Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II),374067-50-2，生产厂家，价格-洛克化工网移动版

Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II)

中文名称：: Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II)

中文别名：: 二乙酸根[(R)-2,2'-二[二(3,5-二甲苯基)膦基]-1,1'-联萘基]钌(II);
[(R)-(+)-2,2'-双[二(3,5-二甲基苯基)膦]-1,1'-联萘]钌二乙酸盐

英文名称：: Ruthenium, bis(acetato-kO,kO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]]-, (OC-6-22)- (9CI)

英文别名：: Ru(OCOCH3)2((S)-dm-binap);
DIACETATO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}RUTHENIUM(II) RU(OAC)2[(R)-XYLBINAP];
DIACETATO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}RUTHENIUM(II);
(R)-RU(OAC)2(DM-BINAP);
(R)-Ru(OAc)2(DM-BINAP)

CAS No.：: 374067-50-2

分子式：: C₅₆H₅₄O₄P₂Ru

分子量：: 954.04

精确分子量：: 954.25400

PSA：: 107.44000

MDL：: MFCD09753022

InChI：: The Key: IFUMNSKQNPECEY-UHFFFAOYSA-L3

分子结构式：

SDS：: 查看

Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II) 物化性质

存储条件/存储方法：: 密封于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II) 毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II) MSDS

Section 1: Product Identification
   Chemical Name:       Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
   CAS Registry Number:       374067-50-2
   Formula:       C56H54O4P2Ru
   EINECS Number:       none
   Chemical Family:       metal phosphine complex
   Synonym:       [RuOAc)2{(R)-xylbinap}]

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 374067-50-2 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.
   Primary Routes of Exposure:       Inhalation, skin, eyes
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes irritation to the skin
   Inhalation:       Causes irritation to the nose, mucous membranes and respiratory tract
   Ingestion:       No information on the physiological effects of ingestion. May be harmful if swallowed.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Chronic Health Affects:       No information available on long-term chronic effects
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       no data
   Explosion Limits:       no data
   Extinguishing Medium:       carbon dioxide, dry chemical or foam
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, this material may emit toxic organic fumes
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       dark brown powder
   Molecular Weight:       954.04
   Melting Point:       >100° (decomp)
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       not determined
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air sensitive
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       contact with air
   Incompatibility:       strong oxidizing agents
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorous pentoxide, organic fumes and ruthenium salts.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files
   Carcinogenic Effects:       no data
   Mutagenic Effects:       no data
   Tetratogenic Effects:       no data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

Diacetato{(R)-(+)-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl}ruthenium(II) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用