Version 1.2
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name GADOLINIUM(III) PERCHLORATE, 99.5%, 40
WT. % SOLUTION IN WATER
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Contact with combustible material may cause fire. Causes burns.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
GADOLINIUM(III) PERCHLORATE, 14017-52-8 237-837-8 None
99.5%,40 WT. % SOLUTION IN WATER
Formula Gd(ClO4)3
Molecular Weight 455,6000 AMU
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER EYE CONTACT
Assure adequate flushing of the eyes by separating the eyelids
with fingers.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.
5 - Fire Fighting Measures
CONDITIONS OF FLAMMABILITY
May accelerate combustion.
EXTINGUISHING MEDIA
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Suitable: Water spray.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions. May
accelerate combustion. Contact with other material may cause
fire.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place.
Unsuitable: Do not store near, nor allow contact with, clothing
and other combustible material.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before
reuse. Discard contaminated shoes.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing. Faceshield (8-inch minimum).
9 - Physical and Chemical Properties
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
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Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure 6,204000000 mmHg 20,00 °C
SG/Density 1,4450 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Organic materials, Finely powdered metals,
Strong reducing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Chlorine.
11 - Toxicological Information
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Blood effects. Exposure can cause: Symptoms of exposure may
include burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. Inhalation
may result in spasm, inflammation and edema of the larynxand
bronchi, chemical pneumonitis, and pulmonary edema. Inhalation
of rare earths may cause sensitivity to heat, itching, and
increased awareness of odor and taste. Rare earth compounds may
cause delayed blood clotting leading to hemorrhages. Material is
extremely destructive to tissue of the mucous membranes and
upper respiratory tract, eyes, and skin.
ROUTE OF EXPOSURE
Multiple Routes: Harmful if swallowed, inhaled, or absorbed
through skin.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
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14 - Transport Information
RID/ADR
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
IMDG
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: OXIDIZING LIQUID, CORROSIVE,
N.O.S.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3098
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Oxidizing liquid, corrosive,
n.o.s.
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: O-C
Oxidizing. Corrosive.
R-PHRASES: 8-34
Contact with combustible material may cause fire. Causes burns.
S-PHRASES: 17-26-27-36/37/39-36-45
Keep away from combustible material. In case of contact with
eyes, rinse immediately with plenty of water and seek medical
advice. Take off immediately all contaminated clothing. Wear
suitable protective clothing, gloves, and eye/face protection.
Wear suitable protective clothing. In case of accident or if
you feel unwell, seek medical advice immediately (show the
label where possible).
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
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unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
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