N,N-二氰乙基苯胺,1555-66-4，生产厂家，价格-洛克化工网移动版

N,N-二氰乙基苯胺

中文名称：: N,N-二氰乙基苯胺

中文别名：: N,N-二氰乙基苯胺;
[4-(2-methylpropyl)phenyl]acetic acid;
[4-(2-methylpropyl)phenyl]acetate;
4-(2-methylpropyl)-benzeneacetic acid;
对异丁基苯乙酸;
布芬酸;
6-(dimethylamino)-3,3-bis[4-(dimethylamino)phenyl]-1(3h)-isobenzofuranon;
6-(Dimethylamino)-3,3-bis[4-(dimethylamino)phenyl]phthalide;
Pergascript Blue I 2R;
6-(dimethylamino)-3,3-bis(4-(dimethylamino)phenyl)-1(3h)-isobenzofuranone;
6-(DIMETHYLAMINO)-3,3-BIS[P-(DIMETHYLAMINO)PHENYL]PHTHALIDE;
3,3-BIS(P-DIMETHYLAMINOPHENYL)-6-DI

英文名称：: Propanenitrile,3,3'-(phenylimino)bis-

英文别名：: 3-[N-(2-cyanoethyl)anilino]propanenitrile;
bis-2-cyanoethyl aniline;
3,3'-(Phenylimino)dipropionitrile;
N,N-Bis(2-cyanoethyl)aniline;
3,3'-Phenylimino-di-propionitril

CAS No.：: 1555-66-4

分子式：: C₁₂H₁₃N₃

分子量：: 199.25

精确分子量：: 199.11100

PSA：: 50.82000

EINECS：: 216-306-4

InChI：: InChI=1/C12H13N3/c13-8-4-10-15(11-5-9-14)12-6-2-1-3-7-12/h1-3,6-7H,4-5,10-11H23

危险品标志：: Xi

风险术语：: R36/37/38

安全术语：: S26;S36;

分子结构式：

SDS：: 查看

N,N-二氰乙基苯胺制备方法及用途

制备方法

用作染料中间体

用途简介

N,N-二氰乙基苯胺物化性质

外观与性状：: 固体
密度：: 1.105g/cm3
熔点：: 81-84 °C(lit.)
沸点：: 175 - 180 (0.3 torr)
闪点：: 189ºC
折射率：: 1.567
蒸汽压：: 5.35E-07mmHg at 25°C
存储条件/存储方法：: 保持贮藏器密封、储存在阴凉、干燥的地方，确保工作间有良好的通风或排气装置
稳定性相关：: 如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物
其它信息：: 1.       性状：白色结晶粉末。

2.       密度（g/mL,25/4℃）：未确定

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：81-84

5.       沸点（ºC,常压）：175-180

6.       沸点（ºC,5.2kPa）：未确定

7.       折射率：未确定

8.       闪点（ºC）：未确定

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（kPa,25ºC）：未确定

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.    溶解性：易溶于有机溶剂、稀酸、稀碱，不溶于水。

N,N-二氰乙基苯胺安全信息

WGK_Germany：: 3
德国有关水污染物质的分类清单
危险类别码：: R36/37/38
安全说明：: S26-S36
危险标志：: Xi:Irritant;

N,N-二氰乙基苯胺毒理性

生态数据：

对是水稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境。

N,N-二氰乙基苯胺 MSDS

Name:	n n-bis(Cyanoethyl)aniline 95% Material Safety Data Sheet
Synonym:
CAS:	1555-66-4

Section 1 - Chemical Product MSDS Name:n n-bis(Cyanoethyl)aniline 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1555-66-4	N,N-Bis(cyanoethyl)aniline	95%	216-306-4

Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50 48/23/24/25

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms. Toxic : danger of serious damage to health by prolonged exposure through inhalation, contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1555-66-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: light beige
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 80 - 88 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H13N3
Molecular Weight: 199.25

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acetic anhydride, acid chlorides, carbon dioxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1555-66-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N-Bis(cyanoethyl)aniline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: 3
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: 3
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1555-66-4: No information available.
Canada
CAS# 1555-66-4 is listed on Canada's NDSL List.
CAS# 1555-66-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1555-66-4 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

N,N-二氰乙基苯胺分子结构与计算化学数据

分子结构数据

1、摩尔折射率：58.92

2、摩尔体积（m³/mol）：180.2

3、等张比容（90.2K）：485.0

4、表面张力（dyne/cm）：52.4

5、介电常数：无可用

6、偶极距（10^-24cm³）：无可用

7、极化率：23.35

计算化学数据

1.疏水参数计算参考值（XlogP）:1.4

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:5

5.互变异构体数量:无

6.拓扑分子极性表面积50.8

7.重原子数量:15

8.表面电荷:0

9.复杂度:241

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

N,N-二氰乙基苯胺上游产品

丙烯腈 N,N-二羟乙基苯胺氰化钾 N/A 乙酸

N,N-二氰乙基苯胺下游产品

3-氯丙酸乙酯 3,3′-(4-甲酰苯基亚氨基)二丙腈