(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷,60419-23-0，生产厂家，价格-洛克化工网移动版

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷

中文名称：: (R)-(-)-1-(2-吡咯烷基甲基)吡咯烷

中文别名：: (R)-(-)-1-(2-吡咯烷基甲基)吡咯烷;
(1S,4R)-4-hydroxycyclopent-2-en-1-yl acetate;
(1R,4S)-4-hydroxycyclopent-2-en-1-yl acetate;
(1S,4R)-CIS-cis-4-acetoxy-2-cyclopenten-1-ol;
(1R,3S)-4-Cyclopentene-1,3-diol 1-acetate;
(1S,4R)-cis-4-Acetoxy-2-cyclopenten-1-ol;
1-BENZYL-PIPERIDIN-3-YLAMINE;
Proconazole;
Propiconazole Tilt;
Wocosin;
Propiconazole E.C.;
(1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole;
1-{[2-(2,4-dichlorophenyl)-4-propyl-1,3-diox

英文名称：: Pyrrolidine,1-[(2R)-2-pyrrolidinylmethyl]-

英文别名：: (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine;
1-[[(2R)-pyrrolidin-2-yl]methyl]pyrrolidine

CAS No.：: 60419-23-0

分子式：: C₉H₁₈N₂

分子量：: 154.25

精确分子量：: 154.14700

PSA：: 15.27000

InChI：: InChI=1/C9H18N2/c1-2-7-11(6-1)8-9-4-3-5-10-9/h9-10H,1-8H2/p+2/t9-/m1/s13

风险术语：: 22

分子结构式：

SDS：: 查看

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷物化性质

密度：: 0.975 g/cm3
沸点：: 265.8ºC at 760 mmHg
闪点：: 87.8ºC

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷 MSDS

(R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine Revision number: 5
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 4
  Flammable liquids
  HEALTH HAZARDS
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statements        Combustible liquid
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Keep away from flames and hot surfaces.
  [Prevention]
    Wash hands thoroughly after handling.
    Wear protective gloves and eye/face protection.
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.
  [Storage]        Store in a well-ventilated place. Keep cool.
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine
  Percent:        >98.0%(GC)(T)
    60419-23-0
  CAS Number:
  Chemical Formula:        C9H18N2
  (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take
    measures to prevent the build up of electrostatic charge. Use explosion-proof
    equipment. Wash hands and face thoroughly after handling.
    Use a closed system, ventilation.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
    Keep container tightly closed. Store in a cool, dark and well-ventilated place.
  Storage conditions:
    Store under inert gas.
    Store away from incompatible materials such as oxidizing agents.
    Air-sensitive
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
  Form:        Clear
  Colour:        Colorless - Slightly pale yellow
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        No data available
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
  [Water]        No data available
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
    Open flame
  Conditions to avoid:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
    No data available
  Crustacea:
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobility in soil
    No data available
  Log Pow:
  Soil adsorption (Koc):        No data available
    No data available
  Henry's Law
  constant(PaM3/mol):
  (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值（XlogP）:0.9

2.氢键供体数量:1

3.氢键受体数量:2

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积15.3

7.重原子数量:11

8.表面电荷:0

9.复杂度:119

10.同位素原子数量:0

11.确定原子立构中心数量:1

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷上游产品

(9CI)-1-[(2R)-2-吡咯烷羰基]-吡咯烷 N-Boc-D-脯氨酸 (5R)-5-(1-吡咯烷基羰基)-2-吡咯烷酮 D-焦谷氨酸

(R)-(-)-1-(2-吡咯烷基甲基)吡咯烷下游产品

(2R)-1-[[5-[(Z)-[5-[[(2,6-二氯苯基)甲基]磺酰]-1,2-二氢-2-氧代-3H-吲哚-3-亚基]甲基]-2,4-二甲基-1H-吡咯-3-基]羰基]-2-(1-吡咯烷甲基)吡咯烷