制备方法

二、 生产方法: 以3-氯丙烯和甘油为原料，乙醇作稀释剂，可进一步合成该品。原料消耗定额：甘油（≥95）2870kg、t；3-氯丙烯（≥90）2150kg、t；乙醇（≥95）3680kg、t；氢氧化钠（≥95）1040kg、t

合成制备方法

二、 生产方法: 以3-氯丙烯和甘油为原料，乙醇作稀释剂，可进一步合成该品。原料消耗定额：甘油（≥95）2870kg、t；3-氯丙烯（≥90）2150kg、t；乙醇（≥95）3680kg、t；氢氧化钠（≥95）1040kg、t

用途简介

三、 用途: 可用于不饱和聚酯型聚氨酯橡胶中不饱和双键的引入单体，使得硫化得以进行。

用途

三、 用途: 可用于不饱和聚酯型聚氨酯橡胶中不饱和双键的引入单体，使得硫化得以进行。

海关代码：

2909499000

WGK_Germany：

1
德国有关水污染物质的分类清单

危险类别码：

R36

安全说明：

S26

RTECS号：

TY2700000

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。

危险标志：

Xi: Irritant;

CHEMICAL IDENTIFICATION

RTECS NUMBER :

TY2700000

CHEMICAL NAME :

1,2-Propanediol, 3-allyloxy-

CAS REGISTRY NUMBER :

123-34-2

BEILSTEIN REFERENCE NO. :

1701144

LAST UPDATED :

199701

DATA ITEMS CITED :

8

MOLECULAR FORMULA :

C6-H12-O3

MOLECULAR WEIGHT :

132.18

WISWESSER LINE NOTATION :

Q1YQ1O2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 2,574,1950

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 2,574,1950

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,632,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

4200 mg/kg

TOXIC EFFECTS :

Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - altered sleep time (including change in righting reflex) Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :

FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 8,477,1949

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

1135 mg/kg

TOXIC EFFECTS :

Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness Lungs, Thorax, or Respiration - other changes

REFERENCE :

JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 93,470,1948

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

>5 gm/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84034 No. of Facilities: 5 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 69 (estimated)

毒理学数据：

1、急性毒性：小鼠经口LD50：4200mg/kg

小鼠经皮下LD50：1135mg/kg

 

中国海关编码：2909499000

概述：

2909499000 其他醚醇及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

摘要/Summary：

2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

分子结构数据

1、   摩尔折射率：34.34

2、   摩尔体积（m³/mol）：124.4

3、   等张比容（90.2K）：310.3

4、   表面张力（dyne/cm）：38.7

5、   极化率（10^-24cm³）：13.61

计算化学数据

1.疏水参数计算参考值（XlogP）:-0.6

2.氢键供体数量:2

3.氢键受体数量:3

4.可旋转化学键数量:5

5.互变异构体数量:无

6.拓扑分子极性表面积49.7

7.重原子数量:9

8.表面电荷:0

9.复杂度:72.7

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:1

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

• 
  3-烯丙氧基-1
• 
  2-丙二醇红外图谱(IR1)
• 
  3-烯丙氧基-1
• 
  2-丙二醇红外图谱(IR2)
• 
  3-烯丙氧基-1
• 
  2-丙二醇质谱(MS)