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Section 1. Chemical Product and Company Identification
    Calamine
    Common Name/
    Trade Name
    Calamine

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Section 4. First Aid Measures
    Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least
    Eye Contact
    15 minutes. Get medical attention if irritation occurs.
    Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
    Skin Contact
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Not available.
    Serious Inhalation
    Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
    Ingestion
    unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms
    appear.
    Not available.
    Serious Ingestion

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Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Not applicable.
    Flash Points
    Not applicable.
    Flammable Limits
    Not available.
    Products of Combustion
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards in
    Risks of explosion of the product in presence of static discharge: Not available.
    Presence of Various
    Substances
    Not applicable.
    Fire Fighting Media
    and Instructions
    Slow addition of zinc oxide to cover linseed oil varnish causes generation of heat and ignition.
    Special Remarks on
    Fire Hazards
    May explode when mixed with chlorinated rubber.
    Special Remarks on
    Zinc Oxide and Magnesium can react explosively when heated.
    Explosion Hazards

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Section 6. Accidental Release Measures
    Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading
    Small Spill
    water on the contaminated surface and dispose of according to local and regional authority requirements.
    Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on
    Large Spill
    the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not
    present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
    Calamine

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Section 7. Handling and Storage
    Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear
    Precautions
    suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label.
    Keep container tightly closed. Keep container in a cool, well-ventilated area.
    Storage

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Section 8. Exposure Controls/Personal Protection
    Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
    Engineering Controls
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.    
    Personal Protection in Case Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to
    avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE
    of a Large Spill
    handling this product.
    Exposure Limits        Zinc oxide    
    TWA: 5 STEL: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation
    TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total.
    TWA: 5 STEL: 10 CEIL: 25 (mg/m3) from NIOSH Inhalation
    TWA: 5 STEL: 10 (mg/m3) from OSHA (PEL) [United States] Inhalation Respirable.
    Ferric oxide
    TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation Total.
    TWA: 5 (mg/m3) from ACGIH (TLV) [United States] Inhalation Respirable.
    TWA: 4 (mg/m3) [United Kingdom (UK)] Inhalation Respirable.
    TWA: 10 (mg/m3) [Canada] Inhalation Total.
    TWA: 5 (mg/m3) [Canada] Inhalation Respirable.
    TWA: 10 (mg/m3) [United Kingdom (UK)] Inhalation Total.
    Consult local authorities for acceptable exposure limits.

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Section 9. Physical and Chemical Properties
    Solid. (Powdered solid.)        Odorless.    
    Physical state and        O dor    
    appearance
    Not available.
    Taste
    Not applicable.
    Molecular Weight
    Pink
    Color
    Not applicable.
    pH (1% soln/water)
    Not available.
    Boiling Point
    1975°C (3587°F) based on data for: Zinc oxide.
    Melting Point
    Not available.
    Critical Temperature
    The only known value is 5.607 (Water = 1) (Zinc oxide).
    Specific Gravity
    Not applicable.
    Vapor Pressure
    Not available.
    Vapor Density
    Not available.
    Volatility
    Not available.
    Odor Threshold
    Not available.
    Water/Oil Dist. Coeff.
    Not available.
    Ionicity (in Water)
    Not available.
    Dispersion Properties
    Insoluble in cold water, hot water.
    Solubility
    Soluble in dilute acetic acid or mineral acid, ammonia, ammonium carbonate, and fixed alkali hydroxide solution
    Calamine

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Section 10. Stability and Reactivity Data
    The product is stable.
    Stability
    Not available.
    Instability Temperature
    Conditions of Instability Incompatible materials
    Incompatibility with various Not available.
    substances
    Non-corrosive in presence of glass.
    Corrosivity
    Reacts violently with magnesium, linseed oil.
    Special Remarks on
    Reacts with hydrochloric acid to produce zinc chloride.
    Reactivity
    Reacts with sulfuric acid to produce zinc sulfate.
    Reacts with hydrogen fluoride to produce zinc fluoride tetrahydrate.
    Gradually absorbs CO2 on exposure to air.
    Sublimes at normal pressure.
    Zinc Oxide reacts with Carbon Monoxide or hydrogen to produce elemental zinc.
    Not available.
    Special Remarks on
    Corrosivity
    Will not occur.
    Polymerization

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Section 11. Toxicological Information
    Inhalation. Ingestion.
    Routes of Entry
    Acute oral toxicity (LD50): 7950 mg/kg [Mouse]. (Zinc oxide).
    Toxicity to Animals
    Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Ferric oxide].
    Contains material which may cause damage to the following organs: lungs, eyes.
    Other Toxic Effects on        Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.    
    Humans
    Not available.
    Special Remarks on
    Toxicity to Animals
    Special Remarks on        May cause adverse reproductive effects based on animal data. No human data found at this time.    
    Chronic Effects on Humans May affect genetic material (mutagenic).
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        May cause mild skin irritation.    
    Eyes: May cause mechanical eye irritation and conjunctivitis.
    Inhalation: May cause mechanical irritation of the respiratory tract. A few sources claim that finely divided zinc oxide
    dust can cause "metal fume fever." Zinc oxide dust is generally considered a nuisance dust; adverse effects are
    unlikely when exposures are kept under reasonable control. Inhalation of high concentrations of Zinc Oxide fume or
    dust may cause "Metal Fume Fever." Symptoms of metal fume fever may include a flu-like condition involving
    headache, chills, fever, sweats, nausea, vomiting, cough, muscle aches and pains, and difficulty breathing, ;ulmonary
    edema. May also affect the liver.
    Ingestion: May cause digestive tract irritation although Zinc oxide has a low toxicity by oral exposure route.
    Chronic Potential Health Effects:
    Ingestion: Prolonged or repeated ingestion of zinc oxide may affect blood, metabolism, and the thyroid.

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Section 12. Ecological Information
    Not available.
    Ecotoxicity
    Not available.
    BOD5 and COD
    Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    arise.
    The product itself and its products of degradation are not toxic.
    Toxicity of the Products
    of Biodegradation
    Calamine
    Not available.
    Special Remarks on the
    Products of Biodegradation

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Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental control    
    regulations.

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Section 14. Transport Information
    Not a DOT controlled material (United States).
    DO T Cl assi fi cati on
    Not applicable.
    Identification
    Not applicable.
    Special Provisions for
    Transport
    DO T (Pi ctograms)

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Section 15. Other Regulatory Information and Pictograms
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    Federal and State
    cause birth defects which would require a warning under the statute: No products were found.
    Regulations
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause cancer which would require a warning under the statute: No products were found.
    Illinois toxic substances disclosure to employee act: Zinc oxide; Ferric oxide
    New York acutely hazardous substances: Ferric oxide
    Rhode Island RTK hazardous substances: Zinc oxide
    Pennsylvania RTK: Zinc oxide; Ferric oxide
    Minnesota: Zinc oxide; Ferric oxide
    Massachusetts RTK: Zinc oxide; Ferric oxide
    New Jersey: Zinc oxide
    California Director's List of Hazardous Substances: Zinc Oxide; Ferric Oxide
    TSCA 8(b) inventory: Zinc oxide; Ferric oxide
    SARA 313 toxic chemical notification and release reporting: Zinc oxide 99% (Listed as Zinc and Zinc compounds)
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    California
    cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause birth defects which would require a warning under the statute: No products were found.
    For Zinc Oxide:
    Other Regulations
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
    2i5-222-5).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    For Calamine:
    EINECS: This product is not on the European Inventory of Existing Commercial Chemical Substances.
    Canada: Not listed on Canadian Domestic Substance List (DSL) or Canadian Non- Domestic Substance List (NDSL).
    China: Listed on National Inventory.
    Japan: Not listed on National Inventory (ENCS).
    Korea: Not listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Not listed on AICS.
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)
    Calamine
    R50/53- Very toxic to aquatic        S60- This material and its container must be    
    organisms, may cause long-term        disposed of as hazardous waste.    
    adverse effects in the aquatic        S61- Avoid release to the environment. Refer to    
    environment.        special instructions/Safety data sheets.    
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG(Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or equivalent.
    Safety glasses.

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SECTION 16 - ADDITIONAL INFORMATION
N/A