cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II),14267-08-4，生产厂家，价格-洛克化工网移动版

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II)

中文名称：: cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II)

中文别名：: 二氯(N,N,N’,N’-四甲基乙二胺)钯;
二氯(N,N,N',N'-四甲基乙二胺)钯;
顺-二氯(N,N,N`,N`-四甲基乙烯二胺)钯(II)

英文名称：: Palladium,dichloro(N1,N1,N2,N2-tetramethyl-1,2-ethanediamine-kN1,kN2)-, (SP-4-2)-

英文别名：: Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II);
N,N,N',N'-tetramethylethylenediamine palladium(II) chloride;
Palladium,dichloro(N,N,N',N'-tetramethyl-1,2-ethanediamine-N,N')-,(sp-4-2);
cis-dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II);
(N,N,N',N'-tetramethylethylenediamine)PdCl2;
Palladium,dichloro(N,N,N',N'-tetramethylethylenediamine);
(N,N,N',N'-tetramethylethylenediamine)dichloridopalladium(II);
[Pd(tmen)Cl2];
DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II);
Cl2Pd(II)(TMEDA);
dichloro(N,N,N',N'-tetramethylethylene-diamine)pa

CAS No.：: 14267-08-4

分子式：: C₆H₁₆Cl₂N₂Pd

分子量：: 293.53

精确分子量：: 291.97300

PSA：: 6.48000

MDL：: MFCD00075317

InChI：: InChI=1/C6H16N2.2ClH.Pd/c1-7(2)5-6-8(3)4;;;/h5-6H2,1-4H3;2*1H;/q;;;+2/p-23

风险术语：: R36/37/38

安全术语：: S26 S37/S39

分子结构式：

SDS：: 查看

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) 物化性质

熔点：: 245ºC (dec.)(lit.)
沸点：: 121ºC at 760 mmHg
闪点：: 10ºC
蒸汽压：: 14.9mmHg at 25°C
存储条件/存储方法：: 密闭于阴凉干燥环境中
稳定性相关：: 遵照规定使用和储存则不会分解。
其它信息：: 1.      性状：无可用
2.      密度（g/mL,25/4℃）：无可用
3.      相对蒸汽密度（g/mL,空气=1）：无可用
4.      熔点（ºC）：245
5.      沸点（ºC,常压）：无可用
6.      沸点（ºC,5.2kPa）：无可用
7.      折射率：无可用
8.      闪点（ºC）：无可用
9.      比旋光度（º）：无可用
10.   自燃点或引燃温度（ºC）：无可用
11.   蒸气压（kPa,25ºC）：无可用
12.   饱和蒸气压（kPa,60ºC）：无可用
13.   燃烧热（KJ/mol）：无可用
14.   临界温度（ºC）：无可用
15.   临界压力（KPa）：无可用
16.   油水（辛醇/水）分配系数的对数值：无可用
17.   爆炸上限（%,V/V）：无可用
18.   爆炸下限（%,V/V）：无可用
19.   溶解性：无可用

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) 安全信息

危险类别码：: R36/37/38
安全说明：: 37/39-26
危险标志：: Xi: Irritant;

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) 毒理性

生态数据：: 该物质对环境可能有危害，对水体应给予特别注意。

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) MSDS

Section 1: Product Identification
   Chemical Name:       cis-Dichloro(N,N,N'N'-tetramethylethylenediamine)palladium(II), 99%
   CAS Registry Number:       14267-08-4
   Formula:       C6H16Cl2N2Pd
   EINECS Number:       none
   Chemical Family:       organometallic complex
   Synonym:       cis-ichloroN,N,N',N'-Tetramethyl-ethane-1,2-diamine)palladium(II)

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 14267-08-4 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.
   Primary Routes of Exposure:       Ingestion, inhalation
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Chronic Health Affects:       No information on long-term chronic effects.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data
   Autoignition Temperature:       no data
   Explosion Limits:       no data
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Keep in a cool, dry, well ventilated place.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow powder
   Molecular Weight:       293.53
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       not determined
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       strong oxidizing agents
   Decomposition Products:       carbon monoxide, carbon dioxide, palladium oxide and organic fumes

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       no data
   Mutagenic Effects:       no data
   Tetratogenic Effects:       no data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、

摩尔体积（cm³/mol）：无可用

3、

等张比容（90.2K）：无可用

4、

表面张力（dyne/cm）：无可用

5、

极化率：无可用

计算化学数据

1、疏水参数计算参考值（XlogP）：无可用

2、

氢键供体数量：0

3、

氢键受体数量：2

4、

可旋转化学键数量：3

5、

拓扑分子极性表面积（TPSA）：6.5

6、

重原子数量：11

7、

表面电荷：0

8、

复杂度：45.2

9、

同位素原子数量：0

10、

确定原子立构中心数量：0

11、

不确定原子立构中心数量：0

12、

确定化学键立构中心数量：0

13、

不确定化学键立构中心数量：0

14、

共价键单元数量：2

cis-Dichloro(N,N,N,N-tetramethylethylenediamine)palladium(II) 上游产品

四甲基乙二胺双(乙腈)二氯钯(II) 氯化钯