2-(三氟甲基)-3,3,3-三幅丙酸甲酯,360-54-3，生产厂家，价格-洛克化工网移动版

2-(三氟甲基)-3,3,3-三幅丙酸甲酯

中文名称：: 2-(三氟甲基)-3,3,3-三幅丙酸甲酯

中文别名：: 2-(三氟甲基)-3,3,3-三幅丙酸甲酯;
2-(三氟甲基)-3,3,3-三氟丙酸甲酯

英文名称：: Propanoic acid,3,3,3-trifluoro-2-(trifluoromethyl)-, methyl ester

英文别名：: methyl 3,3,3-trifluoro-2-(trifluoromethyl)propanoate;
methyl 2-trifluoromethyl-3,3,3-trifluoropropanoate;
Methyl hexafluoroisobutyrate;
ISOBUTYRIC ACID,HEXAFLUORO-,METHYL ESTER;
2-(Trifluoromethyl)-3,3,3-trifluoropropionic Acid Methyl Ester;
PC5184E;
methyl 2-hydrohexafluoroisobutyrate;
Methyl 2-(Trifluoromethyl)-3,3,3-trifluoropropionate;
2-hydrohexafluoroisobutyric acid methyl ester;
Methyl 2,2-Bis(trifluoromethyl)acetate

CAS No.：: 360-54-3

分子式：: C₅H₄F₆O₂

分子量：: 210.08

精确分子量：: 210.01200

PSA：: 26.30000

InChI：: The Key: JGGBVFLRNNDHCM-UHFFFAOYSA-N3

风险术语：: R36/37/38

安全术语：: S16 S26 S36/S37/S39

分子结构式：

SDS：: 查看

2-(三氟甲基)-3,3,3-三幅丙酸甲酯物化性质

密度：: 1.604
沸点：: 90-91ºC
闪点：: 60ºC
折射率：: 1.269
其它信息：: 一、物性数据

性状：不可用

密度（g/mL,25/4℃）： 1.604

相对蒸汽密度（g/mL,空气=1）：不可用

熔点（ºC）：不可用

沸点（ºC,常压）：90-91

沸点（ºC,5.2kPa）：不可用

折射率： 1.269

闪点（ºC）： 60

比旋光度（º）：不可用

自燃点或引燃温度（ºC）：不可用

蒸气压（kPa,25ºC）：不可用

饱和蒸气压（kPa,60ºC）：不可用

燃烧热（KJ/mol）：不可用

临界温度（ºC）：不可用

临界压力（KPa）：不可用

油水（辛醇/水）分配系数的对数值：不可用

爆炸上限（%,V/V）：不可用

爆炸下限（%,V/V）：不可用

溶解性：不可用

2-(三氟甲基)-3,3,3-三幅丙酸甲酯安全信息

海关代码：: 2915900090
危险类别码：: R36/37/38
安全标志：: S16:远离火源。
S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
:

2-(三氟甲基)-3,3,3-三幅丙酸甲酯毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :: NQ4690000

CHEMICAL NAME :: Isobutyric acid, hexafluoro-, methyl ester

CAS REGISTRY NUMBER :: 360-54-3

BEILSTEIN REFERENCE NO. :: 1787515

LAST UPDATED :: 199612

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C5-H4-F6-O2

MOLECULAR WEIGHT :: 210.09

WISWESSER LINE NOTATION :: FXFFYXFFFVO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - body temperature decrease

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 14,114,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 17 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - body temperature decrease

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 14,114,1969

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 15 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - body temperature decrease

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 14,114,1969

毒理学数据：

二、毒理学数据：

急性毒性：不可用。

生态数据：

三、生态学数据：

1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

2-(三氟甲基)-3,3,3-三幅丙酸甲酯 MSDS

Methyl 2-(Trifluoromethyl)-3,3,3-trifluoropropionate Revision number: 5.3
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Methyl 2-(Trifluoromethyl)-3,3,3-trifluoropropionate

  Revision number:        5.3

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 2
  Flammable liquids
  HEALTH HAZARDS
    Category 3
  Acute toxicity (Oral)
  Skin corrosion/irritation        Category 2
    Category 2A
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger
  Hazard statements        Highly flammable liquid and vapour
    Toxic if swallowed
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
  [Prevention]
    Keep container tightly closed.
    Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
    measures against ignition by the static discharge and the spark.
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse
    mouth.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.
  Methyl 2-(Trifluoromethyl)-3,3,3-
  trifluoropropionate

Section 2. HAZARDS IDENTIFICATION
  [Storage]        Store in a well-ventilated place. Keep cool.
    Store locked up.
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  Components:        Methyl 2-(Trifluoromethyl)-3,3,3-trifluoropropionate
    >98.0%(GC)
  Percent:
  CAS Number:        360-54-3
    2-(Trifluoromethyl)-3,3,3-trifluoropropionic Acid Methyl Ester , Methyl 2,2-
  Synonyms:
    Bis(trifluoromethyl)acetate , 2,2-Bis(trifluoromethyl)acetic Acid Methyl Ester
  Chemical Formula:        C5H4F6O2

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Get medical advice/attention if you feel unwell.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
    Rinse cautiously with water for several minutes. Remove contact lenses, if present
  Eye contact:
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Immediately call a POISON CENTER or doctor/physician. Rinse mouth.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  from the chemical:
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
    spraying with water. Eliminate all ignition sources if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (self-contained breathing apparatus). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
  containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
  up: Adhered or collected material should be promptly disposed of, in accordance with
    appropriate laws and regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Methyl 2-(Trifluoromethyl)-3,3,3-
  trifluoropropionate

Section 7. HANDLING AND STORAGE
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
    surfaces. -No smoking. Take measures to prevent the build up of electrostatic
    charge. Use explosion-proof equipment. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust. Also install safety shower and eye bath.
  Engineering controls:
  Personal protective equipment
  Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
  Hand protection:        Impervious gloves.
    Safety goggles. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
    Clear
  Form:
  Colour:        Colorless - Almost colorless
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        88°C
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        1.45
  Solubility(ies):
  [Water]        No data available
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Conditions to avoid:        Spark, Open flame, Static discharge
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        orl-mus LD50:300 mg/kg
    ipr-mus LD50:17 mg/kg
    ivn-mus LD50:15 mg/kg
  Methyl 2-(Trifluoromethyl)-3,3,3-
  trifluoropropionate

Section 11. TOXICOLOGICAL INFORMATION
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available
    No data available
  Reproductive toxicity:
  RTECS Number:        NQ4690000

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system but exert extra care in igniting as this material is
    highly flammable. Observe all federal, state and local regulations when disposing of the substance

Section 14. TRANSPORT INFORMATION
  Hazards Class:        3: Flammable liquid.
  Subsidiary risk:        6.1: Toxic substance.
  UN-No:        1992
  Proper shipping name:        Flammable liquid, toxic, n.o.s.
  Packing group:        II

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Methyl 2-(Trifluoromethyl)-3,3,3-
  trifluoropropionate

SECTION 16 - ADDITIONAL INFORMATION
N/A

2-(三氟甲基)-3,3,3-三幅丙酸甲酯海关数据

中国海关编码：2915900090

概述：: 2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素：: 品名, 成分含量, 用途
监管条件：: A.入境货物通关单B.出境货物通关单
检验检疫：: R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
摘要/Summary：: 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

2-(三氟甲基)-3,3,3-三幅丙酸甲酯分子结构与计算化学数据

分子结构数据

1、摩尔折射率：27.86

2、摩尔体积（m³/mol）：147.7

3、等张比容（90.2K）：300.4

4、表面张力（dyne/cm）：17.1

5、极化率（10^-24cm³）：11.04

2-(三氟甲基)-3,3,3-三幅丙酸甲酯上游产品

1,1,3,3,3-五氟-2-三氟甲基丙基甲基醚甲醇

2-(三氟甲基)-3,3,3-三幅丙酸甲酯下游产品

三甲基氟硅烷 methyl 3-fluoro-3-morpholino-2-(trifluoromethyl)acrylate (Z)-methyl 3-(diethylamino)-3-fluoro-2-(trifluoromethyl)acrylate methyl 3-fluoro-3-(methylamino)-2-(trifluoromethyl)acrylate 三氟丙酸甲酯