2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物),139220-25-0，生产厂家，价格-洛克化工网移动版

2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物)

中文名称：: 2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物)

中文别名：: 2，6-二异丙基苯酰亚胺新值二烯双己基叔丁醇钼;
2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物);
2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(VI)双(六氟叔丁醇化物)

英文名称：: 2,6-diisopropylphenylimido neophylidenemolybdenum(Ⅵ)bis(hexafluoro-t-butoxide)

英文别名：: [2,6-di(propan-2-yl)phenyl]imino-(2-methyl-2-phenylpropylidene)molybdenum,1,1,1,3,3,3-hexafluoro-2-methylpropan-2-ol;
Mo(N(2,6-iPrC6H3))(CHCMe2Ph)(OCMe(CF3)2)2;
{(2-methyl-2-phenyl-propylidene)((2,6-diisopropylphenyl)imido)molybdenum(VI)bis(hexafluoro-tert-butoxide)};
SCHROCK'S CATALYST;
2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) ?SCHROCK'S CATALYST;
Mo(N-2,6-iPr2C6H3)(CHCMe2Ph)(OCMe(CF3)2)2;
2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI) BIS(HEXAFLUORO-T-BUTOXIDE);
(2,6-diisopropylphenylimidoneophylidenemolybdenium (VI) bis(hexafluorotert-butoxide))

CAS No.：: 139220-25-0

分子式：: C₃₀H₃₅NO₂F₁₂Mo

分子量：: 765.53

精确分子量：: 767.15300

PSA：: 30.82000

InChI：: The Key: SREMDTDVHCUUIZ-UHFFFAOYSA-N3

风险术语：: R36/37/38

安全术语：: S26 S36/S37/S39

分子结构式：

SDS：: 查看

2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物) 物化性质

其它信息：: 1.        性状：未确定

2.         密度（g/mL,20℃）：未确定

3.         相对蒸汽密度（g/mL,空气=1）：未确定

4.         熔点（ºC）：未确定

5.         沸点（ºC,常压）：未确定

6.         沸点（ºC, KPa）：未确定

7.         折射率：未确定

8.         闪点（ºC）：未确定

9.         比旋光度（º）：未确定

10.      自燃点或引燃温度（ºC）：未确定

11.      蒸气压（Pa,20ºC）：未确定

12.      饱和蒸气压（KPa,20ºC）：未确定

13.      燃烧热（KJ/mol）：未确定

14.      临界温度（ºC）：未确定

15.      临界压力（KPa）：未确定

16.      油水（辛醇/水）分配系数的对数值：未确定

17.      爆炸上限（%,V/V）：未确定

18.      爆炸下限（%,V/V）：未确定

19.       溶解性：未确定

2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物) 安全信息

危险类别码：: 36/37/38
安全说明：: 26-36/37/39
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物) MSDS

Section 1: Product Identification
   2,6-Diisopropylphenylimido neophylidenemolybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST
   Chemical Name:
   CAS Registry Number:       139220-25-0
   Formula:       Mo(C10H12)(C12H17N)[OC(CH3)(CF3)2]2
   EINECS Number:       none
   Chemical Family:       organometallic complexes
   Synonym:       Schrock's catalyst

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 139220-25-0 100% 10mg/m3( as Mo) 15mg/m3 (as Mo)

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin, eyes and mucous membranes.
   Primary Routes of Exposure:       Ingestion, inhalation
   Eye Contact:       May cause mild to moderate irritation of the eyes.
   Skin Contact:       May cause slight to mild irritation of the skin.
   Inhalation:       Dust may be irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       No specific information is available on the physiological effects of ingestion.
   Acute Health Affects:       Dust may be irritating to skin, eyes and respiratory tract.
   No information available on long-term chronic effects. Product contains fluorine which may generate fluoride
   Chronic Health Affects:
   ion causing hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       no data
   Explosion Limits:       no data
   Extinguishing Medium:       carbon dioxide, dry powder or foam.
   If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
Handling and Storage: Handle and store the material under an inert atmosphere of nitrogen or argon. Keep away from heat.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow to orange powder
   Molecular Weight:       765.53
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       not determined
   Solubility in Water:       reacts with water

SECTION 10: Stability and Reactivity
   Stability:       air and moisture sensitive (store cold)
   Hazardous Polymerization:       No hazardous polymerization.
   Conditions to Avoid:       contact with air and moisture
   Incompatibility:       oxidizing agents and halogens
   Decomposition Products:       carbon monoxide, carbon dioxide, organic fumes and molybdenum oxide.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       no data
   Mutagenic Effects:       no data
   Tetratogenic Effects:       no data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed.
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

2,6-二异丙基苯基亚氨基叔丁基亚苯基钼(Ⅵ)双(六氟叔丁醇化物) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：767.153025 Da

8、标称质量：767 Da

9、平均质量：765.5252 Da

计算化学数据

1、疏水参数计算参考值（XlogP）：0.7

2、氢键供体数量：0

3、氢键受体数量：3

4、可旋转化学键数量：2

5、互变异构体数量：

6、拓扑分子极性表面积（TPSA）：42.7

7、重原子数量：13

8、表面电荷：0

9、复杂度：207

10、同位素原子数量：0

11、确定原子立构中心数量：0

12、不确定原子立构中心数量：0

13、确定化学键立构中心数量：0

14、不确定化学键立构中心数量：0

15、共价键单元数量：1