1,1,2-三氯丙烷,598-77-6，生产厂家，价格-洛克化工网移动版

1,1,2-三氯丙烷

中文名称：: 1,1,2-三氯丙烷

中文别名：: 1,1,2-三氯丙烷;
(±)-3-methyl-butan-2-ol;
(CH3)2CHCH(OH)CH3;
(R,S)-3-Methyl-butan-2-ol;
2-Butanol,3-methyl-;
3-Methyl butan-2-ol;
3-methyl-2-butano;
3-methyl-butan-2-ol;
DL-3-Methyl-2-butanol;
DL-2-Bromopropionic;
DL-2-Bromopropionic acid;
Methylurethan;
NCI-C55594;
NSC 3054;
Urethylane;
Methylurethane;
MCM;
Methyl carbamate;
M-Aminophenol;
m-amino phenol;
Meta Aminophenol;
Aminophenol, 3-;
3-Aminophenol;
Antigene MB;

英文名称：: Propane,1,1,2-trichloro-

英文别名：: 2-Chloropropylidene Chloride;
1,1,2-TRICHLOROPROPANE

CAS No.：: 598-77-6

分子式：: C₃H₅Cl₃

分子量：: 147.43

精确分子量：: 145.94600

PSA：: 0.00000

EINECS：: 209-951-8

InChI：: InChI=1/C3H5Cl3/c1-2(4)3(5)6/h2-3H,1H33

风险术语：: R20/21/22 R36/37/38

安全术语：: S26 S36/S37/S39

分子结构式：

SDS：: 查看

1,1,2-三氯丙烷物化性质

密度：: 1.305g/cm3
沸点：: 125.3ºC at 760mmHg
闪点：: 44.3ºC
折射率：: 1.45
存储条件/存储方法：: 贮存：
将密器密封，储存密封的主藏器内，并放在阴凉，干爽的位置。
稳定性相关：: 性质与稳定性：
常温常压下，或不分解产物。
其它信息：: 一、物性数据
1. 沸点：132℃。
2、相对密度：1.35（19℃）。
3.   相对密度（20℃，4℃）：1.372
4. 相对密度（25℃，4℃）：1.337
5.   常温折射率（n²⁰）：1.480
6.   常温折射率（n²⁵）：1.482

1,1,2-三氯丙烷安全信息

危险类别码：: 20/21/22-36/37/38
安全标志：: S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

1,1,2-三氯丙烷毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TZ8925000

CHEMICAL NAME :: Propane, 1,1,2-trichloro-

CAS REGISTRY NUMBER :: 598-77-6

BEILSTEIN REFERENCE NO. :: 1731988

LAST UPDATED :: 199806

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C3-H5-Cl3

MOLECULAR WEIGHT :: 147.43

WISWESSER LINE NOTATION :: GYGYG1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,99,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1230 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2000 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 14100 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

生态数据：

三、生态学数据：

1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

1,1,2-三氯丙烷 MSDS

Section I.Chemical Product and Company Identification
    Chemical Name 1,1,2-Trichloropropane
    Portland OR
    Synonym        Propane, 1,1,2-trichloro- (CA INDEX NAME);
    2-Chloropropylidene Chloride
    Chemical Formula        C3H5Cl3
    CAS Number        598-77-6

Section II.        Composition and Information on Ingredients
    Toxicology Data
    Chemical Name        CAS Number Percent (%)        TLV/PEL
    Min. 96.0 (GC) Not available.        Rat LD50 (oral) 1230 mg/kg
    1,1,2-Trichloropropane        598-77-6
    Rabbit LD50 (dermal) 14100 uL/kg

Section III. Hazards Identification
    Harmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death.
    Acute Health Effects
    Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the
    eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
    CARCINOGENIC EFFECTS : Not available.
    Chronic Health Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

Section IV.        First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
    minutes. Get medical attention.
    Skin Contact        In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
    before reuse. Thoroughly clean shoes before reuse. Get medical attention.
    Inhalation        If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
    waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
    improve.
    Ingestion        INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
    Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic
    material was ingested; the absence of such signs, however, is not conclusive.

Section V.        Fire and Explosion Data
    Auto-Ignition        Not available.
    Flammability        Combustible.
    Flammable Limits        Not available.
    Flash Points        Not available.
    Combustion Products        These products are toxic carbon oxides (CO, CO2), halogenated compounds.
    WARNING: Highly toxic HCl gas is produced during combustion.
    Fire Hazards        Not available.
    Risks of explosion of the product in presence of mechanical impact: Not available.
    Explosion Hazards
    Risks of explosion of the product in presence of static discharge: Not available.
    Fire Fighting Media
    SMALL FIRE: Use DRY chemical powder.
    LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
    and Instructions
    Consult with local fire authorities before attempting large scale fire-fighting operations.
    Continued on Next Page
    1,1,2-Trichloropropane

Section VI.        Accidental Release Measures
    Spill Cleanup        Combustible material. Harmful material. Irritating material.
    Keep away from heat. Mechanical exhaust required. Stop leak if without risk. Finish cleaning the spill by rinsing any
    Instructions
    contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
    disposal.

Section VII. Handling and Storage
    COMBUSTIBLE. HARMFUL. IRRITANT. Keep away from heat. Mechanical exhaust required. Avoid excessive heat and
    Handling and Storage
    light. Do not breathe gas/fumes/ vapor/spray.
    Information
    Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
    Engineering Controls
    threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
    Splash goggles. Lab coat. Vapor respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
    Personal Protection
    specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
    Exposure Limits        Not available.

Section IX. Physical and Chemical Properties
    Liquid. (Clear, colorless.)        Solubility
    Physical state @ 20°C        Not available.
    1.35 (water=1)
    Specific Gravity
    Molecular Weight        147.43        Partition Coefficient
    Not available.
    Boiling Point        133°C (271.4°F)        Vapor Pressure        Not available.
    Not available.        Not available.
    Melting Point        Vapor Density
    Refractive Index        1.4670 - 1.4700        Volatility        Not available.
    Not available.        Not available.
    Critical Temperature        Odor
    Viscosity        Not available.        Taste        Not available.

Section X. Stability and Reactivity Data

This material is stable if stored under proper conditions. (See Section VII for instructions)
    Stability
    Conditions of Instability        Avoid excessive heat and light.
    Incompatibilities
    Reactive with oxidizing agents.

Section XI. Toxicological Information
    TZ8925000
    RTECS Number
    Eye Contact. Ingestion. Inhalation.
    Routes of Exposure
    Rat LD50 (oral) 1230 mg/kg
    Toxicity Data
    Rabbit LD50 (dermal) 14100 uL/kg
    CARCINOGENIC EFFECTS : Not available.
    Chronic Toxic Effects
    MUTAGENIC EFFECTS : Not available.
    TERATOGENIC EFFECTS : Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
    Harmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death.
    Acute Toxic Effects
    Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye
    is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or,
    occasionally, blistering.
    Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.

Section XII.        Ecological Information
    Ecotoxicity        Not available.
    Environmental Fate        Not available.
    Continued on Next Page
    1,1,2-Trichloropropane

Section XIII. Disposal Considerations
    Waste Disposal        Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
    federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
    DOT Classification        Not a DOT controlled material (United States).
    PIN Number        Not applicable.
    Proper Shipping Name        Not applicable.
    Packing Group (PG)        Not applicable.
    DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
    TSCA Chemical Inventory        This compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.
    (EPA)
    WHMIS Classification        CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).
    On NDSL
    (Canada)
    EINECS Number (EEC) 209-951-8
    EEC Risk Statements        R20/21/22- Harmful by inhalation, in contact with skin and if swallowed.
    R36/37/38- Irritating to eyes, respiratory system and skin.

SECTION 16 - ADDITIONAL INFORMATION
N/A

1,1,2-三氯丙烷分子结构与计算化学数据

分子结构数据

五、分子性质数据：

1、摩尔折射率：30.41

2、摩尔体积（cm³/mol）：112.9

3、等张比容（90.2K）：261.6

4、表面张力（dyne/cm）：28.7

5、极化率（10^-24cm³）：12.05

计算化学数据

四、计算化学数据：

1、疏水参数计算参考值（XlogP）：2.6

2、氢键供体数量：0

3、氢键受体数量：0

4、可旋转化学键数量：1

5、拓扑分子极性表面积（TPSA）：0

6、重原子数量：6

7、表面电荷：0

8、复杂度：35

9、同位素原子数量：0

10、确定原子立构中心数量：0

11、不确定原子立构中心数量：1

12、确定化学键立构中心数量：0

13、不确定化学键立构中心数量：0

14、共价键单元数量：1

1,1,2-三氯丙烷上游产品

2-氯丙烷 1,3-二氯丙烷 3-氯丙醇 1,1-二氯丙烷

1,1,2-三氯丙烷下游产品

四氯丙烷五氯丙烷六氯丙烷 1,2,3-三氯丙烷 1,1-二氯丙烯