氨基磺酸镍,13770-89-3，生产厂家，价格-洛克化工网移动版

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基本信息

制备方法及用途

物化性质

安全信息

毒理性

MSDS

海关数据

结构与计算化学

氨基磺酸镍

中文名称：: 氨基磺酸镍

中文别名：: 氨基磺酸镍;
胺基磺酸鎳

英文名称：: Nickel sulfamate

英文别名：: Sulfamic acid, nickel(2+) salt (2:1);
Nickel sulfamate (6CI,7CI);
Aeronikl 250;
Aeronikl 400;
Aeronikl 575;
Melbright EF 2201;
NS 169;
Nickel aminosulfonate;
Nickel sulfamate (Ni(H2NSO3)2);
Nickel sulfamate (Ni(SO3NH2)2)

CAS No.：: 13770-89-3

分子式：: H₃NO₃S.1/2Ni

分子量：: 250.86

精确分子量：: 251.90208

PSA：: 155.54000

MDL：: MFCD00137261

EINECS：: 237-396-1

InChI：: InChI=1/2H3NO3S.Ni/c2*1-5(2,3)4;/h2*(H3,1,2,3,4);/q;;+2/p-23

风险术语：: R10; R15; R20; R24/25; R36/38; R44; R36/37/38

分子结构式：

SDS：: 查看

氨基磺酸镍物化性质

外观与性状：
绿色至带蓝色的晶体

密度：
1.913g/cm3

熔点：
205ºC

存储条件/存储方法：

1.贮存于通风、干燥的库房中。包装必须完整密封，注意防潮。
2.运输过程中要防雨淋和日光暴晒。

稳定性相关：

1.常温常压下稳定
避免的物料，碱水溶液与碱金属碱土金属和许多有机无机的活性化学药品是不相溶的。易潮解。易溶于水。在高温时失去结晶水同时分解。
2.失火时，可用水、砂土和灭火器扑救。
3.在干燥空气中缓慢风化、受热时会失去4个水生成无水物，温度高于110℃时开始分解并形成碱式盐，继续加热生成棕黑色的三氧化二镍和绿色的氧化亚镍混合物。

其它信息：

1.      性状：绿色结晶。
2.      密度（g/mL,25/4℃）：1.55
3.      相对蒸汽密度（g/mL,空气=1）：未确定
4.      熔点（ºC）：未确定
5.      沸点（ºC,常压）：未确定
6.      沸点（ºC,5.2kPa）：未确定
7.      折射率：未确定
8.      闪点（ºC）：未确定
9.      比旋光度（º）：未确定
10.   自燃点或引燃温度（ºC）：未确定
11.   蒸气压（kPa,25ºC）：未确定
12.   饱和蒸气压（kPa,60ºC）：未确定
13.   燃烧热（KJ/mol）：未确定
14.   临界温度（ºC）：未确定
15.   临界压力（KPa）：未确定
16.   油水（辛醇/水）分配系数的对数值：未确定
17.   爆炸上限（%,V/V）：未确定
18.   爆炸下限（%,V/V）：未确定
19.   溶解性：易溶于水，溶于液氨、乙醇，微溶于丙酮，水溶液呈酸性。

氨基磺酸镍安全信息

包装等级：
II

风险类别：
4.3

海关代码：
2922499990

WGK_Germany：
2
德国有关水污染物质的分类清单

危险类别码：
R10:Flammable. R15:Contact with water liberates extremely flammable gases. R20:Harmful by inhalation. R24/25:Toxic in contact with skin and if swallowed . R36/38:Irritating to eyes and skin . R44:Risk of explosion if heated under confinement. R36/37/38:Ir

安全说明：
S26-S36/37-S43-S45-S36/37/39-S28A

RTECS号：
US3675000

危险标志：
F,T,T+

氨基磺酸镍毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QR9275000

CHEMICAL NAME :
Nickel (II) sulfamate

CAS REGISTRY NUMBER :
13770-89-3

LAST UPDATED :
199712

DATA ITEMS CITED :
33

MOLECULAR FORMULA :
H4-N2-O6-S2.Ni

MOLECULAR WEIGHT :
250.89
HEALTH HAZARD DATA
ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :
Intraperitoneal

SPECIES OBSERVED :
Rodent - mouse

DOSE/DURATION :
250 mg/kg

REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,320,1952 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Ni)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,178,1971 OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-AUSTRALIA:TWA 1 mg(Ni)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen JAN 1993 OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;Carcinogen (insoluble compounds) JAN 1993 OEL-FRANCE:TWA 1 mg(Ni)/m3 JAN 1993 OEL-GERMANY;Carcinogen JAN 1993 OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen (insoluble compounds) JAN 1993 OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3 JAN 1993 OEL-RUSSIA:STEL 0.05 mg(Ni)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Ni)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN 1993 OEL-THAILAND:TWA 1 mg(Ni)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds) JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 50470 No. of Facilities: 256 (estimated) No. of Industries: 10 No. of Occupations: 9 No. of Employees: 900 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 50470 No. of Facilities: 488 (estimated) No. of Industries: 19 No. of Occupations: 18 No. of Employees: 11182 (estimated) No. of Female Employees: 3593 (estimated)

毒理学数据：

1、急性毒性：主要的刺激性影响：
在皮肤上面：可能引起发炎；
在眼睛上面：可能引起发炎;
2、致敏作用：通过吸入可能造成敏化作用，通过皮肤接触可能造成敏化作用。

生态数据：

对水体是极其有害的，即使小量产品也不能接触地下水，水道或污水系统,若无政府许可，勿将材料排入周围环境

氨基磺酸镍 MSDS

Section 1. Chemical Product and Company Identification
    Nickel Sulfamate, Solution
    Common Name/
    Trade Name
    Manufacturer
    Commercial Name(s)
    Synonym
    Chemical Name
    Chemical Family
    Nickel Sulfamate, Solution

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
    least 15 minutes. Cold water may be used. Get medical attention immediately.
    Skin Contact        In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
    clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
    reuse. Thoroughly clean shoes before reuse. Get medical attention.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
    medical attention.
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
    medical attention.
    Serious Inhalation        Not available.
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.
    Flammable Limits        Not applicable.
    Products of Combustion        Not available.
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Non-explosive in presence of open flames and sparks, of shocks.
    of Various Substances
    Fire Fighting Media        Not applicable.
    and Instructions
    Special Remarks on        Not available.
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
    container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and
    regional authority requirements.
    Large Spill        Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
    spreading water on the contaminated surface and allow to evacuate through the sanitary system.
    Nickel Sulfamate, Solution

Section 7. Handling and Storage
    Precautions        Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek
    medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing
    agents.
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
    respective threshold limit value.
    Personal Protection        Safety glasses. Lab coat. Gloves.
    Respiratory protection is not necessary for normal handling. Adequate general (room) ventilation or local exhaust
    (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent
    (e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract
    irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent.
    Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
    a Large Spill        specialist BEFORE handling this product.
    Exposure Limits        Not available.

Section 9. Physical and Chemical Properties
    Physical state and appearance Liquid.        Odor        Odorless.
    Not available.
    Taste
    Molecular Weight        Not applicable.
    Green. Bluish-Green. Clear (Dark.)
    Color
    pH (1% soln/water)        Not available.
    Boiling Point        >104.44°C (220°F)
    Melting Point        Not available.
    Critical Temperature        Not available.
    Specific Gravity        Not available.
    Not applicable.
    Vapor Pressure
    Vapor Density        Not available.
    Not available.
    Volatility
    Odor Threshold        Not available.
    Water/Oil Dist. Coeff.        Not available.
    Ionicity (in Water)        Not available.
    Dispersion Properties        Not available.
    Solubility        Soluble in cold water.

Section 10. Stability and Reactivity Data
    Stability        The product is stable.
    Instability Temperature        Not available.
    Conditions of Instability        Incompatible materials
    Incompatibility with various Reactive with oxidizing agents.
    substances
    Nickel Sulfamate, Solution
    Corrosivity        Non-corrosive in presence of glass.
    Special Remarks on        Not available.
    Reactivity
    Special Remarks on        Not available.
    Corrosivity
    Polymerization        Will not occur.

Section 11. Toxicological Information
    Routes of Entry        Skin contact. Eye contact.
    Toxicity to Animals        LD50: Not available.
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on        Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.
    Humans
    Special Remarks on        Not available.
    Toxicity to Animals
    Special Remarks on        May cause cancer (Nickel Sulfamate)
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:
    Toxic Effects on Humans        Skin: Can cause skin irritation.
    Eyes: Can cause eye irritation.
    Inhalaiton: May cause respiratory tract irritation.
    Ingestion: May be harmful if swallowed.
    Chronic Potential Health Effects:
    Skin: Prolonged or repeated skin contact may cause allergic skin reaction (allergic contact dermatitis).

Section 12. Ecological Information
    Ecotoxicity        Not available.
    BOD5 and COD        Not available.
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    arise.
    Toxicity of the Products        The products of degradation are less toxic than the product itself.
    of Biodegradation
    Not available.
    Special Remarks on the
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste must be disposed of in accordance with federal, state and local environmental
    Waste Disposal
    control regulations.
    Nickel Sulfamate, Solution

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).
    Identification        Not applicable.
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    Federal and State
    cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Nickel
    Regulations
    sulfamate (listed as Nickel compounds)
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel compounds)
    SARA 313 toxic chemical notification and release reporting: Nickel sulfamate (Listed as Nickel compounds)
    California prop. 65: This product contains the following ingredients for which the State of California has found
    California
    Proposition 65        to cause cancer which would require a warning under the statute: Nickel sulfamate (Listed as Nickel
    Warnings        compounds)
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        For Nickel Sulfamate (CAS no. 13770-89-3):
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No.
    237-396-1).
    Canada: Listed on Canadian Domestic Substance List (DSL).
    China: Not listed on National Inventory.
    Japan: Listed on National Inventory (ENCS).
    Korea: Listed on National Inventory (KECI).
    Philippines: Listed on National Inventory (PICCS).
    Australia: Listed on AICS.
    Other Classifications        WHMIS (Canada)        CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
    Class D-2B: Material causing other toxic effects (TOXIC).
    DSCL (EEC)        R22- Harmful if swallowed.        S26- In case of contact with eyes, rinse
    R40- Limited evidence of a        immediately with plenty of water and seek
    carcinogenic effect.        medical advice.
    R43- May cause sensitization by skin        S28- After contact with skin, wash immediately
    contact.        with plenty of water.
    S36/37/39- Wear suitable protective clothing,
    gloves and eye/face protection.
    S46- If swallowed, seek medical advice
    immediately and show this container or label.
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    Nickel Sulfamate, Solution
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate respirator
    when ventilation is inadequate.

SECTION 16 - ADDITIONAL INFORMATION
N/A

氨基磺酸镍海关数据

中国海关编码：2922499990

概述：

2922499990 其他氨基酸及其酯及它们的盐（含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

监管条件：

A.入境货物通关单B.出境货物通关单

检验检疫：

P.进境动植物、动植物产品检疫Q.出境动植物、动植物产品检疫R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验

摘要/Summary：

HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

氨基磺酸镍分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的
2、摩尔体积（cm³/mol）：无可用的
3、等张比容（90.2K）：无可用的
4、表面张力（dyne/cm）：无可用的
5、介电常数：无可用的
6、极化率（10^-24cm³）：无可用的
7、单一同位素质量：249.886425Da
8、标称质量：250Da
9、平均质量：250.865Da

计算化学数据

1.疏水参数计算参考值（XlogP）:无
2.氢键供体数量:2
3.氢键受体数量:8
4.可旋转化学键数量:0
5.互变异构体数量:无
6.拓扑分子极性表面积183
7.重原子数量:11
8.表面电荷:0
9.复杂度:79.2
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:3

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手  机：15271829679
Cas号：13770-89-3
包装：1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋
纯度：99%
价格：1.0元 - 1,000.0元
湖北摆渡化学有限公司

氨基磺酸镍
联系人：邹琦
电  话：027-59106051
手  机：13627137652
Cas号：13770-89-3
包装：25kg
纯度：99%
价格：1.0元

氨基磺酸镍

氨基磺酸镍制备方法及用途

制备方法

合成制备方法

用途简介

用途

氨基磺酸镍物化性质

氨基磺酸镍安全信息

氨基磺酸镍毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

氨基磺酸镍 MSDS

氨基磺酸镍海关数据

中国海关编码：2922499990

氨基磺酸镍分子结构与计算化学数据

分子结构数据

计算化学数据

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氨基磺酸镍

氨基磺酸镍 制备方法及用途

制备方法

合成制备方法

用途简介

用途

氨基磺酸镍 物化性质

氨基磺酸镍 安全信息

氨基磺酸镍 毒理性

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

氨基磺酸镍 MSDS

氨基磺酸镍 海关数据

中国海关编码：2922499990

氨基磺酸镍 分子结构与计算化学数据

分子结构数据

计算化学数据

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氨基磺酸镍制备方法及用途

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氨基磺酸镍安全信息

氨基磺酸镍毒理性

氨基磺酸镍海关数据

氨基磺酸镍分子结构与计算化学数据