Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct,212143-24-3，生产厂家，价格-洛克化工网移动版

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct

中文名称：: Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct

中文别名：: 二氯[(S)-(-)-2,2'-二(二苯基膦基)-1,1'-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)二氯甲烷加合物;
(2S)-1,1-bis(4-methoxyphenyl)-3-methyl-butane-1,2-diamine, dichlo roruthenium, [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-dip henyl-phosphane

英文名称：: Ruthenium,[(1S)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-kP]][(2S)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine-kN,kN']dichloro-, (OC-6-14)- (9CI)

英文别名：: (2S)-1,1-bis(4-methoxyphenyl)-3-methyl-butane-1,2-diamine, dichlo roruthenium, [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-dip henyl-phosphane;
RuCI2[(R)-BINAP][(R)-DAIPEN];
Dichloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl][(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);
RuCI2[(S)-BINAP][(S)-DAIPEN]

CAS No.：: 212143-24-3

分子式：: C₆₃H₅₈Cl₂N₂O₂P₂Ru

分子量：: 1109.07

精确分子量：: 1108.24000

PSA：: 97.68000

InChI：: The Key: ZVVRWLPQKLDJRW-OGLOXHGMSA-L3

安全术语：: S22 S24/25

分子结构式：

SDS：: 查看

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct 物化性质

存储条件/存储方法：: 密闭于0-6 ºC阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct 安全信息

安全说明：: S22-S24/25

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct 毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct MSDS

Section 1: Product Identification
   Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-b
   Chemical Name:
   utanediamine]ruthenium (II) dichloromethane adduct, min
   CAS Registry Number:       212143-24-3
   Formula:       C63H58Cl2N2O2P2Ru
   EINECS Number:       none
   Chemical Family:       organometallic complex
   Synonym:       Ruthenium [(S)-BINAP] [(S)-DAIPEN]

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 212143-24-3 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       No particular hazard associated with this material.
   Primary Routes of Exposure:       Ingestion
   Eye Contact:       May cause irritation to the eyes
   Skin Contact:       May cause slight to mild irritation of the skin.
   Inhalation:       Inhalation is an unlikely source of exposure.
   Ingestion:       No information is available on the physiological effects of ingestion.
   Other than a possible irritant, no information is available on the acute health effects of exposure to this
   Acute Health Affects:
   material.
   Chronic Health Affects:       No information available on long-term chronic effects.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
   The material will degrade on prolonged exposure to air. Store under an inert atmosphere of nitrogen or argon.
   Handling and Storage:       Keep bottle tightly sealed and away from heat and direct sunlight. For prolonged storage keep material
   refrigerated.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to pale yellow powder
   Molecular Weight:       1109.10
   Melting Point:       >100° (dec)
   Boiling Point:       decomposes
   Vapor Pressure:       not applicable
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air-sensitive solid (store cold)
   Hazardous Polymerization:       none
   Conditions to Avoid:       none
   Incompatibility:       strong oxidizing agents
   carbon dioxide, carbon monoxide, hydrogen chloride, phosphorus pentoxide, nitrogen oxides, organic fumes,
   Decomposition Products:
   and ruthenium salts

SECTION 11: Toxicological Information
   RTECS Data:       No data available in the RTECS files
   Carcinogenic Effects:       No data available
   Mutagenic Effects:       No data available
   Tetratogenic Effects:       No data available

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory
   SARA (Title 313):       not regulated by Title 313
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

Dichloro[(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) dichloromethane adduct 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:3

3.氢键受体数量:3

4.可旋转化学键数量:7

5.互变异构体数量:2

6.拓扑分子极性表面积50.4

7.重原子数量:24

8.表面电荷:0

9.复杂度:353

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2