N-BOC-氨基-(4-N-BOC-哌啶基)羧酸,189321-65-1，生产厂家，价格-洛克化工网移动版

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸

中文名称：: N-BOC-氨基-(4-N-BOC-哌啶基)羧酸

中文别名：: 1-Boc-4-(Boc-氨基)哌啶-4-甲酸;
N-BOC-氨基-(4-N-BOC-哌啶基)羧酸

英文名称：: 1,4-Piperidinedicarboxylicacid, 4-[[(1,1-dimethylethoxy)carbonyl]amino]-, 1-(1,1-dimethylethyl) ester

英文别名：: 1-[(2-methylpropan-2-yl)oxycarbonyl]-4-[(2-methylpropan-2-yl)oxycarbonylamino]piperidine-4-carboxylic acid;
4-[[N-(tert-butyloxycarbonyl)amino]methyl]benzoic acid;
4-(tert-butyloxycarbonylamino)methyl benzoic acid;
BOC-(4-AMINOMETHYL)-BENZOIC ACID;
N-Boc-amino-(4-N-Boc-piperidinyl)carboxylic acid;
1-((benzyloxy)carbonyl)-4-((tert-butoxycarbonyl)amino)piperidine-4-carboxylic acid;
4-t-butoxycarbonylaminomethylbenzoic acid;
4-(((tert-butoxycarbonyl)amino)methyl)benzoic acid;
N-BOC-Amino-(4-N-BOC-piperidinyl)carboxylic acid;
4-carboxy-N-t-butoxycarbonylbenzylamine;
4-TERT-BUTOXYCARBONYLAMINO-PIPERIDINE-1,4-DICARBOXYLICACIDMONO-TERT-BUTYLESTER;
4-tert-Butoxycarbonylamino-piperidine-1,4-dicarboxylic acid monobenzyl ester;
4-[N-(tert-butoxycarbonyl)aminomethyl)benzoic acid;
4-TERT-BUTOXYCARBONYLAMINO-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER;
1-(tert-butoxycarbonyl)-4-(tert-butoxycarbonylamino)-4-piperidinecarboxylic acid;
1-(tert-Butoxycarbonyl)-4-((tert-butoxycarbonyl)amino)piperidine-4-carboxylic acid;
1-Boc-4-(Boc-amino)piperidine-4-carboxylic Acid;
1-(tert-butoxycarbonyl)-4-(tert-butoxycarbonylamino)piperidine-4-carboxylic acid;
Boc-Pamb-OH;
1-Boc-4-(Boc-amino)-4-piperidinecarboxylic acid;
1-benzyloxycarbonyl-4-(t-butoxycarbonylamino)piperidin-4-carboxylic acid;
Boc-(N4Boc)Pip-OH

CAS No.：: 189321-65-1

分子式：: C₁₆H₂₈N₂O₆

分子量：: 344.4

精确分子量：: 344.19500

PSA：: 105.17000

MDL：: MFCD02683116

InChI：: InChI=1/C16H28N2O6/c1-14(2,3)23-12(21)17-16(11(19)20)7-9-18(10-8-16)13(22)24-15(4,5)6/h7-10H2,1-6H3,(H,17,21)(H,19,20)/p-13

危险品标志：

风险术语：: R36/37/38

安全术语：: S26 S37/S39

分子结构式：

SDS：: 查看

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸物化性质

密度：: 1.18 g/cm3
沸点：: 482.6ºC at 760 mmHg
闪点：: 245.7ºC
蒸汽压：: 1.22E-10mmHg at 25°C
存储条件/存储方法：: 密闭于0-6 ºC阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：无可用

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸安全信息

危险类别码：: R36/37/38
安全说明：: 37/39-26
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:
危险标志：: Xi: Irritant;

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸毒理性

生态数据：

通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸 MSDS

Name:	N-BOC-Amino-(4-N-BOC-Piperidinyl)Carboxylic Acid 95% Material Safety Data Sheet
Synonym:	None Known
CAS:	189321-65-1

Section 1 - Chemical Product MSDS Name:N-BOC-Amino-(4-N-BOC-Piperidinyl)Carboxylic Acid 95% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
189321-65-1	N-BOC-Amino-(4-N-BOC-Piperidinyl)Carbo	95%	unlisted

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 189321-65-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C16H28N2O6
Molecular Weight: 344.2058

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 189321-65-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-BOC-Amino-(4-N-BOC-Piperidinyl)Carboxylic Acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 189321-65-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 189321-65-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 189321-65-1 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸分子结构与计算化学数据

分子结构数据

1、摩尔折射率：87.00

2、摩尔体积（m³/mol）：289.4

3、等张比容（90.2K）：758.0

4、表面张力（dyne/cm）：47.0

5、极化率（10^-24cm³）：34.49

计算化学数据

1.疏水参数计算参考值（XlogP）:1.8

2.氢键供体数量:2

3.氢键受体数量:6

4.可旋转化学键数量:6

5.互变异构体数量:2

6.拓扑分子极性表面积105

7.重原子数量:24

8.表面电荷:0

9.复杂度:496

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

N-BOC-氨基-(4-N-BOC-哌啶基)羧酸上游产品

1-tert-butyl 4-methyl 4-(tert-butoxycarbonylamino)piperidine-1,4-dicarboxylate 二碳酸二叔丁酯 4-氨基-1Boc-哌啶-4-羧酸