甲基乙拌磷,640-15-3，生产厂家，价格-洛克化工网移动版

甲基乙拌磷

中文名称：: 甲基乙拌磷

中文别名：: 甲基乙拌磷;
S-2-乙基硫代乙基-O,O-二甲基二硫代磷酸酯;
s-2-乙基硫代乙基-0,0-二甲基二硫代磷酸酯;
s-2-乙基硫代乙基-0，0-二甲基二硫代磷酸酯;
二甲硫吸磷标准液

英文名称：: THIOMETON

英文别名：: thiometon;
Dithiophosphorsaeure-S-(2-aethylmercapto-aethylester)-O,O'-dimethylester;
S-[2-(ethylthio)ethyl] O,O-dimethyl phosphorodithioate;
THIOMETON;
Ekatim;
Intration;
Ekatin;
2-ethylsulfanylethylsulfanyl-dimethoxy-sulfanylidene-λ5-phosphane;
S-2-ethylthioethyl O,O-dimethyl phosphorodithioate;
Ebicid;
S-[2-(ethylsulfanyl)ethyl] O,O-dimethyl phosphorodithioate;
Ekatin aerosol;
Intrathion;
Dithiomethon;
M-81;
Dithiometasystox;
Luxistelm;
dithiophosphoric acid S-(2-ethylsulfanyl-ethyl) ester O,O'-dimethyl ester

CAS No.：: 640-15-3

分子式：: C6H15O2PS3

分子量：: 246.35

精确分子量：: 245.99700

PSA：: 110.96000

EINECS：: 211-362-6

InChI：: The Key: OPASCBHCTNRLRM-UHFFFAOYSA-N3

风险术语：: R21; R25; R20/21

SDS：: 查看

甲基乙拌磷制备方法及用途

制备方法

可用二甲氧基二硫代磷酸盐与β-卤代乙基乙硫醚作用制取。

合成制备方法

可用二甲氧基二硫代磷酸盐与β-卤代乙基乙硫醚作用制取。

用途简介

20世纪50年代发现的有机磷内吸杀虫、杀螨剂，用于棉花、蔬菜等多种作物防治蚜虫、螨类、蓟马、蚧类、粉虱、叶蝉等害虫。制剂有乳油、颗粒剂、粉剂。

用途

20世纪50年代发现的有机磷内吸杀虫、杀螨剂，用于棉花、蔬菜等多种作物防治蚜虫、螨类、蓟马、蚧类、粉虱、叶蝉等害虫。制剂有乳油、颗粒剂、粉剂。

甲基乙拌磷物化性质

密度：: 1.209
熔点：: 19 °C
沸点：: 111~120(0.0133kPa)
闪点：: 70 °C
折射率：: 1.546
存储条件/存储方法：: 库房通风低温干燥,与食品原料分开储运
其它信息：: 1.       性状：。

2.       密度（g/mL,25/4℃）：

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：

5.       沸点（ºC,常压）：

6.       沸点（ºC,5.2kPa）：未确定

7.       折射率：未确定

8.       闪点（ºC）：

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（kPa,25ºC）：

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.    溶解性：。

甲基乙拌磷安全信息

包装等级：: II
风险类别：: 6.1(a)
海关代码：: 2930909062
WGK_Germany：: 3
德国有关水污染物质的分类清单
危险类别码：: 21-25-20/21
安全说明：: 36/37-45
安全标志：: S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
:
危险标志：: Xi

甲基乙拌磷毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TE4375000

CHEMICAL NAME :: Phosphorodithioic acid, S-(2-(ethylthio)ethyl) O,O-dimethyl ester

CAS REGISTRY NUMBER :: 640-15-3

BEILSTEIN REFERENCE NO. :: 1707379

LAST UPDATED :: 199612

DATA ITEMS CITED :: 22

MOLECULAR FORMULA :: C6-H15-O2-P-S3

MOLECULAR WEIGHT :: 246.36

WISWESSER LINE NOTATION :: 2S2SPS&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 20 mg/m3/4H

TOXIC EFFECTS :: Behavioral - tremor Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 179 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - convulsions or effect on seizure threshold Behavioral - excitement

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 30 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 38500 ug/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - convulsions or effect on seizure threshold Behavioral - excitement

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 37 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 34 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 36 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 20 mg/m3/4H

TOXIC EFFECTS :: Behavioral - tremor Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 70 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 442 mg/kg/78W-I

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes Liver - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 305 mg/kg/9W-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: Micronucleus test

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 155,131,1985 *** REVIEWS *** TOXICOLOGY REVIEW MZUZA8 Meditsinskii Zhurnal Uzbekistana. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1957- Volume(issue)/page/year: (8),90,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.1 mg/m3;Skin JAN 1993

甲基乙拌磷 MSDS

第一部分：化学品名称

甲基乙拌磷海关数据

中国海关编码：2930909062

概述：: 2930909062 丙溴磷、田乐磷、特丁硫磷等〔包括硫丙磷、地虫硫膦、乙硫磷、丙硫磷、甲基乙拌磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%
申报要素：: 品名, 成分含量, 用途
监管条件：: S.进出口农药登记证明
摘要/Summary：: 2930909062 s-((tert-butylthio)methyl) o,o-diethyl phosphorodithioate

甲基乙拌磷分子结构与计算化学数据

分子结构数据

1、摩尔折射率：63.46

2、摩尔体积（m³/mol）：200.2

3、等张比容（90.2K）：525.1

4、表面张力（dyne/cm）：47.2

5、极化率（10^-24cm³）：25.15

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:7

5.互变异构体数量:无

6.拓扑分子极性表面积101

7.重原子数量:12

8.表面电荷:0

9.复杂度:146

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

甲基乙拌磷上游产品

2-氯乙基乙基硫醚二甲基二硫代磷酸酯; O,O-二甲基二硫代磷酸酯乙硫醇钠

甲基乙拌磷下游产品

久效威亚砜 O,O-二甲基硫代磷酸乙基2-羟基乙基硫醚 2-乙硫基乙硫醇二甲基二硫代磷酸酯; O,O-二甲基二硫代磷酸酯

甲基乙拌磷表征图谱

甲基乙拌磷质谱(MS)