Section 1: Product Identification
Chemical Name: Di-2-norbornylphosphine, min. 98% (mixture of endo and exo isomers)
CAS Registry Number: 148432-44-4
Formula: (C7H11)2PH
EINECS Number: none
Chemical Family: organophosphine ligand
Synonym: none
Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 148432-44-4 100% no data no data
Section 3: Hazards Identification
Harmful by inhalation, in contact with skin and if swallowed. Material has a pungent odor. Inhalation of vapors
Emergency Overview:
may lead to headache and dizziness.
Primary Routes of Exposure: Ingestion, inhalation, skin
Eye Contact: May cause mild to severe irritation of the eyes.
Skin Contact: Liquid may burst in to flame in air, causing thermal burns to skin. Harmful in contact with skin.
The material has a pungent odor. Harmful by inhalation. Inhalation may lead to headaches, dizziness and
Inhalation:
irritation of the respiratory tract.
Ingestion: Harmful if swallowed. May cause vomiting and diarrhea.
Harmful by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory
Acute Health Affects:
tract.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: Pyrophoric
Explosion Limits: Pyrophoric
Extinguishing Medium: carbon dioxide, dry powder or foam.
The pyrophoric liquid may reignite. Fire fighters should be equipped with an approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: Material is pyrophoric. May spontaneously ignite if exposed to air.
SECTION 6: Accidental Release Measures
Material may spontaneously ignite. Spillage in areas not adequately ventilated will require evacuation of site.
Spill and Leak Procedures: Emergency response teams will require self-contained breathing apparatus. Small spills can be mixed with
vermiculite or other suitable absorbents and placed in a sealed metal can.
SECTION 7: Handling and Storage
Handling and Storage: Material must be handled and stored under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material has a pungent odor. Always handle in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material has a pungent odor. Always handle in an efficient fume hood.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless liquid
Molecular Weight: 222.31
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: pungent odor
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air-sensitive, pyrophoric
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Keep away from moisture, air, heat and ignition sources including open flame and electrostatic discharge.
Incompatibility: oxidizing agents and halogens
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Pyrophoric liquids, organic, N.O.S.
Hazard Class (CFR): 4.2
Additional Hazard Class (CFR): NA
Packaging Group (CFR): I
UN ID Number (CFR): UN# 2845
Shipping Name (IATA): Forbidden
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
SECTION 16 - ADDITIONAL INFORMATION
N/A
