三(2-乙基己基)亚磷酸盐,301-13-3，生产厂家，价格-洛克化工网移动版

返回



基本信息

物化性质

安全信息

毒理性

MSDS

海关数据

结构与计算化学

上游产品

下游产品

三(2-乙基己基)亚磷酸盐

中文名称：: 三(2-乙基己基)亚磷酸盐

中文别名：: 亚磷酸三(2-乙基己基)酯;
三(2-乙基己基)亚磷酸酯;
三(2-乙基己基)亚磷酸盐

英文名称：: Phosphorous acid,tris(2-ethylhexyl) ester

英文别名：: tris(2-ethylhexyl) phosphite;
PHOSPHOROUS ACID TRIS(2-ETHYLHEXYL) ESTER;
JP 308;
EINECS 206-111-2;
Trioctyl Phosphite;
Phosphorous Acid Trioctyl Ester

CAS No.：: 301-13-3

分子式：: C₂₄H₅₁O₃P

分子量：: 418.63

精确分子量：: 418.35800

PSA：: 41.28000

EINECS：: 206-111-2

InChI：: The Key: ILLOBGFGKYTZRO-UHFFFAOYSA-N3

风险术语：: R36/37/38

安全术语：: S26 S36/S37/S39

分子结构式：

SDS：: 查看

三(2-乙基己基)亚磷酸盐物化性质

沸点：: 446.7ºC at 760mmHg
闪点：: 278.6ºC
其它信息：: 一、物性数据

性状：不可用

密度（g/mL,25/4℃）： 0.89

相对蒸汽密度（g/mL,空气=1）：不可用

熔点（ºC）：不可用

沸点（ºC,常压）：不可用

沸点（ºC,5.2kPa）：不可用

折射率：不可用

闪点（ºC）： 194

三(2-乙基己基)亚磷酸盐安全信息

海关代码：
2920901900

危险类别码：
36/37/38

安全说明：
S26-S36-S37-S39

安全标志：
S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

三(2-乙基己基)亚磷酸盐毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH2090000

CHEMICAL NAME :
Phosphorous acid, tris(2-ethylhexyl) ester

CAS REGISTRY NUMBER :
301-13-3

BEILSTEIN REFERENCE NO. :
1712332

LAST UPDATED :
199806

DATA ITEMS CITED :
9

MOLECULAR FORMULA :
C24-H51-O3-P
HEALTH HAZARD DATA
ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
6200 mg/kg

TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Behavioral - tremor

REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(12),51,1981

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :
Inhalation

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
>20 gm/m3

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
7600 mg/kg

TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Behavioral - tremor

REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(12),51,1981

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Oral

SPECIES OBSERVED :
Rodent - rabbit

DOSE/DURATION :
8500 mg/kg

TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - somnolence (general depressed activity) Behavioral - tremor

REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(12),51,1981

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :
Administration onto the skin

SPECIES OBSERVED :
Rodent - rabbit

DOSE/DURATION :
>5 gm/kg

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST :
LC - Lethal concentration

ROUTE OF EXPOSURE :
Inhalation

SPECIES OBSERVED :
Mammal - species unspecified

DOSE/DURATION :
>27500 ug/m3

TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(12),51,1981 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :
TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :
Inhalation

SPECIES OBSERVED :
Rodent - rat

DOSE/DURATION :
7 mg/m3/4H/22W-I

TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Blood - changes in leukocyte (WBC) count Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other oxidoreductases

REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(12),51,1981

毒理学数据：

二、毒理学数据：

急性毒性：不可用。

生态数据：

三、生态学数据：

1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

三(2-乙基己基)亚磷酸盐 MSDS

  Tris(2-ethylhexyl) Phosphite      Revision number: 5
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Tris(2-ethylhexyl) Phosphite

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
  Acute toxicity (Dermal)        Category 5
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statements        May be harmful in contact with skin
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Wash hands thoroughly after handling.
  [Prevention]
    Wear protective gloves/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
  [Response]
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.
    Call a POISON CENTER or doctor/physician if you feel unwell.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        Tris(2-ethylhexyl) Phosphite
  Percent:        >90.0%(GC)
  CAS Number:        301-13-3
    Phosphorous Acid Trioctyl Ester , Phosphorous Acid Tris(2-ethylhexyl) Ester ,
  Synonyms:
    Trioctyl Phosphite
  Chemical Formula:        C24H51O3P
  Tris(2-ethylhexyl) Phosphite

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Call a POISON CENTER or doctor/physician if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, carbon dioxide.
  media:
  Unsuitable extinguishing Water (It may scatter and spread fire.)
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapour or mist. Wash hands and face thoroughly after
    handling.
    Use a ventilation, local exhaust if vapour or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
    Keep container tightly closed. Store in a cool and dark place.
  Storage conditions:
    Store under inert gas.
    Protect from moisture.
    Store away from incompatible materials such as oxidizing agents.
    Moisture-sensitive
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Tris(2-ethylhexyl) Phosphite

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
    Clear
  Form:
  Colour:        Colorless - Very pale yellow
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        No data available
  Flash point:        194°C
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        0.89
  Solubility(ies):
  [Water]        No data available
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Phosphorus oxides
  products:

Section 11. TOXICOLOGICAL INFORMATION
    ihl-rat LC50:>20 g/m3
  Acute Toxicity:
    orl-rat LD50:6200 mg/kg
    skn-rbt LD50:>5 g/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available
  RTECS Number:        TH2090000

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
    No data available
  Fish:
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
    No data available
  Soil adsorption (Koc):
  Tris(2-ethylhexyl) Phosphite

Section 12. ECOLOGICAL INFORMATION
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations
    Not listed
  UN-No:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

三(2-乙基己基)亚磷酸盐海关数据

中国海关编码：2920901900

概述：

2920901900 亚磷酸酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途

摘要/Summary：

2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

三(2-乙基己基)亚磷酸盐分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值（XlogP）:9.5
2.氢键供体数量:0
3.氢键受体数量:3
4.可旋转化学键数量:21
5.互变异构体数量:无
6.拓扑分子极性表面积27.7
7.重原子数量:28
8.表面电荷:0
9.复杂度:267
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:3
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:1

三(2-乙基己基)亚磷酸盐上游产品

2-乙基-1-己醇己乙基亚磷三酰胺 tetraethyldiamidophosphorous acid ethyl ester

三(2-乙基己基)亚磷酸盐下游产品

9-(2-乙基己基)咔唑咔唑磷酸三辛酯氯代异辛烷 2-[bis(2-ethylhexoxy)phosphoryl]-N,N-diethylacetamide

推荐供应商

淄博航宇生物科技发展有限公司

三(2-乙基己基)亚磷酸盐
联系人：张经理
电  话：15666366704
手  机：15666366704
Cas号：301-13-3
包装：100kg
纯度：99%
价格：洽谈
湖北齐飞医药化工有限公司

亚磷酸三异辛酯
联系人：汪军蕊（微信同号）
电  话：027-59322506
手  机：18071128683
Cas号：301-13-3
包装：170kg
纯度：99%
价格：洽谈
南京德为奇化工科技有限公司

亚磷酸三异辛酯
联系人：陶陶
电  话：0571-87562561
手  机：15851804510
Cas号：301-13-3
包装：1kg
纯度：
价格：20.0元
湖北沃德化工科技有限公司

抗氧剂1608
联系人：彭振兴
电  话：15972179313
手  机：15972179313
Cas号：301-13-3
包装：25kg
纯度：99
价格：洽谈
青岛真光功能材料科技有限公司

抗氧剂608
联系人：刘女士
电  话：0532-81159002
手  机：16678624618
Cas号：301-13-3
包装：170 桶kg
纯度：98
价格：85.0元
武汉琼格生物科技有限公司

亚磷酸三(2-乙基己基)酯
联系人：时燕
电  话：027-84235681
手  机：13657207535
Cas号：301-13-3
包装：500ml,500ml,500ml,500ml,500ml
纯度：>90.0%(GC)
价格：3,580.0元 - 3,580.0元
成都市华祥化工贸易有限公司

磷酸三辛酯
联系人：郑超
电  话：86-028-68228894
手  机：13457227573
Cas号：301-13-3
包装：洽谈
纯度：
价格：洽谈
成都市智远化工贸易有限公司

磷酸三辛酯
联系人：郭嘉铭
电  话：0138-80444828
手  机：
Cas号：301-13-3
包装：洽谈
纯度：
价格：洽谈
上海开拓实业有限公司

磷酸三辛酯
联系人：赵宏飞
电  话：021-33191237
手  机：13764077054
Cas号：301-13-3
包装：洽谈
纯度：
价格：洽谈
武汉鸿达化工贸易有限公司

磷酸三辛酯
联系人：王杰
电  话：027-62369182
手  机：13720389239
Cas号：301-13-3
包装：洽谈
纯度：
价格：洽谈

三(2-乙基己基)亚磷酸盐

三(2-乙基己基)亚磷酸盐 物化性质

三(2-乙基己基)亚磷酸盐 安全信息

三(2-乙基己基)亚磷酸盐 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

三(2-乙基己基)亚磷酸盐 MSDS

三(2-乙基己基)亚磷酸盐 海关数据

中国海关编码：2920901900

三(2-乙基己基)亚磷酸盐 分子结构与计算化学数据

计算化学数据

三(2-乙基己基)亚磷酸盐 上游产品

三(2-乙基己基)亚磷酸盐 下游产品

推荐供应商

淄博航宇生物科技发展有限公司

三(2-乙基己基)亚磷酸盐

湖北齐飞医药化工有限公司

亚磷酸三异辛酯

南京德为奇化工科技有限公司

亚磷酸三异辛酯

湖北沃德化工科技有限公司

抗氧剂1608

青岛真光功能材料科技有限公司

抗氧剂608

武汉琼格生物科技有限公司

亚磷酸三(2-乙基己基)酯

成都市华祥化工贸易有限公司

磷酸三辛酯

成都市智远化工贸易有限公司

磷酸三辛酯

上海开拓实业有限公司

磷酸三辛酯

武汉鸿达化工贸易有限公司

磷酸三辛酯

三(2-乙基己基)亚磷酸盐物化性质

三(2-乙基己基)亚磷酸盐安全信息

三(2-乙基己基)亚磷酸盐毒理性

三(2-乙基己基)亚磷酸盐海关数据

三(2-乙基己基)亚磷酸盐分子结构与计算化学数据

三(2-乙基己基)亚磷酸盐上游产品

三(2-乙基己基)亚磷酸盐下游产品