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Name:
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Mercuric trifluoroacetate 98% Material Safety Data Sheet
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Synonym:
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Trifluoroacetic acid, mercury(II) sal
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CAS:
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13257-51-7
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Section 1 - Chemical Product
MSDS Name:Mercuric trifluoroacetate 98% Material Safety Data Sheet
Synonym:Trifluoroacetic acid, mercury(II) sal
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
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CAS#
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Chemical Name
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content
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EINECS#
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13257-51-7
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Mercuric trifluoroacetate, 98%
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98%
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236-250-4
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Hazard Symbols: T+
Risk Phrases: 26/27/28 33
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause liver and kidney damage. May cause perforation of the digestive tract. May cause vascular collapse and damage. Causes severe pain, nausea, vomiting, diarrhea, and shock. May cause central nervous system effects.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated inhalation of dusts may cause neurological damage. May cause liver and kidney damage. May cause reproductive and fetal effects. May cause tremors, irritability, loss of memory and intellect. May also cause Pink disease characterized by skin, cardiovascular, and neurobehavioral abnormalities.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
Handling:
Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Poison room locked.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 13257-51-7: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds): mg/m3 VLE (as Hg) France - VME: (listed as mercury, aryl and inorganic compounds): mg/m3 VME (as Hg) Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m VME (as Hg) Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1 mg/m3 TWA (as Hg) Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/ VLA-ED (as Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: @ 760.00mm Hg
Freezing/Melting Point: 171 - 173 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4F6O4Hg
Molecular Weight: 426.61
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas, mercury/mercury oxides.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13257-51-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Mercuric trifluoroacetate, 98% - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: II
IMO
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing Group: II
RID/ADR
Shipping Name: MERCURY COMPOUND, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 2025
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13257-51-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13257-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13257-51-7 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION N/A