Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II),863971-63-5，生产厂家，价格-洛克化工网移动版

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)

中文名称：: Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II)

中文别名：: [6-(二叔丁基膦亚甲基)-2-(N,N-二乙基氨基甲基)-1,6-二氢吡啶]羰基氢化钌;
米尔斯坦催化剂;
三(三苯基膦)羰基氢-[6]-2-(N-2-二乙胺基甲基咪唑)-1,6-二氢]盐(Ⅱ)

英文名称：: Ruthenium,[6-[[bis(1,1-dimethylethyl)phosphino-kP]methylene]-N,N-diethyl-1,6-dihydro-2-pyridinemethanaminato-kN1,kN2]carbonylhydro-, (SP-5-52)-

英文别名：: Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Milstein Catalyst;
Milstein Catalyst

CAS No.：: 863971-63-5

分子式：: C₂₀H₃₅N₂OPRu

分子量：: 451.55

精确分子量：: 452.15300

PSA：: 21.76000

InChI：: The Key: CYXMUFURMPCJIX-FDRCHMJRSA-N3

分子结构式：

SDS：: 查看

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) 物化性质

存储条件/存储方法：: 密封于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) 毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) MSDS

Section 1: Product Identification
   Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(I
   Chemical Name:
   I), min. 98% Milstein Catalyst
   CAS Registry Number:       863971-63-5
   Formula:       C20H35N2OPRu
   EINECS Number:       none
   Chemical Family:       organometallic complex
   Carbonylhydrido[2-(N,N-diethylaminomethyl)-6-(di-t-butylphosphanomethylene)-1,6-dihydropyridine]ruthenium
   Synonym:
   (II), min. 98%

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 863971-63-5 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract
   Primary Routes of Exposure:       Inhalation, skin, eyes
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes irritation to the skin
   Inhalation:       Causes irritation to the nose, mucous membranes and respiratory tract
   Ingestion:       No information on the physiological effects of ingestion. May be harmful if swallowed.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract
   Chronic Health Affects:       No information available on long-term chronic effects
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry chemical or foam
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, this material may emit toxic organic fumes
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store cold, in a tightly sealed container, under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       red-black solid
   Molecular Weight:       451.55
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       not determined
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air sensitive, store cold
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       oxidizing agents, halogens and active metals
   Decomposition Products:       carbon monoxide, carbon dioxide, ruthenium oxide and organic fumes

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files
   Carcinogenic Effects:       No data
   Mutagenic Effects:       No data
   Tetratogenic Effects:       No data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:7

5.互变异构体数量:无

6.拓扑分子极性表面积5.2

7.重原子数量:25

8.表面电荷:0

9.复杂度:439

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:1

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II) 上游产品

[(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine]Ru(hydride)2(carbonyl)