Date Updated: 13/FEB/2006
Version 1.4
Regulation (EC) No 1907/2006
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1 - Product and Company Information
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Product Name 1,3-DICHLORO-1,3-DIMETHYLDIALUMINOXANE,
0.5M SOLUTION IN TOLUENE
Product Number 414425
Company
Century Ba-Shi Building 22A-B,
200020 Shanghai
Technical Phone # 86-21-61415566
Fax 86-21-61415567
E-mail Address
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2 - Hazards Identification
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SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Highly flammable. Reacts violently with water. Toxic by
inhalation, in contact with skin and if swallowed. Causes burns.
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3 - Composition/Information on Ingredients
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Product Name CAS # EC no Annex I
Index Number
1,3-DICHLORO-1,3-DIMETHYLDIALUMINO 87043-37-6 None None
XANE,0.5M SOLUTION IN TOLUENE
Formula C2H6Al2Cl2O
Molecular Weight 170,9400 AMU
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4 - First Aid Measures
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AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
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5 - Fire Fighting Measures
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EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
Unsuitable: Do not use water.
SPECIAL RISKS
Specific Hazard(s): Extremely flammable. Vapor may travel
considerable distance to source of ignition and flash back.
Explosion Hazards: Vapor may travel considerable distance to
source of ignition and flash back. Container explosion may occur
under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
SPECIFIC METHOD(S) OF FIRE FIGHTING
Use water spray to cool fire-exposed containers.
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6 - Accidental Release Measures
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PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with an activated carbon adsorbent, take up and place in
closed containers. Transport outdoors. Ventilate area and wash
spill site after material pickup is complete.
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7 - Handling and Storage
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HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat,
sparks, and open flame. Store in a cool dry place.
Incompatible Materials: Do not allow contact with water
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8 - Exposure Controls / Personal Protection
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ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.
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9 - Physical and Chemical Properties
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pH N/A
BP/BP Range 111,000 °C
MP/MP Range N/A
Flash Point - 11,000 °C. Method: closed cup
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 0,8830 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
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10 - Stability and Reactivity
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STABILITY
Reactions to Avoid: Reacts violently with:
Materials to Avoid: Oxidizing agents, Water.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen chloride gas, Aluminum oxide.
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11 - Toxicological Information
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SIGNS AND SYMPTOMS OF EXPOSURE
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. Material is extremely destructive to tissue of the
mucous membranes and upper respiratory tract, eyes, and skin. To
the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Inhalation studies on toluene have demonstrated the development
of inflammatory and ulcerous lesions of the penis, prepuce, and
scrotum in animals. Exposure to and/or consumption of alcohol
may increase toxic effects.
ROUTE OF EXPOSURE
Multiple Routes: Harmful if swallowed, inhaled, or absorbed
through skin.
TARGET ORGAN INFORMATION
Brain. Bladder. Kidneys. Liver.
CONDITIONS AGGRAVATED BY EXPOSURE
May cause nervous system disturbances.
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12 - Ecological Information
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No data available.
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13 - Disposal Considerations
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SUBSTANCE DISPOSAL
Burn in a chemical incinerator equipped with an afterburner and
scrubber but exert extra care in igniting as this material is
highly flammable. Observe all federal, state, and local
environmental regulations.
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14 - Transport Information
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RID/ADR
UN#: 3399
Class: 4.3
PG: I
Subrisk: 3
Proper Shipping Name: Organometallic substance,
liquid, water-reactive, flammable
IMDG
UN#: 3399
Class: 4.3
PG: I
Subrisk: 3
Proper Shipping Name: Organometallic substance,
liquid, water-reactive, flammable
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3399
Class: 4.3
PG: I
Subrisk: 3
Proper Shipping Name: Organometallic substance,
liquid, water-reactive, flammable
Inhalation Packing Group I: No
Technical Name: Required
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15 - Regulatory Information
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CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F-C
Highly Flammable. Corrosive.
R-PHRASES: 11-14-23/24/25-34
Highly flammable. Reacts violently with water. Toxic by
inhalation, in contact with skin and if swallowed. Causes burns.
S-PHRASES: 16-26-36/37/39-45
Keep away from sources of ignition - no smoking. In case of
contact with eyes, rinse immediately with plenty of water and
seek medical advice. Wear suitable protective clothing, gloves,
and eye/face protection. In case of accident or if you feel
unwell, seek medical advice immediately (show the label where
possible).
Caution: Substance not yet fully tested (EU).
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16 - Other Information
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WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
模块 15 - 法规信息
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模块16 - 其他信息
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