(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I),205064-10-4，生产厂家，价格-洛克化工网移动版

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I)

中文名称：: (＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I)

中文别名：: (+)-1,2-双((2S,5S)-2,5-二甲基磷皂)苯(环辛二烯)铑(I)四氟硼酸盐;
NULL;
(+)-1,2-双[(2S,5S)-2,5-二甲基膦]苯(1,5-环辛二烯)铑(I)四氟硼酸盐

英文名称：: (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE

英文别名：: carbanide,(1Z,5Z)-cycloocta-1,5-diene,(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-ium-1-yl]phenyl]-2,5-dimethylphospholan-1-ium,rhodium(3+),trifluoroborane,fluoride;
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE;
(+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4;
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;
Bisdimethylphospholanobenzenecyclooctadienerhodium;
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-DUPHOS-Rh;
(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-DUPHOS-Rh;
(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]benzene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%

CAS No.：: 205064-10-4

分子式：: C26H40BF4P2Rh 4*

分子量：: 604.25

精确分子量：: 635.22400

PSA：: 27.18000

InChI：: The Key: FKGVQOXVEDXEEW-KZOFNLLLSA-N3

风险术语：: R36/37/38

SDS：: 查看

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I) 物化性质

存储条件/存储方法：: 密闭于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：固体

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I) 安全信息

危险类别码：: 36/37/38
安全说明：: 24/25

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I) 毒理性

生态数据：

通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I) MSDS

Section 1: Product Identification
   (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate, 98+%
   Chemical Name:
   (S,S)-Me-DUPHOS-Rh
   CAS Registry Number:       205064-10-4
   Formula:       Rh(C8H12)(C18H28P2)+ BF4-
   EINECS Number:       none
   Chemical Family:       organometallic complex
   Synonym:       none

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 205064-10-4 100% 2.5mg/m3 (as F) 2.5mg/m3 (as F)

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
   Primary Routes of Exposure:       Ingestion
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to skin, eyes and respiratory tract.
   Ingestion:       No information is available on the physiological effects of ingestion.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Chronic Health Affects:       No information available on long-term chronic effects.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
   The material will degrade on prolonged exposure to air. Store under an inert atmosphere of nitrogen or argon.
   Handling and Storage:
   Keep bottle tightly sealed and away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       red-orange xtl.
   Molecular Weight:       604.26
   Melting Point:       decomposes
   Boiling Point:       decomposes
   Vapor Pressure:       not applicable
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air-sensitive solid
   Hazardous Polymerization:       none
   Conditions to Avoid:       contact with air. This material may degrade on prolonged exposure to air and moisture.
   Incompatibility:       strong oxidizing agents
   Decomposition Products:       carbon dioxide, carbon monoxide, phosphorus pentoxide, organic fumes and fluorinated byproducts.

SECTION 11: Toxicological Information
   RTECS Data:       No data available
   Carcinogenic Effects:       No data available
   Mutagenic Effects:       No data available
   Tetratogenic Effects:       No data available

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory
   SARA (Title 313):       not regulated by Title 313
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

(＋)-1,2-双((2S，5S)-2,5-二甲基磷)苯并(1,5-环辛二烯)铑(I) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:36

8.表面电荷:2

9.复杂度:364

10.同位素原子数量:0

11.确定原子立构中心数量:4

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:2

14.不确定化学键立构中心数量:0

15.共价键单元数量:7