(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇,22422-34-0，生产厂家，价格-洛克化工网移动版

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇

中文名称：: (1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇

中文别名：: (1R,2R,3S,5R)-(-)-2,3-蒎烷二醇;
(1R,2R,3S,5R)-2,6,6-三甲基二环[3.1.1]庚-2,3-二醇;
(1R,2R,3S,5R)-(-)-蒎二醇;
(1R,2R,3S,5R)-(-)-蒎烷二醇;
(1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇;
三甲基庚烷二醇

英文名称：: Bicyclo[3.1.1]heptane-2,3-diol,2,6,6-trimethyl-, (1R,2R,3S,5R)-

英文别名：: (1R,3S,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptane-3,4-diol;
(1R,2R,3S,5R)-(-)-Pinanediol;
(1R,2R,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol;
Pinanediol [INCI];
(-)-2,3-Pinanediol;
(-)-pinane-2,3-diol;
(-)-(1R,2R,3S,5R)-pinane-2,3-diol;
(1R,2R,3S,5R)-(-)-2,3-Pinanediol;
(-)-cis-Pinane-cis-2,3-diol;
(1R,2R,3S,5R)-2,6,6-trimethylbicyclo[3.3.1]heptane-2,3-diol;
(-)-pinanediol;
(1R,2R,3S,4R)-2,6,6-trimethylcyclo[3.1.1]heptane-2,3-diol;
[1R-(1|A,2|A,3|A,5|A)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol;
(1R,2R,3S,5R)-2,3-Pinanediol;
(1R,2R,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-2,3-diol;
(-)-2-Hydroxyisopinocampheol

CAS No.：: 22422-34-0

分子式：: C₁₀H₁₈O₂

分子量：: 170.25

精确分子量：: 170.13100

PSA：: 40.46000

MDL：: MFCD00010365

BRN：: 2039144

InChI：: InChI=1/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8-,10+/m0/s13

风险术语：: S24/25

安全术语：: S24/25

分子结构式：

SDS：: 查看

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇物化性质

外观与性状：: 白色结晶固体
密度：: 1.091g/cm3
熔点：: 55-59ºC
沸点：: 101-102ºC (1 mmHg)
闪点：: 120.9ºC
折射率：: 1.52
蒸汽压：: 0.001mmHg at 25°C
存储条件/存储方法：: 密闭于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：55-59

5.       沸点（ºC,常压）：101-102/1mmHg

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：-8.5（C=6.5,甲苯）

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇安全信息

海关代码：: 2942000000
危险类别码：: R36/37/38
安全说明：: S24/25
安全标志：: S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。
危险标志：: Xi

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇 MSDS

Name:	(1R 2R 3S 5R)-(-)-2 3-Pinanediol 98% Material Safety Data Sheet
Synonym:
CAS:	22422-34-0

Section 1 - Chemical Product MSDS Name:(1R 2R 3S 5R)-(-)-2 3-Pinanediol 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
22422-34-0	(1R,2R,3S,5R)-(-)-2,3-Pinanediol	98%	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 22422-34-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 101 - 102 deg C @ 1mmHg
Freezing/Melting Point: 57 - 59 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H18O2
Molecular Weight: 170.25

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 22422-34-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(1R,2R,3S,5R)-(-)-2,3-Pinanediol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 22422-34-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22422-34-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22422-34-0 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇分子结构与计算化学数据

分子结构数据

1、摩尔折射率：47.45

2、摩尔体积（m³/mol）：156.0

3、等张比容（90.2K）：389.2

4、表面张力（dyne/cm）：38.7

5、极化率（10^-24cm³）：18.81

计算化学数据

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇上游产品

(1S)-(-)-α-蒎烯 α-蒎烯 (1S,2S,5S)-(-)-2-羟基-3-蒎烷酮; (1S,2S,5S)-2-羟基-2,6,6-三甲基-双环[3.1.1]庚-3-酮无水乙醚

(1R,2R,3S,5R)-(-)-2,3-蒎烷二醇; (1R-(1alpha,2beta,3beta,5alpha))-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇下游产品

(+)-烯丙基硼酸频那二醇酯