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邻磷酸三甲酚酯

中文名称：: 邻磷酸三甲酚酯

中文别名：: 磷酸三邻甲苯酯;
磷酸三甲苯(酚)酯;
邻磷酸三甲酚酯;
磷酸三(2-甲苯)酯;
磷酸邻三甲酚酯

英文名称：: Phosphoric acid,tris(2-methylphenyl) ester

英文别名：: Tri-o-tolyl phosphate;
tris(2-methylphenyl) phosphate

CAS No.：: 78-30-8

分子式：: C₂₁H₂₁O₄P

分子量：: 368.36

精确分子量：: 368.11800

PSA：: 54.57000

MDL：: MFCD00041906

EINECS：: 201-103-5

InChI：: The Key: YSMRWXYRXBRSND-UHFFFAOYSA-N3

危险品标志：: N

风险术语：: R39/23/24/25 R51/53

安全术语：: S28 S45 S61

分子结构式：

SDS：: 查看

邻磷酸三甲酚酯制备方法及用途

制备方法

(1)亚磷酸邻三甲苯酯的合成将邻甲酚加入反应釜,升温至40℃,在搅拌下滴加三氯化磷。三氯化磷滴加完后,于40℃左右继续反应半小时,反应生成亚磷酸邻三甲苯酯。 (2)磷酰氯邻三甲苯酯的合成将上述反应系统继续升温至70℃,通入氯气进行氯氧化反应,生成磷酰氯邻三甲苯酯。 (3)磷酸邻三甲苯酯的合成将上述反应系统降温至50℃左右,滴加水进行水解反应。反应完成后,用5%的纯碱水溶液进行中和,再用水洗涤,静置分去水层后,进行浓缩、减压蒸馏,即获得磷酸邻三甲苯酯成品。

合成制备方法

(1)亚磷酸邻三甲苯酯的合成将邻甲酚加入反应釜，升温至40℃，在搅拌下滴加三氯化磷。三氯化磷滴加完后，于40℃左右继续反应半小时，反应生成亚磷酸邻三甲苯酯。

(2)磷酰氯邻三甲苯酯的合成将上述反应系统继续升温至70℃，通入氯气进行氯氧化反应，生成磷酰氯邻三甲苯酯。

(3)磷酸邻三甲苯酯的合成将上述反应系统降温至50℃左右，滴加水进行水解反应。反应完成后，用5%的纯碱水溶液进行中和，再用水洗涤，静置分去水层后，进行浓缩、减压蒸馏，即获得磷酸邻三甲苯酯成品。

用途简介

用作主增塑剂,制品有很好的阻燃性、防霉性、耐磨性、挥发性低,电气性能好。主要用于聚氯乙烯电缆线、人造革、运输带、薄板、地板料等,也可用于氯丁橡胶。在黏胶纤维中也可用作增塑剂和防腐剂。本品对中枢神经有毒害作用,不可用于食品和医药包装材料、奶嘴、儿童玩具等。

用途

用作主增塑剂，制品有很好的阻燃性、防霉性、耐磨性、挥发性低，电气性能好。主要用于聚氯乙烯电缆线、人造革、运输带、薄板、地板料等，也可用于氯丁橡胶。在黏胶纤维中也可用作增塑剂和防腐剂。本品对中枢神经有毒害作用，不可用于食品和医药包装材料、奶嘴、儿童玩具等。

邻磷酸三甲酚酯毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TD0350000

CHEMICAL NAME :: Phosphoric acid, tri-o-tolyl ester

CAS REGISTRY NUMBER :: 78-30-8

BEILSTEIN REFERENCE NO. :: 1892885

LAST UPDATED :: 199712

DATA ITEMS CITED :: 65

MOLECULAR FORMULA :: C21-H21-O4-P

MOLECULAR WEIGHT :: 368.39

WISWESSER LINE NOTATION :: 1R BOPO&OR B1&OR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1160 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 900 mg/kg

TOXIC EFFECTS :: Gastrointestinal - hypermotility, diarrhea Skin and Appendages - hair Behavioral - muscle weakness

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1960 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 12500 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Gastrointestinal - hypermotility, diarrhea Kidney, Ureter, Bladder - interstitial nephritis

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Primate - monkey

DOSE/DURATION :: 1 gm/kg

TOXIC EFFECTS :: Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - food intake (animal) Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - miosis (pupillary constriction) Behavioral - muscle weakness Gastrointestinal - hypermotility, diarrhea

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 185 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - ataxia Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Behavioral - muscle weakness Gastrointestinal - hypermotility, diarrhea Kidney, Ureter, Bladder - interstitial nephritis

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >3700 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - tremor Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Kidney, Ureter, Bladder - other changes in urine composition

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intramuscular

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 135 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Kidney, Ureter, Bladder - urine volume decreased Musculoskeletal - other changes

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 18900 mg/kg/9W-C

TOXIC EFFECTS :: Liver - changes in liver weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Blood - changes in erythrocyte (RBC) count

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1500 mg/kg/3D-I

TOXIC EFFECTS :: Peripheral Nerve and Sensation - structural change in nerve or sheath Autonomic Nervous System - other (direct) parasympathomimetic

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2800 mg/kg/7D-I

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other esterases

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 4725 mg/kg/21D-I

TOXIC EFFECTS :: Liver - changes in liver weight Nutritional and Gross Metabolic - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 60750 mg/kg/39W-I

TOXIC EFFECTS :: Spinal Cord - other degenerative changes Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - ataxia

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 900 mg/kg/90D-I

TOXIC EFFECTS :: Behavioral - ataxia Related to Chronic Data - death

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 1800 mg/kg/18D-I

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - multiple enzyme effects Related to Chronic Data - changes in testicular weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: 3 gm/kg/30D-I

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - ataxia

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - domestic

DOSE/DURATION :: 900 mg/kg/26W-I

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes Spinal Cord - other degenerative changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1500 mg/kg

SEX/DURATION :: male 10 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 2100 mg/kg

SEX/DURATION :: female 14 day(s) after conception

TOXIC EFFECTS :: Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 450 mg/kg

SEX/DURATION :: male 3 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - other effects on male

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 3150 mg/kg

SEX/DURATION :: male 21 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Paternal Effects - testes, epididymis, sperm duct

MUTATION DATA

TEST SYSTEM :: Rodent - rat

REFERENCE :: CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 14,2039,1993 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.1 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 3,289,1975 TOXICOLOGY REVIEW IRXPAT International Review of Experimental Pathology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1962- Volume(issue)/page/year: 3,219,1964 TOXICOLOGY REVIEW CRTXB2 CRC Critical Reviews in Toxicology. (CRC Press, Inc., 2000 Corporate Blvd., NW, Boca Raton, FL 33431) V.1- 1971- Volume(issue)/page/year: 2,365,1973 TOXICOLOGY REVIEW CMTVAS Cahiers de Medecine du Travail. (Association Professionnelle Belge des Medecine du Travail, rue du Bultia, 6280 Gerpinnes, Belgium) V.1- 1963- Volume(issue)/page/year: 10(3),49,1973 TOXICOLOGY REVIEW ARENAA Annual Review of Entomology. (Annual Reviews, Inc., POB 10139, Palo Alto, CA 94303) V.1- 1956- Volume(issue)/page/year: 26,29,1981 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,271,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg/m3 JAN 1993 OEL-FINLAND:TWA 0.1 mg/m3;STEL 0.3 mg/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg/m3;Skin JAN 1993 OEL-HUNGARY:TWA 0.1 mg/m3;STEL 0.2 mg/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg/m3;STEL 0.3 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO TRIORTHOCRESYL PHOSPHATE-air:10H TWA 0.1 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 74600 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 14 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 74600 No. of Facilities: 20 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 20 (estimated) No. of Female Employees: 20 (estimated)

毒理学数据：

可经皮肤或呼吸道吸入而引起中毒，发生多发性神经炎。严重中毒可造成胃肠障碍，食欲不振，并会引起腿、脚、臂及手的麻痹或肌肉萎缩等现象。空气中最高允许浓度为3mg/m3。

邻磷酸三甲酚酯 MSDS

磷酸三邻甲苯酯 修改号码：5

模块 1. 化学品
产品名称： Tri-o-cresyl Phosphate
修改号码： 5

模块 2. 危险性概述
  GHS分类
    　物理性危害        未分类
    　健康危害
    特异性靶器官毒性        神经系统
  - 单一接触 [第1级]
    特异性靶器官毒性        神经系统
  - 单一接触 [第1级]
    　环境危害
    急性水生毒性      第2级
    慢性水生毒性      第2级
  GHS标签元素
    　图标或危害标志
    　信号词        危险
    　危险描述
    对器官引起损害：神经系统
    可能因延长或接触对器官产生损害：神经系统
    对水生生物有毒性
    长期影响对水生生物有毒性
    　防范说明
  [预防]        切勿吸入。
    避免释放到环境中。
    使用本产品时切勿吃东西，喝水或吸烟。
    处理后要彻底清洗双手。
  [急救措施]      如接触到：呼叫解毒中心/医生。
    收集溢出物。
  [储存]        存放处须加锁。
  [废弃处置]      根据当地政府规定把物品/容器交与工业废弃处理机构。
    磷酸三邻甲苯酯      修改号码：5

模块 3. 成分/组成信息
  单一物质/混和物        单一物质
  化学名(中文名)：        磷酸三邻甲苯酯
    百分比：      >96.0%(GC)
  CAS编码：      78-30-8
    俗名：      Phosphoric Acid Tri-o-tolyl Ester , Phosphoric Acid Tri-o-cresyl Ester ,
  Tri-o-tolyl Phosphate
    分子式：      C21H21O4P

模块 4. 急救措施
    吸入：      将受害者移到新鲜空气处，保持呼吸通畅，休息。立即呼叫解毒中心/医生。
    皮肤接触：      立即去除/脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。
  呼叫解毒中心/医生。
    眼睛接触：        用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。
  立即呼叫解毒中心/医生。
    食入：      呼叫解毒中心/医生。漱口。
    危害迹象：      头痛, 恶心, 呕吐, 虚弱, 腹痛
    紧急救助者的防护：        救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。
    医生注意事项：        根据接触程度，建议定期体检。建议医学观察。

模块 5. 消防措施
    合适的灭火剂：        干粉，泡沫，雾状水，二氧化碳
    不适用的灭火剂：        棒状水
    特殊危险性：        小心，燃烧或高温下可能分解产生毒烟。
    特定方法：        从上风处灭火，根据周围环境选择合适的灭火方法。
    非相关人员应该撤离至安全地方。
    周围一旦着火：如果安全，移去可移动容器。
    消防员的特殊防护用具：        灭火时，一定要穿戴个人防护用品。

模块 6. 泄漏应急处理
    个人防护措施，防护用具，      使用特殊的个人防护用品（自携式呼吸器）。远离溢出物/泄露处并处在上风处。确保
    紧急措施：        足够通风。
    泄露区应该用安全带等圈起来，控制非相关人员进入。
    环保措施：        小心，切勿排入河流等。因为考虑对环境有负面影响。
    控制和清洗的方法和材料：        用合适的吸收剂（如：旧布，干砂，土，锯屑）吸收泄漏物。一旦大量泄漏，筑堤控
    制。附着物或收集物应该立即根据合适的法律法规废弃处置。

模块 7. 操作处置与储存
    处理
    技术措施：        在通风良好处进行处理。穿戴合适的防护用具。防止烟雾产生。处理后彻底清洗双手
    和脸。
    注意事项：        如果可能，使用封闭系统。如果蒸气或浮质产生，使用通风、局部排气。
    操作处置注意事项：        避免接触皮肤、眼睛和衣物。
    贮存
    储存条件：        保持容器密闭。存放于凉爽、阴暗处。
    存放处须加锁。
    远离不相容的材料比如氧化剂存放。
    包装材料：        依据法律。
    磷酸三邻甲苯酯      修改号码：5

模块 8. 接触控制和个体防护
    工程控制：        尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。
    接触极限：
  　ACGIH TLV(TWA):      0.1 mg/m3 (skin)
  　OSHA PEL(TWA):      0.1 mg/m3
    个人防护用品
    　呼吸系统防护：      半面罩或全面罩呼吸器，自携式呼吸器（SCBA），供气呼吸器等。依据当地和政府法
    规，使用通过政府标准的呼吸器。
    　手部防护：        防渗手套。
    　眼睛防护：        护目镜。如果情况需要，佩戴面具。
    　皮肤和身体防护：        防渗防护服。如果情况需要，穿戴防护靴。

模块 9. 理化特性
  外形（20°C）：        液体
    外观：        透明
    颜色：      微浅黄色-黄色
    气味：        无味
  pH:        无数据资料
    熔点：        无资料
  沸点/沸程      410 °C
    闪点：      225°C
    爆炸特性
    　爆炸下限：        无资料
    　爆炸上限：        无资料
    蒸气压：
  0.2x10-2Pa/25°C
    蒸气密度：      12.7
    密度：      1.18
    溶解度：
  [水]        不溶于
  [其他溶剂]
    溶于：      醚, 酒精
  log水分配系数 =      6.3
    自燃温度：      385°C

模块 10. 稳定性和反应性
    化学稳定性：        一般情况下稳定。
    危险反应的可能性：        未报道特殊反应性。
    须避免接触的物质        氧化剂
  危险的分解产物:      一氧化碳, 二氧化碳, 磷氧化物

模块 11. 毒理学信息
    急性毒性：      orl-mam LD50:400 mg/kg
  orl-mus LD50:900 mg/kg
  orl-rat LD50:1160 mg/kg
  skn-rbt LD50:>3700 mg/kg
    对皮肤腐蚀或刺激：        无资料
    对眼睛严重损害或刺激：        无资料
    生殖细胞变异原性：      dnd-rat-orl 500 mg/kg/10D-C
    致癌性：
  IARC =        无资料
  NTP =        无资料
    磷酸三邻甲苯酯      修改号码：5

模块 11. 毒理学信息
生殖毒性：无资料
RTECS 号码: TD0350000

模块 12. 生态学信息
    生态毒性：
    鱼类：        无资料
    甲壳类：        无资料
    藻类：        无资料
  残留性 / 降解性：      65.7% (by BOD), 81.6% (by UV-VIS), 82.6% (by GC)
  潜在生物累积（BCF):      36000
    土壤中移动性
  　log水分配系数：      6.3
  　土壤吸收系数（Koc）：      2.4 x 104
  5.5 x 10-3
    　亨利定律
  constant(PaM3/mol):

模块 13. 废弃处置
如果可能，回收处理。请咨询当地管理部门。建议在装有后燃和洗涤装置的化学焚烧炉中焚烧。废弃处置时请遵守
国家、地区和当地的所有法规。

模块 14. 运输信息
    联合国分类：      第1项毒害品。
  UN编号：      2574
    正式运输名称：        三甲苯磷酸酯
    包装等级：      II
  海洋污染物:      Y

模块 15. 法规信息
《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、
生产、储存、运输、装卸等方面均作了相应的规定。

模块16 - 其他信息
N/A