哒螨灵,96489-71-3，生产厂家，价格-洛克化工网移动版

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基本信息

制备方法及用途

物化性质

安全信息

毒理性

MSDS

海关数据

结构与计算化学

上游产品

表征图谱

哒螨灵

中文名称：: 哒螨灵

中文别名：: 哒螨灵;
哒螨净;
特螨酮;
速螨酮;
2-特丁基-5-(4-特丁基苄硫基)-4-氯-2H-哒嗪-3-酮;
达螨灵：扫螨净;
哒螨酮;
速螨灵;
2-特丁基-5-(4-特丁基苄硫基-4-氯-3(H)-哒嗪-3-酮

英文名称：

英文别名：: pyridaben;
NCI 129;
2-tert-butyl-4-chloro-5-(4-tert-butyl-benzylthio)-3(2H)-pyridazinone;
2-tert-butyl-5-[(4-tert-butylphenyl)methylsulfanyl]-4-chloropyridazin-3-one;
Sanmite;
2-tert-butyl-5-{[(4-tert-butylphenyl)methyl]sulfanyl}-4-chloropyridazin-3(2H)-one;
Pyridaben;
4-chloro-2-(1,1-dimethylethyl)-5-(((4-(1,1-dimethylethyl)phenyl)methyl)thio)-3(2H)-pyridazinone;
2-t-butyl-5-(p-t-butylbenzylthio)-4-chloro-3(2H)-pyridazinone;
4-chloro-2-(1,1-dimethylethyl)-5-[[[4-(1,1-dimethylethyl)phenyl]methyl]thio]-3(2H)-pyridazinone;
Pyridaben [ISO];
2-tert-butyl-5-(4-tert-butylbenzylthio)-4-chloropyridazin-3(2H)-one

CAS No.：: 96489-71-3

分子式：: C₁₉H₂₅ClN₂OS

分子量：: 364.939

精确分子量：: 364.13800

PSA：: 60.19000

MDL：: MFCD00274601

EINECS：: 405-700-3

BRN：: 7933972

InChI：: InChI=1/C19H25ClN2OS/c1-18(2,3)14-9-7-13(8-10-14)12-24-15-11-21-22(19(4,5)6)17(23)16(15)20/h7-11H,12H2,1-6H33

风险术语：: 23/25-50/53

SDS：: 查看

哒螨灵制备方法及用途

制备方法

1.对特丁基基苄硫醇的制备对特丁基甲苯在偶氮二异丁腈存在下，于68～72℃通氯氯化6h，得对特丁基氯苄；然后将精制的对特丁基氯苄以甲苯为溶剂，在四丁基溴化铵和醋酸的存在下，滴加23%硫氢化钠水溶液，滴毕后于50℃继续反应30min，经后处理得对特丁基苄硫醇，收率92%。2.2-特丁基-4，5-二氯-3-（2H）-哒嗪酮的制备将糠醛与浓盐酸混合，于90～100℃通氯气氯化，得糠氯酸，收率87%；将盐酸肼与特丁基醇于82～105℃反应得特丁基肼盐酸盐，收率97%；然后将特丁基肼盐酸盐溶于5%NaOH溶液，于0～5℃加长糠氯酸四氢呋喃溶液反应30min，再升温至10～15℃反应30min，得糖氯酸特丁基腙，收率87%；再在苯和醋酸存在下，糠氯酸特丁基腙加热至35～45℃，反应4h，缩合、环合生成2-特丁基-4，5-二氯-3（2H）-哒嗪酮，收率98%。3.哒螨灵的合成将2-特丁基-4，5-二氢-3（2H）-哒嗪酮和对特丁基苄硫醇，以甲醇为溶剂，再在0℃加入甲醇钠甲醇溶液，于10～15℃搅拌反应1h，经后处理得哒螨灵，m.p.111～112℃，收率96%。制备方法二制备方法三

合成制备方法

1.对特丁基基苄硫醇的制备对特丁基甲苯在偶氮二异丁腈存在下，于68～72℃通氯氯化6h，得对特丁基氯苄；然后将精制的对特丁基氯苄以甲苯为溶剂，在四丁基溴化铵和醋酸的存在下，滴加23%硫氢化钠水溶液，滴毕后于50℃继续反应30min，经后处理得对特丁基苄硫醇，收率92%。
2. 2-特丁基-4，5-二氯-3-（2H）-哒嗪酮的制备将糠醛与浓盐酸混合，于90～100℃通氯气氯化，得糠氯酸，收率87%；将盐酸肼与特丁基醇于82～105℃反应得特丁基肼盐酸盐，收率97%；然后将特丁基肼盐酸盐溶于5%NaOH溶液，于0～5℃加长糠氯酸四氢呋喃溶液反应30min，再升温至10～15℃反应30min，得糖氯酸特丁基腙，收率87%；再在苯和醋酸存在下，糠氯酸特丁基腙加热至35～45℃，反应4h，缩合、环合生成2-特丁基-4，5-二氯-3（2H）-哒嗪酮，收率98%。
3.哒螨灵的合成将2-特丁基-4，5-二氢-3（2H）-哒嗪酮和对特丁基苄硫醇，以甲醇为溶剂，再在0℃加入甲醇钠甲醇溶液，于10～15℃搅拌反应1h，经后处理得哒螨灵，m.p.111～112℃，收率96%。

制备方法二

制备方法三

用途简介

为广谱、触杀性杀螨杀虫剂，用于棉花、柑橘、果树等经济作物上防治螨类害虫。

用途

为广谱、触杀性杀螨杀虫剂，用于棉花、柑橘、果树等经济作物上防治螨类害虫，防治果树、棉花、小麦、花生、蔬菜等作物上各种螨虫。

哒螨灵物化性质

外观与性状：
白色固体

密度：
1.12 g/cm3

熔点：
111-112ºC

沸点：
429.9ºC at 760 mmHg

闪点：
213.8ºC

折射率：
1.564

存储条件/存储方法：
密封储存，储存于阴凉、干燥的库房。远离热源，火焰。

稳定性相关：

常温常压下稳定，避免与强氧化剂接触。对眼和皮肤无刺激性，对豚鼠皮肤无致敏性。

其它信息：

1.      性状：黄褐色有微弱香草气味粉末
2.      密度（g/mL,25℃）：1.22
3.      相对蒸汽密度（g/mL,空气=1）：未确定
4.      熔点（ºC）：111～112
5.      沸点（ºC,常压）：430
6.      沸点（ºC，2mmHg）：未确定
7.      折射率(n20/D)：未确定
8.      闪点（ºC）：214
9.      比旋光度（º）：未确定
10.   自燃点或引燃温度（ºC）：394
11.   蒸气压（mmHg,20ºC）：未确定
12.   饱和蒸气压（kPa,25ºC）：未确定
13.   燃烧热（KJ/mol）：68.5
14.   临界温度（ºC）：未确定
15.   临界压力（KPa）：未确定
16.   油水（辛醇/水）分配系数的对数值：未确定
17.   爆炸上限（%,V/V）：未确定
18.   爆炸下限（%,V/V）：未确定
19.   溶解性：不溶于水

哒螨灵安全信息

包装等级：
II

风险类别：
6.1(a)

海关代码：
2933399027

危险类别码：
R23/25;R50/53

安全说明：
S36/37-S45-S60-S61

RTECS号：
UR6149000

安全标志：
S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。
:

危险标志：
T:Toxic;N:Dangerousfortheenvironment;

哒螨灵毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UR6149000

CHEMICAL NAME :
3(2H)-Pyridazinone, 4-chloro-2-(1,1-dimethylethyl)-5-(((4-(1,1-dimethylet hyl)phenyl)methyl) thio)-

CAS REGISTRY NUMBER :
96489-71-3

LAST UPDATED :
199606

DATA ITEMS CITED :
14

MOLECULAR FORMULA :
C19-H25-Cl-N2-O-S

MOLECULAR WEIGHT :
364.97
HEALTH HAZARD DATA
ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
570 mg/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :
Inhalation

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
620 mg/m3

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (63),12,1993

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
>2 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C269,1991

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
58100 ug/kg

TOXIC EFFECTS :
Behavioral - muscle weakness Lungs, Thorax, or Respiration - respiratory depression Skin and Appendages - hair

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
205 mg/kg

TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Skin and Appendages - hair

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - rabbit

DOSE/DURATION :
>2 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (63),12,1993 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
3494 mg/kg/2Y-C

TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :
Inhalation

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
10 mg/m3/6H/4W-I

TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
983 mg/kg/13W-C

TOXIC EFFECTS :
Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
5242 mg/kg/78W-C

TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Mammal - dog

DOSE/DURATION :
364 mg/kg/13W-I

TOXIC EFFECTS :
Gastrointestinal - changes in structure or function of salivary glands Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Mammal - dog

DOSE/DURATION :
1484 mg/kg/53W-I

TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S243,1994 ** REPRODUCTIVE DATA **

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
300 mg/kg

SEX/DURATION :
female 6-15 day(s) after conception

TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects Reproductive - Effects on Embryo or Fetus - extra-embryonic structures (e.g., placenta, umbilical cord) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S203,1994

TYPE OF TEST :
TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :
Oral

DOSE :
210 mg/kg

SEX/DURATION :
female 6-19 day(s) after conception

TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects

REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 19,S203,1994

毒理学数据：

雄大鼠急性经口LD50为1350mg/kg,雌性为820mg /kg;小鼠急性经口358-435mg/kg;大鼠急性吸入工_(、为0. 62-0. 66mg/L;大鼠和兔急LD50>2000mg /kg 。2年慢性毒性试验为28mg/kg.Ames、试验、DNA修复、离体染色体畸变、小鼠微核试验均为阴性。鹤鹑急性经口LD50>2250mg /kg >野鸭为2500mg /kg >鲤鱼LC50 < 0.5mg/L(48h)>蜜蜂经口LD50为0.55μg/只(24h).

哒螨灵 MSDS

Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
  Product identifiers
    Product name        : Pyridaben
    CAS-No.        : 96489-71-3
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances



Section 2. HAZARDS IDENTIFICATION
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
    Acute toxicity, Inhalation (Category 3)
    Acute toxicity, Oral (Category 3)
    Acute aquatic toxicity (Category 1)
    Chronic aquatic toxicity (Category 1)
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Toxic by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects
    in the aquatic environment.
  Label elements
  Labelling according Regulation (EC) No 1272/2008 [CLP]
    Pictogram
    Signal word        Danger
    Hazard statement(s)
    H301        Toxic if swallowed.
    H331        Toxic if inhaled.
    H410        Very toxic to aquatic life with long lasting effects.
    Precautionary statement(s)
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
    P273        Avoid release to the environment.
    P301 + P310        IF SWALLOWED: Immediately call a POISON CENTER or doctor/
    physician.
    P311        Call a POISON CENTER or doctor/ physician.
    P501        Dispose of contents/ container to an approved waste disposal plant.
    Supplemental Hazard        none
    Statements
  According to European Directive 67/548/EEC as amended.
    Hazard symbol(s)
    R-phrase(s)
    R23/25        Toxic by inhalation and if swallowed.
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in
    the aquatic environment.
    S-phrase(s)
    S36/37        Wear suitable protective clothing and gloves.
    S45        In case of accident or if you feel unwell, seek medical advice immediately
    (show the label where possible).
    S60        This material and its container must be disposed of as hazardous waste.
    S61        Avoid release to the environment. Refer to special instructions/ Safety
    data sheets.
  Other hazards - none

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substances
    Formula        : C19H25ClN2OS
    Molecular Weight        : 364,93 g/mol
    Component        Concentration
  2-tert-Butyl-5-(4-tert-butylbenzylthio)-4-chloro-pyridazine-3(2H)-one
    CAS-No.        96489-71-3        -
    EC-No.        405-700-3
    Index-No.        613-149-00-7

Section 4. FIRST AID MEASURES
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
  Indication of any immediate medical attention and special treatment needed
    no data available

Section 5. FIREFIGHTING MEASURES
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas
    Nature of decomposition products not known.
    Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    no data available

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions, protective equipment and emergency procedures
    Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate
    ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
    Provide appropriate exhaust ventilation at places where dust is formed.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
  Specific end uses
    no data available

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
    the product.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
    respirator type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to engineering
    controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
    respirators and components tested and approved under appropriate government standards such
    as NIOSH (US) or CEN (EU).

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Information on basic physical and chemical properties
    a) Appearance        Form: solid
    b) Odour        no data available
    c) Odour Threshold        no data available
    d) pH        no data available
    e) Melting point/freezing        no data available
    point
    f) Initial boiling point and no data available
    boiling range
    g) Flash point        no data available
    h) Evaporation rate        no data available
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available
    flammability or
    explosive limits
    k) Vapour pressure        no data available
    l) Vapour density        no data available
    m) Relative density        no data available
    n) Water solubility        no data available
    o) Partition coefficient: n- no data available
    octanol/water
    p) Autoignition        no data available
    temperature
    q) Decomposition        no data available
    temperature
    r) Viscosity        no data available
    s) Explosive properties        no data available
    t) Oxidizing properties        no data available
  Other safety information
    no data available

Section 10. STABILITY AND REACTIVITY
  Reactivity
    no data available
  Chemical stability
    no data available
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    no data available
  Incompatible materials
    Strong oxidizing agents
  Hazardous decomposition products
    Other decomposition products - no data available

Section 11. TOXICOLOGICAL INFORMATION
  Information on toxicological effects
  Acute toxicity
    LD50 Oral - mouse - 205 mg/kg
    Remarks: Behavioral:Somnolence (general depressed activity). Respiratory disorder Skin and
    Appendages: Other: Hair.
    LC50 Inhalation - rat - 620 mg/m3
    LD50 Dermal - rabbit - > 2.000 mg/kg
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitization
    no data available
  Germ cell mutagenicity
    no data available
  Carcinogenicity
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    Reproductive toxicity - rat - Oral
    Maternal Effects: Other effects. Effects on Embryo or Fetus: Extra embryonic structures (e.g., placenta,
    umbilical cord). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Potential health effects
  Inhalation
    Toxic if inhaled. May cause respiratory tract irritation.
  Ingestion        Toxic if swallowed.
  Skin
    May be harmful if absorbed through skin. May cause skin irritation.
  Eyes        May cause eye irritation.
  Additional Information
    RTECS: UR6149000

Section 12. ECOLOGICAL INFORMATION
  Toxicity
    Toxicity to fish        LC50 - Oncorhynchus mykiss (rainbow trout) - 0,72 µg/l - 96,0 h
    Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0,53 µg/l - 48 h
    other aquatic
    invertebrates
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    no data available
  Other adverse effects
    Very toxic to aquatic life with long lasting effects.

Section 13. DISPOSAL CONSIDERATIONS
  Waste treatment methods
  Product
    Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
  Contaminated packaging
    Dispose of as unused product.

Section 14. TRANSPORT INFORMATION
  UN number
    ADR/RID: 3077        IMDG: 3077        IATA: 3077
  UN proper shipping name
    ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-tert-Butyl-5-(4-tert-
    butylbenzylthio)-4-chloro-pyridazine-3(2H)-one)
    IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-tert-Butyl-5-(4-tert-
    butylbenzylthio)-4-chloro-pyridazine-3(2H)-one)
    IATA:        Environmentally hazardous substance, solid, n.o.s. (2-tert-Butyl-5-(4-tert-butylbenzylthio)-4-
    chloro-pyridazine-3(2H)-one)
  Transport hazard class(es)
    ADR/RID: 9        IMDG: 9        IATA: 9
  Packaging group
    ADR/RID: III        IMDG: III        IATA: III
  Environmental hazards
    ADR/RID: yes        IMDG Marine pollutant: yes        IATA: yes
  Special precautions for user
  Further information
    EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
    packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

Section 15. REGULATORY INFORMATION
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
    no data available
  Chemical Safety Assessment
    no data available

Section 16. OTHER INFORMATION
  Further information
    Copyright 2012 Co. LLC. License granted to make unlimited paper copies for internal use
    only.
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

哒螨灵海关数据

中国海关编码：2933399027

概述：

2933399027 甲基毒死蜱,吡虫啉等〔包括吡氯氰菊酯,啶蜱脲,氟啶脲,哒幼酮,吡丙醚〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

申报要素：

品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

监管条件：

S.进出口农药登记证明

摘要/Summary：

2933399027 2-(tert-butyl)-5-((4-(tert-butyl)benzyl)thio)-4-chloropyridazin-3(2h)-one。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

哒螨灵分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值（XlogP）:5.2
2.氢键供体数量:0
3.氢键受体数量:3
4.可旋转化学键数量:5
5.互变异构体数量:无
6.拓扑分子极性表面积58
7.重原子数量:24
8.表面电荷:0
9.复杂度:535
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:1

哒螨灵上游产品

对叔丁基氯苄 4-氯-2-(1,1-二甲基乙基)-5-疏基-3(2H)-吡嗪酮对叔丁基溴苄

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哒螨灵

哒螨灵 制备方法及用途

制备方法

合成制备方法

用途简介

用途

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哒螨灵 安全信息

哒螨灵 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

哒螨灵 MSDS

哒螨灵 海关数据

中国海关编码：2933399027

哒螨灵 分子结构与计算化学数据

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