S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物,503538-70-3，生产厂家，价格-洛克化工网移动版

S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物

中文名称：: S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物

中文别名：: S-(+)-5,5'-双(二苯基磷)-2,2,2',2'-四氟-4,4'-二-1,3-苯并二氧二氯甲烷络合物;
5,5'-双(二苯基磷)-四氟-二-1,3-苯二氧杂环;
S-(+)-5,5'-双(二苯基磷)-2,2,2',2'-四氟-4,4'-二-1,3-苯并二氧二氯甲烷络合物T

英文名称：: Phosphine,1,1'-[(4S)-2,2,2',2'-tetrafluoro[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-diphenyl-

英文别名：: (R)-[4,4'-bi(2,2-difluoro-1,3-benzodioxol)-5,5'-diyl]bis(diphenylphosphane);
S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE, DICHLOROMETHANE ADDUCT;
(R)-DIFLUORPHOS;
S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE,DICHLOROMETHANEADDUCT;
S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE, DICHLOROMETHANE ADDUCT, (S)-DIFLUORPHOS;
(R)-FluorPhos

CAS No.：: 503538-70-3

分子式：: C₃₈H₂₄F₄O₄P₂

分子量：: 682.54

精确分子量：: 682.10900

PSA：: 64.10000

InChI：: The Key: HGMLTMOEYCQDDR-UHFFFAOYSA-N3

风险术语：: R36/37/38

安全术语：: S26 S36/S37/S39

分子结构式：

SDS：: 查看

S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物物化性质

存储条件/存储方法：: 密封于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物 MSDS

Section 1: Product Identification
   S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min.
   Chemical Name:
   97% (S)-DIFLUORPHOS™
   CAS Registry Number:       503538-70-3
   Formula:       C38H24F4O4P2.xCH2Cl2
   EINECS Number:       none
   Chemical Family:       organophosphine ligand
   Synonym:       None

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 503538-70-3 100% 2.5mg/m3 (as F) 2.5mg/m3 (as F)

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
   Primary Routes of Exposure:       Ingestion, inhalation
   Eye Contact:       Irritating to eyes
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       May be harmful if swallowed. No information available on the physiological effects of ingestion.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate
   Chronic Health Affects:       fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth
   structure and kidney and liver damage.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
   Store in a tightly sealed container under an inert atmopshre of nitrogen or argon. Prolonged exposure to the
   Handling and Storage:
   atmosphere may lead to degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       White pwdr.
   Molecular Weight:       682.54
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       slight odor
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air sensitive solid
   Hazardous Polymerization:       none
   Conditions to Avoid:       Prolonged contact with the atmosphere. Contact with strong oxidizing agents
   Incompatibility:       strong oxidizing agents, halogens
   carbon dioxide, carbon monoxide, phosphorus pentoxide, fluorinated organics, nitrogen oxides, and organic
   Decomposition Products:
   fumes.

SECTION 11: Toxicological Information
   RTECS Data:       No data available in the RTECS files.
   Carcinogenic Effects:       No data available
   Mutagenic Effects:       No data available
   Tetratogenic Effects:       No data available

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory
   SARA (Title 313):       not reportable under SARA Title (313)
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

S-(+)-5,5-双(二苯基磷)-2,2,2,2-四氟-4,4-二-1,3-苯并二氧二氯甲烷络合物分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用