(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester,262280-14-8，生产厂家，价格-洛克化工网移动版

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester

中文名称：: (1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester

中文别名：: (1S,2S,4R)-N-Boc-1-氨基-2-羟基环戊烷-4-羧酸甲酯;
(1S,2S,4R)-N-BOC-1-氨基-2-羟基环戊烷-4-羧酸甲酯

英文名称：: Cyclopentanecarboxylicacid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-4-hydroxy-, methyl ester,(1R,3S,4S)-

英文别名：: methyl (1R,3S,4S)-3-hydroxy-4-[(2-methylpropan-2-yl)oxycarbonylamino]cyclopentane-1-carboxylate;
3-endo-bromo-1,7,7-trimethylbicyclo<2.2.1>heptan-2-one;
d-campho;
Bromocamphor;
(1S,2S,4R)-N-BOC-1-Amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester;
endo-3-Bromo-D-camph

CAS No.：: 262280-14-8

分子式：: C₁₂H₂₁NO₅

分子量：: 259.30

精确分子量：: 259.14200

PSA：: 84.86000

MDL：: MFCD02259721

InChI：: The Key: SSATZBUCOTXXGA-VGMNWLOBSA-N3

分子结构式：

SDS：: 查看

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester 物化性质

密度：: 1.16g/cm3
沸点：: 378ºC at 760mmHg
闪点：: 182.4ºC
折射率：: 1.491
蒸汽压：: 2.9E-07mmHg at 25°C
存储条件/存储方法：: 密闭于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.      性状：白色结晶性粉末
2.      密度（g/mL,25/4℃）：无可用
3.      相对蒸汽密度（g/mL,空气=1）：无可用
4.      熔点（ºC）：无可用
5.      沸点（ºC,常压）：无可用
6.      沸点（ºC,5.2kPa）：无可用
7.      折射率：无可用
8.      闪点（ºC）：无可用
9.      比旋光度（º）：无可用
10.   自燃点或引燃温度（ºC）：无可用
11.   蒸气压（kPa,25ºC）：无可用
12.   饱和蒸气压（kPa,60ºC）：无可用
13.   燃烧热（KJ/mol）：无可用
14.   临界温度（ºC）：无可用
15.   临界压力（KPa）：无可用
16.   油水（辛醇/水）分配系数的对数值：无可用
17.   爆炸上限（%,V/V）：无可用
18.   爆炸下限（%,V/V）：无可用
19.   溶解性：无可用

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester 安全信息

安全说明：: 24/25

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester 毒理性

生态数据：: 该物质对环境可能有危害，对水体应给予特别注意。

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester MSDS

Name:	(1S 2S 4R)-N-BOC-1-Amino-2-hydroxycyclopentane-4-carboxylic acid Material Safety Data Sheet
Synonym:	Methyl (1R,3S,4S)-N-BOC-3-amino-4-hydroxycyclopentanecarboxylate
CAS:	262280-14-8

Section 1 - Chemical Product MSDS Name:(1S 2S 4R)-N-BOC-1-Amino-2-hydroxycyclopentane-4-carboxylic acid Material Safety Data Sheet
Synonym:Methyl (1R,3S,4S)-N-BOC-3-amino-4-hydroxycyclopentanecarboxylate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
262280-14-8	(1S,2S,4R)-N-BOC-1-Amino-2-hydroxycycl	95%	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 262280-14-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H21NO5
Molecular Weight: 259.3

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 262280-14-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(1S,2S,4R)-N-BOC-1-Amino-2-hydroxycyclopentane-4-carboxylic - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 262280-14-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 262280-14-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 262280-14-8 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、

摩尔体积（cm³/mol）：无可用

3、

等张比容（90.2K）：无可用

4、

表面张力（dyne/cm）：无可用

5、

极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:0.7

2.氢键供体数量:2

3.氢键受体数量:5

4.可旋转化学键数量:5

5.互变异构体数量:2

6.拓扑分子极性表面积84.9

7.重原子数量:18

8.表面电荷:0

9.复杂度:323

10.同位素原子数量:0

11.确定原子立构中心数量:3

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

(1S,2S,4R)-N-Boc-1-amino-2-hydroxycyclopentane-4-carboxylic acid methyl ester 上游产品

重氮甲烷 (1R,3S,4S)-3-((tert-butoxycarbonyl)amino)-4-hydroxycyclopentanecarboxylic acid 二碳酸二叔丁酯 (1R-4S)-4-[[(1,1-二甲基乙氧基)羰基]氨基]- 2-环戊烯-1-羧酸甲酯