(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基,185913-97-7，生产厂家，价格-洛克化工网移动版

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基

中文名称：: (R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基

中文别名：: (R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基;
R(+)-5,5' - 二氯-6,6'-双(DIPHE.PHOS)2,2' - 二甲氧基联苯;
(+)-(5,5′-二氯-6,6′-二甲氧基-1,1′-联苯基)-2,2′-二基-双(二苯基膦);
(+)-2,2′-双(二苯基膦)-5,5′-二氯-6,6′-二甲氧基-1,1′-联苯;
(S)-(+)-5,5′-二氯-2,2′-双(二苯基膦)-6,6′-二甲氧基-1,1′-联苯

英文名称：: Phosphine,1,1'-[(1R)-5,5'-dichloro-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-

英文别名：: (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL;
(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5'-DICHLORO-6,6'-DIMETHOXY-1,1'-BIPHENYL;
MeO-Cl-PHEP;
Cl-MeO-BIPHEP;
min.(r)-cl-meo-biphep;
(S)-(-)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL;
(R)-CL-MEO-BIPHEP;
(-)-5,5'-DICHLORO-2,2'-BIS(DIPHENYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL;
(+)-5,5'-DICHLORO-2,2'-BIS(DIPHE.PHOS)6,6'-DIMETHOXYBIPHENYL;
[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]-bis-diphenylphosphine;
(S)-CL-MEO-BIPHEP;
(5,5'-dichloro-6,6'-dimethoxybiphenyl-2,2'-diyl)-bisdiphenylphosphine

CAS No.：: 185913-97-7

分子式：: C₃₈H₃₀Cl₂O₂P₂

分子量：: 651.50

精确分子量：: 650.11000

PSA：: 45.64000

MDL：: MFCD03426987

InChI：: The Key: GCBRCSSVOVNEIX-UHFFFAOYSA-N3

安全术语：: S24/25

分子结构式：

SDS：: 查看

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基物化性质

熔点：: 176-180ºC
存储条件/存储方法：: 密封于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.       性状：无可用

2.       密度（g/mL,25/4℃）：无可用

3.       相对蒸汽密度（g/mL,空气=1）：无可用

4.       熔点（ºC）：176-180

5.       沸点（ºC,常压）：无可用

6.       沸点（ºC,5.2kPa）：无可用

7.       折射率：无可用

8.       闪点（ºC）：无可用

9.       比旋光度（º）：无可用

10.    自燃点或引燃温度（ºC）：无可用

11.    蒸气压（kPa,25ºC）：无可用

12.    饱和蒸气压（kPa,60ºC）：无可用

13.    燃烧热（KJ/mol）：无可用

14.    临界温度（ºC）：无可用

15.    临界压力（KPa）：无可用

16.    油水（辛醇/水）分配系数的对数值：无可用

17.    爆炸上限（%,V/V）：无可用

18.    爆炸下限（%,V/V）：无可用

19.    溶解性：无可用

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基安全信息

安全说明：: S24/25
安全标志：: S24/25:防止皮肤和眼睛接触。

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基毒理性

生态数据：

通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基 MSDS

Section 1: Product Identification
   (R)-(+)-5,5'-Dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl, min. 95% (R)-Cl-MeO-BIPHEP
   Chemical Name:
   CAS Registry Number:       185913-97-7
   Formula:       C38H30Cl2O2P2
   EINECS Number:       none
   Chemical Family:       organophosphine ligand
   Synonym:       (R)-Cl-MeO-BIPHEP

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 185913-97-7 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes, and respiratory tract. May be harmful if swallowed.
   Primary Routes of Exposure:       Ingestion, eyes
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       May be harmful if swallowed. No specific information is available on the physiological effects of ingestion.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Chronic Health Affects:       No information available on long-term chronic effects.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow-white powder
   Molecular Weight:       651.5
   Melting Point:       178°
   Boiling Point:       no data
   Vapor Pressure:       not applicable
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       oxidizing agents
   Decomposition Products:       carbon dioxide, carbon monoxide, phosphorus pentoxide, and organic fumes.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       no data
   Mutagenic Effects:       no data
   Tetratogenic Effects:       no data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.
   SARA (Title 313):       Title compound not listed.
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

(R)-(+)-5,5-二氯-6,6-二甲氧基-2,2-双(二苯基磷酸)-1,1-联苯基分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、摩尔体积（cm³/mol）：无可用

3、等张比容（90.2K）：无可用

4、表面张力（dyne/cm）：无可用

5、极化率：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:10.1

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:9

5.互变异构体数量:无

6.拓扑分子极性表面积18.5

7.重原子数量:44

8.表面电荷:0

9.复杂度:735

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1