kidneys), heart, liver, musculoskeletal system as well as other symptoms similar
    to acute ingestion.
    Inhalation: Prolonged or repeated inhalation may affect the blood (changes in red and white cell blood count)
    Wintergreen Oil, Natural

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Section 12. Ecological Information
    Not available.
    Ecotoxicity
    Not available.
    BOD5 and COD
    Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    arise.
    The products of degradation are less toxic than the product itself.
    Toxicity of the Products
    of Biodegradation
    1. TERRESTRIAL FATE: If released on soil, methyl salicylate would readily leach. It would also be expected to
    Special Remarks on the
    partially volatilize from dry soil and photolyze on the soil surface. Based on the results of sceening tests, it would be
    Products of Biodegradation
    expected to readily biodregrade. Chemical hydrolysis may be important in alkaline soil. (SRC) [Peer Reviewed]
    2. AQUATIC FATE: Methyl salicylate is readily biodegradable in screening tests and may be expected to biodegrade
    in surface waters. Methyl salicylate is expected to hydrolyze in water, the hydrolysis rate increasing with pH. At pH
    7.5, its hydrolysis half-life is estimated to be 14.1days(1,2,SRC). Methyl salicylate will react with singlet oxygen in
    natural surface waters resulting in a half-life of about 52 hr(3). Methyl salicylate absorbs UV radiation >290 nm and
    therefore may undergo direct photolysis under environmental conditions. Based on an estimated Henry's Law constant
    of 9.3X10-7 atm-cu-m/mol(4,5,SRC), a volatilization half-life of 49 days would be expected in a model river(SRC).
    [Peer Reviewed] [(1) Magid LJ, Larsen JW; J Org Chem 39: 3142-4 (1974) (2) Senent S et al; An Quim; 69:13-23
    (1973) (3) Scully FE Jr, Hoigne J; Chemosphere 16: 681-94 (1987) (4) Daubert TE, Danner RP; Data Compilation
    Tables of Properties of Pure Compounds NY, NY: Amer Inst for Phys Prop Data (1989) (5) Riddick JA et al; Organic
    Solvents 4th ed; NY, NY: Wiley (1986) ]
    3. ATMOSPHERIC FATE: Methyl salicylate reacts with photochemically-produced hydroxyl radicals in the
    atmosphere resulting in an estimated half-life of 1.4 days(1,SRC). It is fairly soluble in water, 7400 mg/L(2)and
    may be washed out by rain. [Peer Reviewed] [(1) Meylan WM, Howard PH; Chemosphere 26: 2293-9 (1993) (2)
    Riddick JA et al; Organic Solvents 4th ed; NY, NY: Wiley (1986)]
    Biodegradation:
    Methyl salicylate in a five day BOD test exhibited a value of 55-57% of the theoretical BOD(1,2). Another 5-day
    BODdetermination yielded 65% of the theoretical BOD(3). Methyl salicylate was completely degraded by a microbial
    mixture when incubated for 7 days at 30 deg C(4). Significant biodegradation of methyl salicylate in the environment
    would be expected from this result; however no data concerning biodegradation in natural waters or soil could be
    located. [Peer Reviewed] [(1) Maggio P et al; Ind Carta 14:105-11 (1976) (2) Maggio P et al; Tinctoria 73:15-20
    (1976) (3) Crespi-Rosell M, Cegarra-Sanchez J; Bol Inst Invest Text Coop Ind 77: 41-57 (1980) (4) Goulding C et al;
    J Appl Bact 65: 1-5 (1988)]
    (The above information was obtained from the Hazardous Substance Bank)
    (Methyl salicylate)

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Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental control    
    regulations.

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Section 14. Transport Information
    Not a DOT controlled material (United States).
    DO T Cl assi fi cati on
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    DO T (Pi ctograms)
    Wintergreen Oil, Natural

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Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Wintergreen Oil, Natural
    Federal and State
    Regulations
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    California
    cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
    204-317-7).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Not listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    WHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC).
    Other Classifications
    R22- Harmful if swallowed.        S26- In case of contact with eyes, rinse    
    DSCL (EEC)
    R36/38- Irritating to eyes and skin.        immediately with plenty of water and seek    
    medical advice.
    S37- Wear suitable gloves.
    S46- If swallowed, seek medical advice
    immediately and show this container or label.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    1 Flammability
    1 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    h
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG(Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Wintergreen Oil, Natural
    Vapor respirator. Be sure to use an
    approved/certified respirator or equivalent.
    Wear appropriate respirator when ventilation
    is inadequate.

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SECTION 16 - ADDITIONAL INFORMATION
N/A