(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物,328123-04-2，生产厂家，价格-洛克化工网移动版

(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物

中文名称：: (4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物

中文别名：: (4R,5R)-(-)-2,2-二甲基-alpha,alpha,alpha’,alpha’-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV);
(4R,5R)-(-)-2,2-二甲基-ALPHA,ALPHA,ALPHA',ALPHA'-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV);
(4R,5r)-(-)-2,2-二甲基-alpha,alpha,alpha,alpha-四苯基-1,3-二氧戊环-4,5-d

英文名称：: (4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DIC

英文别名：: acetonitrile,cyclohexa-1,3-dien-1-yl-[(4R,5R)-5-[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-phenylmethanol,dichlorotitanium,1,2-dimethoxyethane;
(4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DIC;
(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV)dichlorideacetonitrileadduct;
(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato(1,2-bis(dimethoxy)ethane)titanium(IV) dichloride acetonitrile addu;
(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium (IV) dichloride;
(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct;
(4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct

CAS No.：: 328123-04-2

分子式：: C31H30Cl2O4Ti.C4H10O2.C2H3N

分子量：: 716.521

精确分子量：: 715.19500

PSA：: 79.17000

SDS：: 查看

(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物物化性质

存储条件/存储方法：: 密封于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物 MSDS

Section 1: Product Identification
   (4R,5R)-(-)-2,2-Dimethyl-alpha-alpha-alpha'-alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimeth
   Chemical Name:
   oxy)ethane]titanium (IV) dichloride acetonitrile adduct
   CAS Registry Number:       328123-04-2
   Formula:       [C31H28O4][C4H10O2]TiCl2.CH3CN
   EINECS Number:       none
   Chemical Family:       organometallic complex
   Synonym:       Tetraphenyl-TADDOL-DME-titaniumdichloride

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 328123-04-2 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. With moisture , may liberate irritating fumes of hydrogen chloride.
   Primary Routes of Exposure:       Inhalation, skin, eyes
   Eye Contact:       Dust and vapors cause moderate irritation of the eyes.
   Skin Contact:       Causes moderate irritation of the skin.
   Inhalation:       Inhalation causes irritation to the nose, mucous membranes and respiratory tract.
   Ingestion:       No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
   Acute Health Affects:       Exposure to moisture slowly produces hydrochloric acid. Irritating to skin, eyes and respiratory tract.
   Chronic Health Affects:       No information on long-term chronic effects.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam.
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with lime, sodium carbonate or other suitable non combustible neutralizing
   Spill and Leak Procedures:
   adsorbent and swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Exposure to the air or moisture will result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective gloves.
   Ventilation:       Handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.
   Molecular Weight:       673.45(714.50)
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air sensitive, moisture sensitive
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       strong oxidizing agents
   Decomposition Products:       carbon monoxide, carbon dioxide, hydrochloric acid, organic vapors, metal oxides

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       no data
   Mutagenic Effects:       no data
   Tetratogenic Effects:       no data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.
   SARA (Title 313):       Title compound not listed.
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

(4R,5R)-(-)-2,2-二甲基-α,α,α'',α''-四苯基-1,3-二氧戊环-4,5-二甲醇并[1,2-双(二甲氧基)乙烷]二氯化钛(IV)乙腈加合物分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1、疏水参数计算参考值（XlogP）：2.9

2、氢键供体数量：0

3、氢键受体数量：2

4、可旋转化学键数量：1

5、拓扑分子极性表面积（TPSA）：12.5

6、重原子数量：15

7、表面电荷：0

8、复杂度：213

9、同位素原子数量：0

10、确定原子立构中心数量：0

11、不确定原子立构中心数量：2

12、确定化学键立构中心数量：0

13、不确定化学键立构中心数量：0

14、共价键单元数量：1